Home Chemistry Organometallic Reagents Organoborons 4,4,5,5-Tetramethyl-2-(Naphthalen-1-Yl)-1,3,2-Dioxaborolane
Ring Opening Reactions: 1,4-dioxane can undergo ring-opening reactions with various nucleophiles, including alkyl lithium compounds, Grignard reagents, and sodium amide. These reactions result in the formation of open-chain compounds.
Acetal Formation: 1,4-dioxane can react with aldehydes or ketones in the presence of an acid catalyst to form acetals or ketals. This is a protective group strategy often used in organic synthesis.
Oxidation: 1,4-dioxane can be oxidized under specific conditions, leading to the formation of various oxidation products. Common oxidants used in these reactions include potassium permanganate (KMnO4) and hydrogen peroxide (H2O2).
Reduction: 1,4-dioxane can be reduced to diol compounds using reducing agents like lithium aluminum hydride (LiAlH4) or sodium borohydride (NaBH4).
Ether Formation: 1,4-dioxane can react with alkyl halides or alkyl tosylates in the presence of a base to form ethers. This reaction is similar to the Williamson ether synthesis.
Halogenation: 1,4-dioxane can undergo halogenation reactions when treated with halogens (e.g., bromine or chlorine) or with appropriate halogenating agents.
Nucleophilic Substitution: The oxygen atoms in 1,4-dioxane can act as nucleophilic sites, and the molecule can undergo nucleophilic substitution reactions when exposed to electrophilic reagents.
Polymerization: Under certain conditions and with the appropriate catalysts, 1,4-dioxane can undergo polymerization reactions to form polymeric materials.
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4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-2-ol
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N,N-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-1-amine
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2-(4-Chloronaphthalen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
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2-(4-(Bromomethyl)naphthalen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
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2-(8-Chloronaphthalen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
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4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-1-ol
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4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-naphthaldehyde
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Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-naphthoate
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4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-naphthoic acid
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4,4,5,5-Tetramethyl-2-(5-nitronaphthalen-1-yl)-1,3,2-dioxaborolane
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4,4,5,5-Tetramethyl-2-(4-nitronaphthalen-1-yl)-1,3,2-dioxaborolane
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4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-1-amine
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4,4,5,5-Tetramethyl-2-(naphthalen-1-yl)-1,3,2-dioxaborolane
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4,4,5,5-Tetramethyl-2-(4-methylnaphthalen-1-yl)-1,3,2-dioxaborolane
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