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Chemical Structure| 6147-53-1 Chemical Structure| 6147-53-1

Structure of 6147-53-1

Chemical Structure| 6147-53-1

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Product Details of [ 6147-53-1 ]

CAS No. :6147-53-1
Formula : C4H14CoO8
M.W : 249.08
SMILES Code : CC([O-])=O.CC([O-])=O.[H]O[H].[H]O[H].[H]O[H].[H]O[H].[Co+2]
MDL No. :MFCD00149569
InChI Key :ZBYYWKJVSFHYJL-UHFFFAOYSA-L
Pubchem ID :61372

Safety of [ 6147-53-1 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302-H315-H317-H334-H341-H350-H360-H410
Precautionary Statements:P201-P261-P280-P284-P304+P340-P308+P313
Class:9
UN#:3077
Packing Group:

Application In Synthesis of [ 6147-53-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 6147-53-1 ]

[ 6147-53-1 ] Synthesis Path-Downstream   1~35

  • 1
  • [ 33421-36-2 ]
  • [ 6147-53-1 ]
  • mer-Co(C11H8NO)3 [ No CAS ]
  • 4
  • [ 6147-53-1 ]
  • [ 135616-40-9 ]
  • [ 176763-62-5 ]
  • 5
  • [ 108-86-1 ]
  • [ 4054-67-5 ]
  • [ 6147-53-1 ]
  • [ 65-85-0 ]
  • Co(2+)*2((CH3)2C3HN2)2*2C6H5COO(1-)*2C6H5Br=[Co(((CH3)2C3HN2)2)2(C6H5COO)2]*2C6H5Br [ No CAS ]
  • Co(2+)*((CH3)2C3HN2)2*C6H5COO(1-)*CH3COO(1-)*2C6H5Br=[Co((CH3)2C3HN2)2(C6H5COO)(CH3COO)]*2C6H5Br [ No CAS ]
  • 6
  • [ 288-32-4 ]
  • [ 7791-07-3 ]
  • [ 75-09-2 ]
  • [ 6147-53-1 ]
  • [ 151433-25-9 ]
  • [Co(III)(di-3,5-tert-butylsalicylidene-1,2-diaminocyclohexane)(2-)(imidazole)2](ClO4)*CH2Cl2 [ No CAS ]
  • 7
  • [ 7791-07-3 ]
  • [ 693-98-1 ]
  • [ 6147-53-1 ]
  • [ 151433-25-9 ]
  • [Co(III)(di-3,5-tert-butylsalicylidene-1,2-diaminocyclohexane)(2-)(2-methylimidazole)2](ClO4) [ No CAS ]
  • 8
  • [ 554-95-0 ]
  • [ 6147-53-1 ]
  • [ 65039-08-9 ]
  • [ 174899-82-2 ]
  • [ 951026-20-3 ]
  • 9
  • [ 26239-55-4 ]
  • [ 6147-53-1 ]
  • [(sodium)2 cobalt(II) (N-carbamoylmethyl-iminodiacetate)2(water)4]n [ No CAS ]
  • 10
  • [ 366-18-7 ]
  • [ 554-95-0 ]
  • [ 6147-53-1 ]
  • [ 174899-82-2 ]
  • (EMIm)[Co2(trimesate)4H7(2,2′-bipyridyl)2] [ No CAS ]
  • 11
  • [ 554-95-0 ]
  • [ 6147-53-1 ]
  • [ 174899-82-2 ]
  • Co5(OH)2(OAc)8(H2O)x [ No CAS ]
  • 12
  • [ 366-18-7 ]
  • [ 940-07-8 ]
  • [ 7732-18-5 ]
  • [ 6147-53-1 ]
  • [Co(pyrazine-2,6-dicarboxylic acid(-2H))(2,2'-bipyridine)(H2O)]*0.5H2O [ No CAS ]
  • 13
  • [ 67-56-1 ]
  • [ 4916-57-8 ]
  • [ 940-07-8 ]
  • [ 7732-18-5 ]
  • [ 6147-53-1 ]
  • [Co2(pyrazine-2,6-dicarboxylic acid(-2H))2(1,2-bis(4-pyridyl)ethane)(H2O)4]*0.5CH3OH*H2O [ No CAS ]
  • 14
  • [ 4916-57-8 ]
  • [ 940-07-8 ]
  • [ 7732-18-5 ]
  • [ 6147-53-1 ]
  • [Co(pyrazine-2,6-dicarboxylic acid(-2H))(1,2-bis(4-pyridyl)ethane)]*0.125(1,2-bis(4-pyridyl)ethane)*1.75H2O [ No CAS ]
  • 15
  • [ 376-73-8 ]
  • [ 6147-53-1 ]
  • [ 65039-08-9 ]
  • [ 174899-82-2 ]
  • [1-ethyl-3-methylimidazolium]2[Co3(H2O)4(hexafluoroglutarate)4] [ No CAS ]
  • 16
  • [ 377-38-8 ]
  • [ 6147-53-1 ]
  • [ 65039-08-9 ]
  • [ 174899-82-2 ]
  • [1-ethyl-3-methylimidazolium]2[Co(H2O)2(tetrafluorosuccinate)2] [ No CAS ]
  • 17
  • [ 17252-51-6 ]
  • [ 499-49-0 ]
  • [ 6147-53-1 ]
