Home Chemistry Organic Building Blocks Aryls 9H-Xanthene
Halogenation: Xanthene can be halogenated with halogens like chlorine, bromine, or iodine. The reaction typically involves the substitution of hydrogen atoms with halogen atoms.
Oxidation: Xanthene can be oxidized to form xanthenone. Common oxidizing agents such as chromic acid (H2CrO4) or potassium permanganate (KMnO4) can be used for this purpose.
Reduction: Xanthene can be reduced to form dihydroxanthene. Reducing agents like lithium aluminum hydride (LiAlH4) or sodium borohydride (NaBH4) can be employed.
Friedel-Crafts Acylation: Xanthene can undergo Friedel-Crafts acylation, where an acyl group is introduced onto the aromatic ring using an acyl chloride and a Lewis acid catalyst like aluminum chloride (AlCl3).
Ring-Closure Reactions: Xanthene can participate in various ring-closure reactions. For example, it can undergo cyclization reactions to form derivatives like 9-oxo-9H-xanthen-1-yl derivatives, which can be used in the synthesis of various compounds.
Nucleophilic Substitution: Xanthene derivatives can undergo nucleophilic substitution reactions when appropriate nucleophiles are present.
Cross-Coupling Reactions: Xanthene compounds can participate in cross-coupling reactions with various organometallic compounds to introduce different substituents onto the xanthene ring.
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(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(di-tert-butylphosphine)
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