Dichloro(benzene)ruthenium(II) dimer | Benzeneruthenium(II) chloride dimer | Ruthenium

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Quality Control of Dichloro(benzene)ruthenium(II) dimer Purity: 97% SDS Specification

COA

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NMR

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CNMR

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HPLC

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Product Details of Dichloro(benzene)ruthenium(II) dimer

CAS No. :	37366-09-9
Formula :	C₁₂H₁₂Cl₄Ru₂
M.W :	500.18
SMILES Code :	C1=CC=CC=C1.C2=CC=CC=C2.[Ru+2].[Cl-].[Cl-].[Ru+2].[Cl-].[Cl-]
Synonyms :	Benzeneruthenium(II) chloride dimer
MDL No. :	MFCD00064686
InChI Key :	YGXMUPKIEHNBNQ-UHFFFAOYSA-J
Pubchem ID :	10962144

Safety of Dichloro(benzene)ruthenium(II) dimer

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H315-H319-H335
Precautionary Statements:	P261-P305+P351+P338

Application In Synthesis of Dichloro(benzene)ruthenium(II) dimer

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 37366-09-9 ]

[ 37366-09-9 ] Synthesis Path-Downstream 1~35

1
[ 37366-09-9 ]
[ 22795-99-9 ]
[Ru(II)((S)-(-)-2-aminomethyl-1-ethylpyrrolidine)(η6-benzene)Cl]Cl [ No CAS ]

References: [1]Inorganica Chimica Acta,2004,vol. 357,p. 1247 - 1255.

2
[ 17084-13-8 ]
[ 37366-09-9 ]
[ 15184-96-0 ]
[ 75-05-8 ]
[ 827627-09-8 ]

References: [1]Journal of Organometallic Chemistry,2004,vol. 689,p. 4820 - 4832.

3
[ 37366-09-9 ]
[ 1091606-67-5 ]
(S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine) [ No CAS ]
C₇₀H₅₆Cl₂NP₃Ru [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		Tetrahydrofuran (20 ml) was added to a mixture of the S-binap ligand (0.5 g, 0.8 mmol) and [RuCl2(benzene)]2 (200 mg, 0.4 mmol), followed by DMF (0.5 ml) and the mixture refluxed for 6 hours under argon. The solvent was removed under reduced pressure and a solution of the aminophosphine (0.8 mmol) in toluene 20 added. The mixture was refluxed for 4 hours and the solvent removed under reduced pressure. Ether (10 ml) was then added and the mixture stirred for 2 hours under argon. The solids were filtered, washed with ether and dried under vacuum. The catalysts were

References: [1]Patent: WO2008/148202,2008,A1 .Location in patent: Page/Page column 55.

4
[ 37366-09-9 ]
[ 865169-07-9 ]
[ 1442692-01-4 ]

