Home Chemistry Organic Building Blocks Ketones Cyclohexane-1,3-Dione
Ketone Reactions: As a compound with carbonyl groups, it can undergo many reactions typical of ketones, such as nucleophilic addition reactions, reduction reactions, and others.
Aldol Condensation: Cyclohexane-1,3-dione can undergo aldol condensation, a reaction in which it reacts with a base to form a β-hydroxy ketone or an α,β-unsaturated ketone.
Cannizzaro Reaction: It can undergo the Cannizzaro reaction under specific conditions to give rise to the corresponding alcohol and carboxylic acid.
Nucleophilic Addition: It can react with nucleophiles (such as Grignard reagents or amines) at the carbonyl group, forming addition products.
Oxidation: Depending on the reaction conditions, it can be oxidized to form various products, including diols and dicarboxylic acids|https://www.ambeed.com/carboxylic-acids.html.
Reduction: It can be reduced to form a diol or even further to a saturated cyclohexane.
Crossed Cannizzaro Reaction: In the presence of other aldehydes or ketones, cyclohexane-1,3-dione can undergo a crossed Cannizzaro reaction, leading to the reduction of the other carbonyl compound while itself being oxidized to a carboxylic acid.
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5,5-Dimethyl-2-(3-methylbutanoyl)cyclohexane-1,3-dione
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Methyl 3,5-dioxocyclohexane-1-carboxylate
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