1593-60-8|N-Hydroxy-4-methylbenzenesulfonamide| Ambeed

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Quality Control of [ 1593-60-8 ] Purity: 98% SDS Specification

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Product Details of [ 1593-60-8 ]

CAS No. :	1593-60-8
Formula :	C₇H₉NO₃S
M.W :	187.22
SMILES Code :	O=S(C1=CC=C(C)C=C1)(NO)=O
MDL No. :	MFCD11850835
InChI Key :	XMJJPCJUQLGGND-UHFFFAOYSA-N
Pubchem ID :	10081163

Safety of [ 1593-60-8 ]

GHS Pictogram:
Signal Word:	Danger
Hazard Statements:	H315-H319-H228
Precautionary Statements:	P240-P210-P241-P264-P280-P302+P352-P370+P378-P337+P313-P305+P351+P338-P362+P364-P332+P313
Class:	4.1
UN#:	1325
Packing Group:	Ⅲ

Application In Synthesis of [ 1593-60-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 1593-60-8 ]

[ 1593-60-8 ] Synthesis Path-Downstream 1~35

1
[ 98-59-9 ]
[ 1593-60-8 ]

Yield	Reaction Conditions	Operation in experiment
87.5%	With hydroxylamine hydrochloride; magnesium oxide; In tetrahydrofuran; methanol; water; at 20℃;	Hydroxylamine hydrochloride (7.2 g, 86 mmol) was dissolved in methanol (30 ml) and water (20 ml), magnesium oxide (5.1 g, 129 mmol) was added, stirred for 10 minutes, then p-toluenesulfonyl chloride (8 g, 43 mmol) in tetrahydrofuran (300 ml), stirred vigorously at room temperature, and reacted to TLC to monitor the starting material for complete reaction. The extract was filtered through Celite, dried over anhydrous magnesium sulfate and concentrated under reduced pressure to give N-hydroxy-4-methylbenzenesulfonamide (7 g, white solid) in 87.5% yield.

References: [1]Patent: CN105418632,2016,A .Location in patent: Paragraph 0175; 0176; 0177.
[2]Synlett,2009,p. 2149 - 2153.
[3]Journal of Inorganic Biochemistry,2013,vol. 118,p. 134 - 139.
[4]Green Chemistry,2021,vol. 23,p. 9428 - 9432.
[5]Journal fur praktische Chemie (Leipzig 1954),1901,vol. <2>63,p. 176.
Chemisches Zentralblatt,1901,vol. 72,p. 455.
[6]European Journal of Medicinal Chemistry,1996,vol. 31,p. 1001 - 1010.
[7]Organometallics,2017,vol. 36,p. 1259 - 1268.
[8]Advanced Synthesis and Catalysis,2019,vol. 361,p. 5552 - 5557.

2
C₂₆H₂₃NO₃S [ No CAS ]
[ 1593-60-8 ]

References: [1]Journal of Organic Chemistry,2007,vol. 72,p. 8123 - 8126.

3
[ 100-42-5 ]
[ 1593-60-8 ]
[ 1377813-85-8 ]