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Quality Control of [ 64443-05-6 ]

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Product Details of [ 64443-05-6 ]

CAS No. :	64443-05-6	MDL No. :	MFCD00064810
Formula :	C₈H₁₂CuF₆N₄P	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	GNQXUMGHBSAQBV-UHFFFAOYSA-N
M.W :	372.72	Pubchem ID :	11068737
Synonyms :

Safety of [ 64443-05-6 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313	UN#:	N/A
Hazard Statements:	H315-H319	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 64443-05-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 64443-05-6 ]

[ 64443-05-6 ] Synthesis Path-Downstream 1~88

1
[ 64443-05-6 ]
[ 3002-77-5 ]
[ 889663-63-2 ]

Reference： [1]Dalton Transactions,2006,p. 2058 - 2065
[2]Inorganic Chemistry,2003,vol. 42,p. 255 - 257
[3]Electrochimica Acta,2014,vol. 141,p. 324 - 330
[4]Inorganic Chemistry,2019,vol. 58,p. 16800 - 16817

2
[ 64443-05-6 ]
[ 56100-22-2 ]
[ 889663-76-7 ]

Reference： [1]Dalton Transactions,2011,vol. 40,p. 12584 - 12594
[2]Inorganic Chemistry,2003,vol. 42,p. 255 - 257
[3]Dalton Transactions,2006,p. 2058 - 2065

3
[ 64443-05-6 ]
Ru₄H₂^(2-)*12CO*2N(P(C₆H₅)3)2⁽¹⁺⁾=(N(P(C₆H₅)3)2)2(Ru₄H₂(CO)12) [ No CAS ]
[ 19845-69-3 ]
Cu₂Ru₄H₂((C₆H₅)2P(CH₂)6P(C₆H₅)2)(CO)12 [ No CAS ]

Reference： [1]Journal of the Chemical Society. Chemical communications,1985,p. 1439 - 1441

4
[ 64443-05-6 ]
Ru₄H₂^(2-)*12CO*2N(P(C₆H₅)3)2⁽¹⁺⁾=(N(P(C₆H₅)3)2)2(Ru₄H₂(CO)12) [ No CAS ]
[ 27721-02-4 ]
Cu₂Ru₄H₂((C₆H₅)2P(CH₂)5P(C₆H₅)2)(CO)12 [ No CAS ]

Reference： [1]Journal of the Chemical Society. Chemical communications,1985,p. 1439 - 1441

5
[ 64443-05-6 ]
Ru₄H₂^(2-)*12CO*2N(P(C₆H₅)3)2⁽¹⁺⁾=(N(P(C₆H₅)3)2)2(Ru₄H₂(CO)12) [ No CAS ]
[ 19845-69-3 ]
{Cu2Ru4(μ3-H)2(μ-Ph2P(CH2)6PPh2)(CO)12} [ No CAS ]

Reference： [1]Journal of the Chemical Society, Dalton Transactions,1988,p. 757 - 768

6
[ 64443-05-6 ]
Ru₄H₂^(2-)*12CO*2N(P(C₆H₅)3)2⁽¹⁺⁾=(N(P(C₆H₅)3)2)2(Ru₄H₂(CO)12) [ No CAS ]
[ 27721-02-4 ]
1,2-μ-{1',5'-bis(diphenylphosphino)pentane}-3,3,3,4,4,4,5,5,5,6,6,6-dodecacarbonyl-1,3,5;1,4,5-di-μ-hydrido-cyclo-1,2-dicopper-3,4,5,6-tetraruthenium (Cu-Cu)(5 Cu-Ru)(6 Ru-Ru) [ No CAS ]

Reference： [1]Journal of the Chemical Society, Dalton Transactions,1988,p. 757 - 768

7
[ 254-60-4 ]
[ 64443-05-6 ]
bis(1,8-naphthyridine)(carbon monoxide)bis(acetonitrile)dicopper(I) dihexafluorophosphate [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1990,vol. 167,p. 181 - 188

8
[ 64443-05-6 ]
[ 131833-89-1 ]
(Cu(biox)2)PF₆ [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1991,vol. 179,p. 155 - 156

9
[ 64443-05-6 ]
[ 4733-39-5 ]
[ 47895-81-8 ]

Reference： [1]Inorganic Chemistry,1996,vol. 35,p. 6406 - 6412
[2]Dalton Transactions,2018,vol. 47,p. 4959 - 4967
[3]Electrochimica Acta,2014,vol. 141,p. 324 - 330

10
[ 64443-05-6 ]
[ 19845-69-3 ]
[Cu(1,4-bis(diphenylphosphino)hexane)2(μ-PF2O2)2] [ No CAS ]

Reference： [1]Inorganic Chemistry,1995,vol. 34,p. 1455 - 1465
Inorg. Chem.,

11
[ 64443-05-6 ]
[ 123640-38-0 ]
[Cu(C₁₁H₉N₅)]2⁽²⁺⁾*2PF₆^(1-) = [Cu(C₁₁H₉N₅)]2(PF₆)2 [ No CAS ]

Reference： [1]Journal of the Chemical Society, Dalton Transactions,1999,p. 521 - 523

12
[ 254-60-4 ]
[ 64443-05-6 ]
[ 2071-20-7 ]
[Cu₂(1,8-naphthyridine)2(bis(diphenylphosphino)methane)(MeCN)](PF₆)2 [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1998,vol. 271,p. 129 - 136

