Home Chemistry Heterocyclic Building Blocks Pyrans Tetrahydro-2H-Thiopyran
Oxidation: Thiopyran can be oxidized to produce sulfoxides and sulfones using oxidizing agents like hydrogen peroxide (H2O2) or m-chloroperbenzoic acid (MCPBA). The sulfur atom in thiopyran is susceptible to oxidation to form sulfoxides and sulfones.
Reduction: Thiopyran can be reduced to the corresponding tetrahydrothiopyran using reducing agents such as sodium borohydride (NaBH4) or lithium aluminum hydride (LiAlH4).
Substitution Reactions: Thiopyran can undergo substitution reactions at the sulfur atom. For example, it can react with alkyl halides to form alkylthio-substituted derivatives.
Ring-Opening Reactions: Thiopyran can undergo ring-opening reactions under specific conditions. For instance, treatment with strong acids or nucleophiles can lead to the cleavage of the ring, resulting in the formation of new compounds.
Metal Complexation: Thiopyran can form complexes with various metal ions, especially transition metals like copper, nickel, and palladium. These complexes can have unique reactivity and find applications in catalysis.
Electrophilic Aromatic Substitution: Depending on its substitution pattern, thiopyran can undergo electrophilic aromatic substitution reactions on the aromatic ring, similar to benzene derivatives.
Photochemical Reactions: Thiopyran may undergo photochemical reactions, particularly when exposed to ultraviolet (UV) light, leading to the formation of photoproducts.
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4-(Aminomethyl)tetrahydro-2H-thiopyran-4-ol
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1-(Tetrahydro-2H-thiopyran-4-yl)hydrazine dihydrochloride
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Ethyl 2-(tetrahydro-2H-thiopyran-4-yl)acetate
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Tetrahydro-2H-thiopyran-4-amine hydrochloride
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