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Chemical Structure| 373-02-4 Chemical Structure| 373-02-4

Structure of 373-02-4

Chemical Structure| 373-02-4

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Product Details of [ 373-02-4 ]

CAS No. :373-02-4
Formula : C4H6NiO4
M.W : 176.78
SMILES Code : CC([O-])=O.CC([O-])=O.[Ni+2]
MDL No. :MFCD00012451

Safety of [ 373-02-4 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314-H372-H317-H334-H350
Precautionary Statements:P501-P272-P260-P270-P202-P201-P264-P280-P284-P308+P313-P362+P364-P303+P361+P353-P333+P313-P301+P330+P331-P304+P340+P310-P305+P351+P338+P310-P405
Class:8
UN#:1759
Packing Group:

Application In Synthesis of [ 373-02-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 373-02-4 ]

[ 373-02-4 ] Synthesis Path-Downstream   1~11

  • 1
  • [ 373-02-4 ]
  • [ 135616-40-9 ]
  • Ni((R,R)-N,N-bis(3,5-di-tert-butylsalicylidene)cyclohexane-1,2-diamine) [ No CAS ]
YieldReaction ConditionsOperation in experiment
66% In methanol; dichloromethane; water; at 3 - 20℃; for 2.5h; Ni(salen*) was prepared as follows: First, to a 250 mL round bottom flask was added 1.0087 g (1.8446 mmol) of (R,R)-N,N'-Bis(5-3-tert-butyl-salicylidene)-l,2- cyclohexanediamine that was dissolved in 44 mL of methylene chloride. Concurrently, Ni?(OAc)24H2O (0.5076 g, 2.040 mmol) was dissolved in 25 mL of dry methanol. The nickel solution was added dropwise to the reaction mixture was stirred for 2 hours at room temperature. The mixture was then cooled to 3 C in an ice bath and stirred for an additional 0.5 hour. The solid product was filtered using a 60 mL medium frit and washed with cold dry methanol until the filtrate became clear. The solid was dried under vacuum overnight. The yield of the complex was 0.7316 g (66%). 1H NMR: (CDCl3, ppm) mu = 1.28 (s, 9H); 1.34 (m, EPO <DP n="13"/>2H); 1.43 (s, 9H); 1.92 (m, IH); 2.45 (m, IH); 2.99 (m, IH); 6.90 (d, J = 2.4Hz, IH); 7.31 (d, IH); 7.40 (s, IH). ELEMENTAL ANALYSIS: Theoretical (%) C 71.41, H 8.99, N 4.63, Ni 9.69. Experimental (%) C 71.72, H 8.66, N 4.57, Ni 9.55.
  • 3
  • [ 373-02-4 ]
  • [ 66-72-8 ]
  • [ 1482-98-0 ]
  • Ni(2+)*OC5HN(CH3)(CH2O)CHNCH2CH2CH(CO2)NCHC5HN(CH3)(CH2O)O(5-)*3H(1+)={NiC20H22N4O6} [ No CAS ]
  • 4
  • [ 373-02-4 ]
  • [ 66-72-8 ]
  • [ 1482-98-0 ]
  • Ni(2+)*2OC5HN(CH3)(CH2O)CHNCH2CH2CH(NH2)CO2(3-)*4H(1+)={Ni(C12H16N3O4)2} [ No CAS ]
  • 5
  • [ 441-38-3 ]
  • [ 373-02-4 ]
  • K(1+)*Ni(2+)*C6H5CH(O)C(NO)C6H5(2-)*C6H5CH(OH)C(NO)C6H5(1-)=K{NiC14H11NO2(C14H12NO2)} [ No CAS ]
  • 6
  • [ 7310-95-4 ]
  • [ 373-02-4 ]
  • [ 81-16-3 ]
  • (alsatH)nickel*trihydrate [ No CAS ]
  • 7
  • [ 288-32-4 ]
  • [ 14257-84-2 ]
  • [ 373-02-4 ]
  • [ 176861-83-9 ]
  • 8
  • [ 7732-18-5 ]
  • [ 373-02-4 ]
  • [ 148332-36-9 ]
  • Ni(2,2':6',2''-terpyridine-4'-carboxylate)2*4H2O [ No CAS ]
  • 9
  • [ 3646-50-2 ]
  • [ 96293-17-3 ]
  • [ 373-02-4 ]
  • C34H31N3NiO3 [ No CAS ]
  • C34H31N3NiO3 [ No CAS ]
  • 10
  • [ 7732-18-5 ]
  • [ 373-02-4 ]
  • [ 547-32-0 ]
  • [ 1096252-90-2 ]
YieldReaction ConditionsOperation in experiment
Ca. 35% In methanol; for 3h;Reflux; Sodium salt of sulfadiazine (0.545 g, 2 mmol) is dissolved in hot methanol and to this, an aqueous solution of nickel acetate(0.176 g, 1 mmol) is added with constant stirring and the mixture is refluxed for 3 h. A light blue precipitate is formed, filtered, and washed with hot distilled water and methanol successively and dried in a desiccator over anhydrous CaCl2.The yield at the end of reaction for the complex is around 35%.The results for [C20H22N8Ni1O6S2] are: Anal. Calcd. (%): C,40.49; H, 3.73; N, 18.88. Found (%): C, 40.16; H, 3.47; N, 17.54.
  • 11
  • [ 4877-80-9 ]
  • [ 373-02-4 ]
  • 2C18H6O6(3-)*3Ni(2+) [ No CAS ]
 

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