  • [Co2(5-methylisophthalate)2(1,3-bis(4-bipyridyl)propane)2(H2O)]n [ No CAS ]
  • 18
  • [ 110-86-1 ]
  • [ 23351-91-9 ]
  • [ 6147-53-1 ]
  • Co(2+)*3NC5H5*BrC6H3(CO2)2(2-)=Co(NC5H5)3(BrC6H3(CO2)2) [ No CAS ]
  • 19
  • [ 17252-51-6 ]
  • [ 23351-91-9 ]
  • [ 6147-53-1 ]
  • [ 1379609-52-5 ]
  • 20
  • [ 499-49-0 ]
  • [ 6147-53-1 ]
  • [ 345952-55-8 ]
  • [Co(mip)(1,4-bis(1,2,4-triazol)butane)]·H2O}n [ No CAS ]
  • 21
  • [ 69506-86-1 ]
  • [ 499-49-0 ]
  • [ 6147-53-1 ]
  • [Co(5-methylisophthalate)(1,4-bis(imidazol-1-yl)butane)]·2H2O}n [ No CAS ]
  • 22
  • [ 2645-22-9 ]
  • [ 23351-91-9 ]
  • [ 6147-53-1 ]
  • [Co(5-bromoisophthalate)(4,4'-dipyridylsulfide)](4,4'-dipyridyltrisulfide)0.5}2n [ No CAS ]
  • 23
  • [ 499-49-0 ]
  • [ 6147-53-1 ]
  • [ 69506-87-2 ]
  • [ 1448179-35-8 ]
  • 24
  • [ 6147-53-1 ]
  • [ 917-23-7 ]
  • [ 14172-90-8 ]
YieldReaction ConditionsOperation in experiment
93% With sodium acetate; potassium carbonate; In N,N-dimethyl-formamide; chlorobenzene; at 150℃; General procedure: In a 250mL distillation flask, 5,10,15,20-tetraphenylporphyrin (H2TPP) (0.50g, 0.81mmol) and NaOAc (0.30g, 3.6mmol) was stirred in 75mL of chlorobenzene and 50mL of DMF. After the addition of two equivalents of metal acetate, a Soxhlet extractor with a cellulose filter thimble filled with ?3g of K2CO3 was attached to the distillation flask. The assembly was completed with a condenser on the top of the extractor; and then the mixture was heated to reflux at 150C overnight. The reaction extent was monitored by TLC or UV-Vis until all the H2TPP was consumed. After the reaction was compete, the solvent was removed under vacuum. The remaining solid was dissolved in 150mL of chloroform, and washed with water (50mL×3). The organic layer was further washed with a saturated sodium bicarbonate solution (50mL×3), and then dried over K2SO4. After removal of the solvent in vacuo, the solid was recrystallized from chloroform/heptane.
87% In N,N-dimethyl-formamide; for 0.166667h;Heating; (5,10,15,20-tetraphenyl-21,23-porphinato)cobalt(II) (CoTPP) was prepared by reaction of 5,10,15,20-tetraphenyl-21,23-porphine (H2TPP) (50 mg, 0.081 mmol) with Co(AcO)2 · 4H2O (101 mg, 0.41 mmol) in boiling dimethylformamide (DMF) for 10 min. When the reaction was(as judged from the disappearance of H2TPP bands and the end of evolution of the electronic absorption spectrum (UV-vis spectrum) of a reaction mixture sample in chloroform) the contents of the reaction flask were cooled and the products were extracted into chloroform after dilution with water. The solution in CHCl3 was repeatedly washed with distilled water to remove DMF. The CHCl3 was partially distilled off; the residual solution was purified by chromatography on an Al2O3-packed column (grade II activity according to Brockman) using chloroform. CoTPP yield: 87%. UV-vis spectrumin toluene (lambdamax nm, (logepsilon)): 413 (5.35), 529 (4.38). IR spectrum in KBr (nu, cm-1): 415, 467, 527, 557, 567, 621, 650, 671, 700, 716, 751, 797, 835, 846, 900, 923, 997, 1005, 1020, 1071, 1155, 1178, 1205, 1236, 1309, 1350, 1441, 1492, 1540, 1576, 1599, 2852, 2922, 3025, 3052. 1H NMR in CDCl3 (delta, ppm): 9.83 (m, 12Hm,p), 13.16 (br. s, 8H),15.94 (br. s, 8Hbeta). 13CNMR in CDCl3 (delta, ppm): 157.59, 141.79, 131.38, 130.92, 99.61. MS (MALDI-TOF) (m/z): 671.25 [M]+.
