Home Chemistry Heterocyclic Building Blocks Aromatic Heterocycles 1,2,4,5-Tetrazine
Diels-Alder Reaction: 1,2,4,5-Tetrazine can undergo a Diels-Alder reaction with certain dienophiles, such as strained alkenes and alkynes. This reaction is highly selective and fast, resulting in the formation of a cycloadduct. The reaction is often used for bioorthogonal chemistry and labeling applications.
Cycloadditions: Tetrazines can participate in other cycloaddition reactions, such as the inverse-electron-demand Diels-Alder reaction, which involves the reaction of tetrazines with certain strained alkenes or alkynes.
Photochemical Reactions: Tetrazines are known to undergo photochemical reactions, including photoisomerization and photodissociation, when exposed to appropriate wavelengths of light.
Metal-Catalyzed Reactions: Tetrazines can be used in metal-catalyzed reactions, particularly as ligands for transition metal complexes, which can lead to various transformations.
Reduction Reactions: Tetrazines can be reduced to corresponding dihydrotetrazines under certain conditions. Reduction reactions may involve the use of various reducing agents.
Substitution Reactions: Like other nitrogen-containing heterocycles, tetrazines can undergo substitution reactions with suitable electrophiles and nucleophiles.
Ring Cleavage Reactions: Depending on the reaction conditions and reagents, tetrazines can undergo ring cleavage reactions, leading to the formation of different products.
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Dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate
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2,2'-((1,2,4,5-Tetrazine-3,6-diyl)bis(sulfanediyl))diacetic acid
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1,2,4,5-Tetrazine-3,6-dicarboxylic acid
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