Yield	Reaction Conditions	Operation in experiment
45.7%	In dichloromethane; at 60℃; for 0.5h;Microwave irradiation;	General procedure: A mixture of [(C6H6)RuCl2]2 (0.1 mmol, 50 mg) and 1a, 2a, 3a, 4a,5a, 6a and 7a (0.2 mmol) in 20 ml of dichloromethane was heated in microwave reactor at 60 C for 30 min. The solvent was removed by rotary evaporation and the residue was dissolved in minimum amounts of methanol and then filtered to remove unreacted ligand to obtain a yellow crude product after recrystallization. 1b: yield: 91.2%. ESI-MS (in MeOH): m/z 435.1, ([M - Cl]+). UV-visible in MeOH [λmax, nm (ε/M-1 cm-1)]: 249 (29,585), 295 (20,095). IR (in KBr, νmax/cm-1): 3855.9, 3390.64, 3050.41, 1621.98, 1603.62, 1536.61, 1478.49, 1252.77, 1198.21, 1084.36, 848.13, 811.34, 724.29 cm-1 . 1H NMR (DMSO-d6, δ ppm) δ 9.84 (d, J = 5.0 Hz, 2H),9.22 (d, J = 7.9 Hz, 2H), 8.60 (d, J = 8.1 Hz, 2H), 8.09 (dd, J = 8.1,5.3 Hz, 1H), 6.31 (s, 6H). 13C NMR (126 MHz, DMSO) δ 155.93 (s), 145.19 (s), 144.96 (s), 134.34 (s), 128.00 (s), 88.67 (s). 2b: yield: 90.3%. ESI-MS (in MeOH): m/z 554.1, ([M -Cl]+). UV-visible in MeOH [λmax, nm (ε/M-1 cm-1)]: 290 (43,780), 342 (38,460). IR (in KBr, νmax/cm-1): 3859.28, 3389.91, 3057.66, 1608.17, 1529.30, 1486.91, 1202.82, 823.99, 812.25, 722.79. 1H NMR (in DMSO-d6, δ/ppm): 10.20-9.76 (2H, m), 9.60 (2H, t, J = 22.3 Hz), 9.40 (2H, d, J = 8.2 Hz), 9.11 (2H, dd, J = 17.3, 8.0 Hz), 8.57-8.29 (2H, m), 8.28-8.07 (2H, m), 6.91 (2H, t, J = 16.9 Hz), 6.45-6.19 (6H, m). 13C NMR(126 MHz, DMSO) δ 190.31 (s), 151.87 (s), 128.49 (s), 126.17 (s), 116.98 (s), 112.21 (s), 111.50 (s), 87.19 (s). 3b: yield: 91.4%. ESI-MS (in MeOH): m/z 541.13, ([M -Cl]+) . UV-visible in MeOH [λmax, nm (ε/M-1 cm-1)]: 289 (41,520). IR (in KBr, νmax/cm-1): 3862.15, 3423.39, 2987.91, 1610.97, 1524.46, 1483.18, 1255.81, 1181.77, 1066.11, 839.63, 810.66, 722.07. 1H NMR (DMSO-d6, δ/ppm): 9.96 (dd, J = 5.3, 1.1 Hz, 2H), 8.42 (d, J = 8.6 Hz, 2H), 8.21 (s, 2H), 7.73 (d, J = 8.7 Hz, 2H), 7.37 (s, 2H), 6.33 (s, 6H). 13C NMR (126 MHz, DMSO) δ 162.61 (s), 155.41 (s), 144.84 (s), 134.43 (s), 130.27 (s), 127.64 (s), 116.29 (s), 88.63 (s), 57.30 (s). 4b: yield: 90.8%. ESI-MS (in MeOH): m/z 527.07 ([M -Cl]+). UV-visible in MeOH [λmax, nm (ε/M-1 cm-1)]: 287 (46,030). IR (in KBr, νmax/cm-1): 3865.69, 3400.23, 3068.44, 1611.12, 1481.83, 1276.56, 1175.75, 842.83, 808.44, 721.33. 1H NMR (in DMSO-d6, δ/ppm): 9.70 (d, J = 5.2 Hz, 2H), 9.07 (d, J = 7.2 Hz, 2H), 8.76 (d, J = 7.9 Hz, 2H), 8.11 (d, J = 10.6 Hz, 2H), 7.96 (dd, J = 8.2, 5.2 Hz, 2H), 7.37 (s, 2H), 6.28 (s, 6H). 13C NMR (126 MHz, DMSO) δ 161.47 (s), 155.15 (s), 135.98 (s), 129.69 (s), 117.71 (s), 88.65 (s). 5b: yield: 45.7%. ESI-MS (in MeOH): m/z 555.13, ([M -Cl]+). UV-visible in MeOH [λmax, nm (ε/M-1 cm-1)]: 280 (35,385). IR (in KBr, νmax/cm-1): 3860.42, 3414.54, 3080.94, 1612.23, 1548.55, 1481.39, 1253.06, 1182.67, 1072.72, 838.57, 806.33, 738.21. 1H NMR (DMSO-d6, δ/ppm): 9.96 (d, J = 4.7 Hz, 2H), 9.20 (dd, J = 31.3, 7.5 Hz, 2H), 8.70 (s, 2H), 8.32-8.06 (m, 2H), 7.37 (s, 2H), 6.32 (s, 6H). 13C NMR (126 MHz, DMSO) δ 156.04 (s), 153.65 (s), 145.34 (s), 131.84 (s), 128.64 (s), 127.96 (s), 88.70 (s). 6b: yield: 91.3%. ESI-MS (in MeOH): m/z 579.13 ([M -Cl]+). UV-visible in MeOH [λmax, nm (ε/M-1 cm-1)]: 290 (41,885). IR (in KBr, νmax/cm-1): 66.14, 3401.22, 3059.80, 1607.30, 1620.53, 1551.47, 1454.98, 1167.3, 851.02, 810.46, 722.48. 1H NMR (DMSO-d6, δ ppm): 9.91 (d, J = 4.7 Hz, 2H), 8.31 (t, J = 11.1 Hz, 2H), 8.13 (dd, J = 23.8, 15.5 Hz, 2H), 7.37 (s, 2H), 6.98 (d, J 8.7 Hz, 2H), 6.32 (s, 6H). 13C NMR (126 MHz, DMSO) δ 156.03 (s), 145.39 (s), 129.24 (s), 127.95 (s), 88.70 (s). 7b: yield: 89.8%. ESI-MS (in MeOH): m/z 590.9, ([M -Cl]+). UV-visible in MeOH [λmax, nm (ε/M-1 cm-1)]: 283 (46,320). IR (in KBr, νmax/cm-1): 3869.75, 3369.99, 3042.42, 1625.14, 1603.67, 1543.71, 1459.87, 1275.97, 1186.24, 1070.50, 722.92. 1H NMR (DMSO-d6, δ ppm) δ 9.93 (dd, J = 5.3, 1.1 Hz, 2H), 8.31 (d, J = 8.6 Hz, 2H), 8.18 (dd, J = 8.1, 5.5 Hz, 2H), 7.84 (d, J = 8.6 Hz, 2H), 7.34 (s, 2H), 6.30 (s, 6H). 13C NMR (126 MHz, DMSO) δ 150.45 (s), 133.93 (s), 131.31 (s), 130.17 (s), 127.35 (s), 124.51 (s), 88.59 (s).

References: [1]European Journal of Medicinal Chemistry,2013,vol. 63,p. 57 - 63.

5
[ 1121-60-4 ]
[ 37366-09-9 ]
[ 109903-35-7 ]
C₂₀H₂₁ClN₃O₂RuS⁽¹⁺⁾*Cl^(1-) [ No CAS ]