1.7 kg With potassium carbonate; In N,N-dimethyl-formamide; chlorobenzene; at 150℃;Large scale; In a 1000 L metallization reactor, a mixed solvent of 250 L of chlorobenzene and 160 L of N,N-dimethylformamide (DMF) was added. Stirring was started by adding 5,10,15,20-tetraphenylporphyrin (H2TPP) at 1.7 kg. Finally, add two equivalents of cobalt acetate tetrahydrate (Co(OAc)2*4H2O) 1.33kg, then, about 12 kg of potassium carbonate (K2CO3) is charged into the alkali storage chamber. The mixture in the reactor was heated to 150 C and kept under reflux. The progress of the reaction was then monitored by thin layer chromatography (TLC) or UV-Vis absorption spectroscopy (UV-Vis) until the complete reaction of H2TPP was completed. The solvent was distilled off under vacuum and the remaining solid was dissolved in 600 L of chloroform. Wash three times with water 150L, then collect these liquids for static stratification. Drying the organic layer with molecular sieves, The solvent is distilled off under vacuum, The remaining solid was recrystallized from chloroform/heptane. A pink purple crystalline solid product, cobalt porphyrin, 1.7 kg was obtained.
  • 25
  • [ 4054-67-5 ]
  • [ 6147-53-1 ]
  • [ 787-70-2 ]
  • [ 68-12-2 ]
  • [ 75-05-8 ]
  • [Co2(4,4′-biphenyldicarboxylate)1.5(3,3′,5,5′-tetramethyl-4,4′-bipyrazole(1-))]·DMF·CH3CN·H2O [ No CAS ]
  • 26
  • [ 4054-67-5 ]
  • [ 6147-53-1 ]
  • [ 787-70-2 ]
  • [ 68-12-2 ]
  • [Co2(4,4′-biphenyldicarboxylicacid)2(3,3′,5,5′-tetramethyl-4,4′-bipyrazole)]*2(DMF)*5(H2O) [ No CAS ]
YieldReaction ConditionsOperation in experiment
23.4% In acetonitrile; at 140℃; for 72.0h; A mixture of Co(CH3COO)2·4H2O (0.050 g, 0.20 mmol), H2bpdc (0.072 g, 0.30 mmol) and H2bpz (0.038 g, 0.20 mmol) in DMF (5 mL) and CH3CN (5 mL) was placed in a Teflon-lined stainless steel vessel (15 mL). The vessel was heated at 140 C for 72 h, then slowly cooled to room temperature. The purple crystals of 1 were isolated by filtrating, washing with DMF, and dried in vacuo. Yield: 24 mg (23.4%). Anal. Calcd for C44H54Co2N6O15: C, 51.57; H, 5.31; N, 8.20%. Found: C, 51.45; H, 5.17; N, 8.11%. IR (KBr, cm-1): 3426(vs), 2919(w), 1680(s), 1605(s), 1540(m), 1394(s), 1297(m), 1172(w), 1130(w), 851(m), 765(s).
  • 27
  • [ 63089-50-9 ]
  • [ 6147-53-1 ]
  • [ 86665-25-0 ]
YieldReaction ConditionsOperation in experiment
