Home Chemistry Heterocyclic Building Blocks Dioxolanes 1,3-Dioxolan-2-One
Ring-Opening Reactions: 1,3-dioxolan-2-one can undergo ring-opening reactions, typically in the presence of a nucleophile such as amines or alcohols. This results in the formation of an open-chain compound, which may further react with other reagents.
Nucleophilic Addition: Nucleophiles can add to the carbonyl group in 1,3-dioxolan-2-one, resulting in the formation of new compounds. For example, an amine can react with the carbonyl group to yield an amide derivative.
Acylation Reactions: 1,3-dioxolan-2-one can be acylated using acylating agents, leading to the introduction of acyl groups (RCO-) onto the oxygen atom. Common acylating agents include acyl chlorides and anhydrides.
Esterification: The carbonyl group can react with alcohols in the presence of an acid catalyst to form esters.
Oxidation and Reduction: Depending on the reaction conditions, 1,3-dioxolan-2-one can undergo oxidation or reduction reactions, leading to the formation of different products.
Rearrangements: In some cases, 1,3-dioxolan-2-one can undergo intramolecular rearrangements, leading to the formation of different cyclic compounds.
Hydrolysis: 1,3-dioxolan-2-one can be hydrolyzed in the presence of an acid or base, resulting in the cleavage of the ring and the formation of carboxylic acids and/or alcohols, depending on the reaction conditions.
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(2-Oxo-1,3-dioxolan-4-yl)methyl methacrylate
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