1091606-67-5|(1S,2S)-2-(Diphenylphosphino)-1,2-diphenylethanamine| Ambeed

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Quality Control of [ 1091606-67-5 ] Purity: 97% 98%ee SDS Specification

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Product Details of [ 1091606-67-5 ]

CAS No. :	1091606-67-5
Formula :	C₂₆H₂₄NP
M.W :	381.44
SMILES Code :	N[C@@H](C1=CC=CC=C1)[C@@H](P(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4
MDL No. :	MFCD11045444
InChI Key :	MIPGTOGPLXZBQX-UIOOFZCWSA-N
Pubchem ID :	46177587

Safety of [ 1091606-67-5 ]

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H315-H319-H335
Precautionary Statements:	P261-P305+P351+P338

Application In Synthesis of [ 1091606-67-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 1091606-67-5 ]

[ 1091606-67-5 ] Synthesis Path-Downstream 1~22

1
[ 37366-09-9 ]
[ 1091606-67-5 ]
(S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine) [ No CAS ]
C₇₀H₅₆Cl₂NP₃Ru [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		Tetrahydrofuran (20 ml) was added to a mixture of the S-binap ligand (0.5 g, 0.8 mmol) and [RuCl2(benzene)]2 (200 mg, 0.4 mmol), followed by DMF (0.5 ml) and the mixture refluxed for 6 hours under argon. The solvent was removed under reduced pressure and a solution of the aminophosphine (0.8 mmol) in toluene 20 added. The mixture was refluxed for 4 hours and the solvent removed under reduced pressure. Ether (10 ml) was then added and the mixture stirred for 2 hours under argon. The solids were filtered, washed with ether and dried under vacuum. The catalysts were

References: [1]Patent: WO2008/148202,2008,A1 .Location in patent: Page/Page column 55.

2
[ 1206227-48-6 ]
[ 1091606-67-5 ]

References: [1]Journal of Organic Chemistry,2010,vol. 75,p. 937 - 940.
[2]Organometallics,2014,vol. 33,p. 6452 - 6465.

3
[ 1091606-67-5 ]
[ 103-71-9 ]
[ 1220906-04-6 ]

References: [1]Dalton Transactions,2010,vol. 39,p. 1929 - 1931.

4
[ 1091606-67-5 ]
[ 1222630-38-7 ]

Yield	Reaction Conditions	Operation in experiment
60%	With tetrafluoroboric acid; In dichloromethane; water; at 20℃; for 0.5h;Inert atmosphere;	To a solution of <strong>[1091606-67-5](1S,2S)-2-(Diphenylphosphino)1,2-diphenylethylammine</strong> (0.091 g, 0.24 mmol) in CH2Cl2 (5 mL) was added an aqueous solution of HBF4 (0.033 mL, 48 wt %) dropwise via syringe. After stirring for 30 minutes at ambient temperature the organic layer was removed, dried over MgSO4, and then reduced to dryness leaving a white solid (1g). The solid was redissolved in CH2Cl2 (1 mL) and then hexanes was added to afford a white solid which was filtered off and dried in vacuo. Yield 0.067 g (60%). 1H NMR (300 MHz, CD2Cl2): d 4.48 (1br, 1H, CH), 4.68 (1br, 1H, CH), 6.50-7.92 (br m, 20H, Ar). 31P NMR (121.4 MHz, CD2Cl2): d -9.95 (s). 19F NMR (282.3 MHz, CD2Cl2): d -148.0(s).

References: [1]Patent: US2012/46479,2012,A1 .Location in patent: Page/Page column 10.

5
[ 23190-16-1 ]
[ 1091606-67-5 ]

References: [1]Organometallics,2014,vol. 33,p. 6452 - 6465.

6
[ 813459-59-5 ]
[ 1091606-67-5 ]

References: [1]Organometallics,2014,vol. 33,p. 6452 - 6465.

7
(4S,5R)-4,5-diphenyl-1,2,3-oxathiazolidine-3-carboxylic acid 1,1-dimethylethyl ester 2-oxide [ No CAS ]
[ 1091606-67-5 ]

References: [1]Organometallics,2014,vol. 33,p. 6452 - 6465.

8
[ 1091606-63-1 ]
[ 1091606-67-5 ]

References: [1]Organometallics,2014,vol. 33,p. 6452 - 6465.

9
[ 1091606-67-5 ]
[ 201230-82-2 ]
[ 143-66-8 ]
iron(II) bromide [ No CAS ]
C₅₃H₄₈BrFeN₂OP₂⁽¹⁺⁾*C₂₄H₂₀B^(1-) [ No CAS ]

References: [1]Organometallics,2014,vol. 33,p. 6452 - 6465.

10
[ 1091606-67-5 ]
[ 50777-76-9 ]
C₄₅H₃₇NP₂ [ No CAS ]

References: [1]Organometallics,2014,vol. 33,p. 6452 - 6465.

11
[ 1091606-67-5 ]
[cyclo(-P(i-Pr)2CH₂CH(OH)-)2](Br)2 [ No CAS ]
C₃₄H₄₁NP₂ [ No CAS ]

References: [1]Chemistry - A European Journal,2017,vol. 23,p. 7212 - 7216.

12
[ 1091606-67-5 ]
[cyclo(-PCy₂CH₂CH(OH)-)2](Br)2 [ No CAS ]
C₄₀H₄₉NP₂ [ No CAS ]

References: [1]Chemistry - A European Journal,2017,vol. 23,p. 7212 - 7216.

13
[ 1091606-67-5 ]
[ 40138-16-7 ]
[ 18531-99-2 ]
C₅₃H₃₉BNO₂P [ No CAS ]