82% With butyl(2-hydroxyethyl)dimethylammonium acetate; at 100℃; for 2h;Ionic liquid; Inert atmosphere; General procedure: A mixture of desired phthalonitrile (4a-i, 200mg) and corresponding metal salts (0.25 equivalents) were stirred at 100C with functional ionic liquid 2c (1 equivalent) for the appropriate time (Table 1, 2 and 3). The progress of the reaction was monitored by TLC and UV-Visible spectroscopic analysis. When reaction was completed, the mixture was cooled to room temperature, and distilled water (50 mL) was added to dissolve the functional ionic liquid. The blue-green solid mass was filtered and the aqueous filtrate was evaporated using reduced pressure to recover the pure ionic liquid for further use. The solid mass was further washed thoroughly with H2O-MeOH (1:1, 100 mL) to remove the colorless impurities and metallophthalocyanines are obtained in pure form. All of the phthalocyanines are known compounds and their purities were confirmed by UV-Visible spectroscopic analysis and further comparison with literature.
  • 28
  • [ 63400-46-4 ]
  • [ 499-49-0 ]
  • [ 6147-53-1 ]
  • [Co2(5-methylisophthalic acid)2(1,6-bis(triazol)hexane)2](H2O)0.5 [ No CAS ]
YieldReaction ConditionsOperation in experiment
With sodium hydroxide; In water; at 140℃; for 72h;Autoclave; A mixture of <strong>[499-49-0]5-methylisophthalic acid</strong> (18.2 mg, 0.1 mmol),1,6-bis(triazol)hexane (22.0 mg, 0.1 mmol), Co(OAc)2¢4H2O(24.9 mg, 0.1 mmol), NaOH(4 mg, 0.1mmol), and H2O(12 mL) was placed into 25mL Teflon-lined autoclave andheated at 140C for 72 h. The autoclave was cooled over aperiod of 11 h at a rate 5C h1 to room temperature. Redcrystals of complex 1 were obtained. It was collected by filtration,and dried in air. Anal. Calcd. (percent) forC38H45Co2N16O4.5: C, 49.84; H, 4.95; N, 24.47. Found (percent):C, 49.80; H, 4.89; N, 24.42. IR (cm1):3119 (s), 2919(m),2850(m), 1614 (s), 1539 (s), 1383 (s), 1279 (m), 1131 (s), 778(s), 725 (s), 667 (s).
  • 29
  • [ 17084-13-8 ]
  • [ 7732-18-5 ]
  • [ 6147-53-1 ]
  • [ 112881-51-3 ]
  • [Co(4'-(4'''-pyridyl)-2,2':6',2''-terpyridine)2](PF6)2*H2O [ No CAS ]
  • 30
  • [ 4877-80-9 ]
  • [ 6147-53-1 ]
  • 2C18H6O6(6-)*3Co(2+) [ No CAS ]
  • 31
  • [ 64-17-5 ]
  • [ 19829-72-2 ]
  • [ 7732-18-5 ]
  • [ 6147-53-1 ]
  • 2H2O*2H(1+)*6Co(2+)*O(2-)*2C8H2O6(4-)*6C2H6O*2C8H4O6(2-) [ No CAS ]
  • 32
  • [ 4923-84-6 ]
  • [ 6147-53-1 ]
  • [ 112881-51-3 ]
  • C48H46Co2N8O6P2 [ No CAS ]
  • 33
  • [ 18351-38-7 ]
  • [ 6147-53-1 ]
  • [ 112881-51-3 ]
  • C64H62Co2N8O6P2 [ No CAS ]
  • 34
  • cobalt(II) chloride hexahydrate [ No CAS ]
  • [ 5704-04-1 ]
  • [ 6147-53-1 ]
  • C6H12NO5(1-)*Co(2+)*Cl(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
60.7% A mixture of CoCl2*6H2O (1 mmol) and Co(Ac)2*4H2O (0.5 mmol) with tricH5 (0.5 mmol) and 9 ml of ethanol was stirred at room temperature for 15 min, then 0.25 ml triethylamine was added and the reactants were sealed toa 15-ml Teflon-lined autoclave at 140 C for 3 days. After cooling to room temperature at a rate of 10 K/h-1, purpleoctahedral block crystals (Fig. S2 of Supplementary Materials) were picked out, washed with ethanol, and dried in air (yield:60.7 % based on CoII). Anal. Calcd. (%) for C6H12ClCoNO5: C 26.33, H 4.76, N 5.13; Found C 26.43, H 4.78, N 5.15. IR data for 1 (KBr, cm-1): 3397 (m), 3310 (m), 3243 (m), 2948 (w), 1611 (s), 1459 (w), 1440 (w), 1398 (s), 1013 (s).
  • 35
  • [ 1835-65-0 ]
  • [ 6147-53-1 ]
  • [ 3317-67-7 ]
 

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