Fmoc-D-Lys(Boc)-OH is a protected D-lysine derivative with the amino group protected by 9-fluorenylmethoxycarbonyl (Fmoc) and the side-chain amino group protected by tert-butoxycarbonyl (Boc), suitable for peptide synthesis.

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Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

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Quality Control of Fmoc-D-Lys(Boc)-OH Purity: 98% SDS Specification

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NMR

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CNMR

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Product Details of Fmoc-D-Lys(Boc)-OH

CAS No. :	92122-45-7
Formula :	C₂₆H₃₂N₂O₆
M.W :	468.54
SMILES Code :	O=C(O)[C@H](NC(OCC1C2=C(C3=C1C=CC=C3)C=CC=C2)=O)CCCCNC(OC(C)(C)C)=O
MDL No. :	MFCD00065660
InChI Key :	UMRUUWFGLGNQLI-JOCHJYFZSA-N
Pubchem ID :	13585941

Safety of Fmoc-D-Lys(Boc)-OH

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H302-H315-H319-H335
Precautionary Statements:	P261-P305+P351+P338

Application In Synthesis of Fmoc-D-Lys(Boc)-OH

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 92122-45-7 ]

[ 92122-45-7 ] Synthesis Path-Downstream 1~18

1
[ 501-81-5 ]
[ 5451-55-8 ]
[ 18942-49-9 ]
[ 92122-45-7 ]
C₃₃H₄₆N₅O₄Pol [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2013,vol. 56,p. 10103 - 10117.

2
[ 501-81-5 ]
[ 5451-55-8 ]
[ 92122-45-7 ]
[ 127095-92-5 ]
C₃₃H₅₂N₅O₄Pol [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2013,vol. 56,p. 10103 - 10117.

3
[ 4530-20-5 ]
[ 501-81-5 ]
[ 5451-55-8 ]
[ 92122-45-7 ]
C₂₆H₄₀N₅O₄Pol [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2013,vol. 56,p. 10103 - 10117.

4
[ 29022-11-5 ]
[ 35661-39-3 ]
C₃₇H₃₂NO₃PolS [ No CAS ]
[ 35661-40-6 ]
[ 71989-33-8 ]
[ 92122-45-7 ]
[ 71989-23-6 ]
[ 71989-26-9 ]
[ 35661-38-2 ]
[ 71989-33-8 ]
[ 104091-08-9 ]
Fmoc-protected derivative of His [ No CAS ]
H-Gly-Lys-D-His-Ser-D-Lys-Phe-D-Ala-Phe-D-Glu-Ile-D-Ser-Ala-NHC2H4SH [ No CAS ]

References: [1]ChemBioChem,2013,vol. 14,p. 2492 - 2499.

5
[ 27144-18-9 ]
[ 29022-11-5 ]
[ 68858-20-8 ]
[ 35661-39-3 ]
C₃₆H₃₀NO₃Pol [ No CAS ]
[ 35661-40-6 ]
[ 92122-45-7 ]
[ 35661-38-2 ]
[ 71989-33-8 ]
[ 104091-08-9 ]
Fmoc-protected derivatives of D-His and Met [ No CAS ]
SHC2H4CO-D-Ser-Met-D-Glu-Val-D-Ala-Gly-D-Lys-Ala-D-His-Phe-Gly-Gly-NHC2H4OH [ No CAS ]

References: [1]ChemBioChem,2013,vol. 14,p. 2492 - 2499.

6
[ 27144-18-9 ]
[ 29022-11-5 ]
[ 35661-39-3 ]
C₃₆H₃₀NO₃Pol [ No CAS ]
[ 35661-40-6 ]
[ 92122-45-7 ]
[ 71989-23-6 ]
[ 35661-38-2 ]
[ 104091-08-9 ]
SHC2H4CO-D-Ala-Ile-D-Lys-Phe-D-Ala-Gly-D-Lys-Ala-D-Glu-Ile-D-Lys-Ala-NHC2H4OH [ No CAS ]

References: [1]ChemBioChem,2013,vol. 14,p. 2492 - 2499.

7
[ 1865-01-6 ]
[ 29022-11-5 ]
[ 68858-20-8 ]
[ 35661-60-0 ]
[ 35661-39-3 ]
C₄₅H₄₁N₂O₇Pol [ No CAS ]
[ 92122-45-7 ]
[ 141-43-5 ]
[ 104091-08-9 ]
[ 84624-17-9 ]
[ 143824-78-6 ]
C₉₈H₁₃₇N₂₁O₁₉ [ No CAS ]

References: [1]ChemMedChem,2015,vol. 10,p. 540 - 545.

8
[ 198544-94-4 ]
C₁₉H₁₆NO₅Pol [ No CAS ]
[ 35661-39-3 ]
[ 40138-16-7 ]
[ 92122-45-7 ]
[ 71989-14-5 ]
[ 104091-08-9 ]
H-Asp-Glu-Ala-Ala-Lys(PBA)-Ala-Ala-Lys-Asp-OH [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
49%		General procedure: Peptides were synthesized using standard, Fmoc-based, solid-phase protocols on a Liberty Microwave Peptide Synthesizer (CEM Corporation). The peptides Fmoc-Phe-Phe-Wang resin, Fmoc-Phe-Phe-RinkAmide AM resin, and Fmoc-Asp(OtBu)-Glu(OtBu)-(Ala)2-Lys(Mtt)-(Ala)2-Lys(Boc)-Asp(OtBu)-Wangresin were assembled from C-terminus to N-terminus on 0.1 mmol or 0.25 mmol scales using Fmoc-Phe-Wang resin, RinkAmide AM resin, and Fmoc-Asp(OtBu)- , respectively. Fmoc deprotection was accomplished using a 0.1 M solution of HOBt in 20:80 (vol:vol) piperidine:DMF. The resin was treated with two cycles of deprotect solution at 75 C for 180 s. Fmoc-protected amino acids were coupled to the deprotected amine ofthe resin-bound peptide using 5 eq. amino acid, 4.5 eq. HBTU, and 10 eq. DIEA relative to the resin loading. Each coupling reaction was conducted at 75 C for 180 s. The amino acids, HBTU, and DIEA were utilized as 0.2 M solutions in DMF, a 0.5 M solution in HBTU, and a 2 M solution in NMP, respectively.

References: [1]Tetrahedron Letters,2015,vol. 56,p. 5731 - 5734.

9
[ 29022-11-5 ]
[ 92122-45-7 ]
[ 35661-38-2 ]
[ 35661-60-0 ]
[ 86123-10-6 ]
[ 71989-33-8 ]
[ 71989-28-1 ]
[ 71989-14-5 ]
[ 104091-08-9 ]
[ 71989-31-6 ]
[ 84624-17-9 ]
N_α-fmoc-N_(im)-trityl-D-histidine [ No CAS ]
1-tert-butoxycarbonyl-N-[(9-fluorenyl)methoxycarbonyl]-D-tryptophan [ No CAS ]
(R)-2-(9H-Fluoren-9-ylmethoxycarbonylamino)-N-trityl-succinamic acid [ No CAS ]
N-FMOC-O-tert-butyl-D-threonine [ No CAS ]
Fmoc-D-Gln(Trt)-OH [ No CAS ]
N-α-[(9H-fluoren-9-ylmethoxy)carbonyl]-N^G-(2,2,4,6,7-pentamethyldihydrobenzofuran-5-sulfonyl)-D-arginine [ No CAS ]
lsdedfkavfGmtrsafanlplwkqqhlkkekGlf; lower case letters = D-amino acid residues [ No CAS ]