13
[ 254-60-4 ]
[ 64443-05-6 ]
[ 67-64-1 ]
[Cu₂(1,8-naphthyridine)2(Me₂CO)](PF₆)2 * 2 Me₂CO [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1998,vol. 271,p. 129 - 136

14
[ 64443-05-6 ]
[ 23593-75-1 ]
[Cu(1-[(2-chlorophenyl)diphenylmethyl]-1H-imidazole)2]PF₆ [ No CAS ]

Reference： [1]Inorganica Chimica Acta,1998,vol. 275-276,p. 528 - 540

15
[ 230-07-9 ]
[ 64443-05-6 ]
[Cu(4,7-phenanthroline)(acetonitrile)2]PF₆ [ No CAS ]

Reference： [1]Inorganic Chemistry,1999,vol. 38,p. 1883 - 1888

16
[ 64443-05-6 ]
[Pt3(μ-CNXyl)2(μ-CO)(CNXyl)(PCy3)2] [ No CAS ]
[ 1179-06-2 ]
[(1,4-(CuPPh2)2C6H4)(Pt3(μ2-CO)(μ2-CNXyl)2(CNXyl)(PCy3)2)2][PF6]2 [ No CAS ]

Reference： [1]Inorganic Chemistry,1997,vol. 36,p. 1813 - 1820

17
[ 64443-05-6 ]
Pt₃(CO)3(tricyclohexylphosphine)3 [ No CAS ]
[ 1179-06-2 ]
[(1,4-(CuPPh2)2C6H4)(Pt3(μ2-CO)3(PCy3)3)2][PF6]2 [ No CAS ]

Reference： [1]Inorganic Chemistry,1997,vol. 36,p. 1813 - 1820

18
[ 64443-05-6 ]
[ 1071-06-3 ]
[ 5197-95-5 ]
[ 809234-43-3 ]

Reference： [1]Inorganica Chimica Acta,2004,vol. 357,p. 3950 - 3956

19
[ 64443-05-6 ]
[ 1618-26-4 ]
[Cu(n)(MeSCH₂SMe)2n](PF₆)n [ No CAS ]

Reference： [1]Inorganic Chemistry,1996,vol. 35,p. 4432 - 4438

20
[ 64443-05-6 ]
[ 484-11-7 ]
[ 27721-02-4 ]
[ 914370-27-7 ]

Reference： [1]Dalton Transactions,2006,p. 4444 - 4448

21
[ 64443-05-6 ]
[ 118949-61-4 ]
[Cu(2,6-bis[4'-(S)-isopropyloxazolin-2'-yl]pyridine)2][PF₆] [ No CAS ]

Reference： [1]Inorganic Chemistry,2009,vol. 48,p. 11147 - 11160
[2]Inorganic Chemistry,2006,vol. 45,p. 10043 - 10045

22
[ 64443-05-6 ]
[ 118949-61-4 ]
[dicopper(I)(2,6-bis[4'-(S)-isopropyloxazolin-2'-yl]pyridine)2](hexafluorophosphate)2 [ No CAS ]

Reference： [1]Inorganic Chemistry,2006,vol. 45,p. 10043 - 10045

23
[ 64443-05-6 ]
[ 128249-70-7 ]
[Cu(2,6-bis[4'-(R)-phenyloxazolin-2'-yl]pyridine)2][PF₆] [ No CAS ]

Reference： [1]Inorganic Chemistry,2006,vol. 45,p. 10043 - 10045
[2]Inorganic Chemistry,2009,vol. 48,p. 11147 - 11160

24
[ 64443-05-6 ]
[ 128249-70-7 ]
[Cu₂((R,R)-Ph-pybox)2][PF₆]2 [ No CAS ]

Reference： [1]Inorganic Chemistry,2006,vol. 45,p. 10043 - 10045

25
[ 64443-05-6 ]
[ 4241-27-4 ]
[ 175480-83-8 ]

Reference： [1]Journal of the American Chemical Society,1996,vol. 118,p. 3117 - 3124

26
[ 64443-05-6 ]
[ 4241-27-4 ]
[ 178265-35-5 ]

Reference： [1]Journal of the Chemical Society, Dalton Transactions,1996,p. 2031 - 2037

27
[ 254-60-4 ]
[ 64443-05-6 ]
[ 166330-10-5 ]
[ 1115239-87-6 ]

Reference： [1]Inorganic Chemistry Communications,2007,vol. 10,p. 1473 - 1477

28
[ 64443-05-6 ]
[ 117330-40-2 ]
[ 1173294-21-7 ]

Reference： [1]Chemical Communications,2008,p. 3717 - 3719

29
[ 39621-11-9 ]
[ 64443-05-6 ]
[ 13680-35-8 ]
2C₃₅H₄₀N₄O₂*2Cu⁽¹⁺⁾*2F₆P^(1-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
36%		6-Hydroxymethylpyridine-2-carboxaldehyde (0.137 g, 1.0 mmol) was dissolved in dry methanol (15 ml) with 4,4' methylene bis 2,6 diethyl aniline (0.155 g, 0.5 mmol). The pale yellow solution was left stirring at room temperature under nitrogen for 30 min. Then [Cu(MeCN)4][PF6] (0.018 g, 0.5 mmol) dissolved in dry methanol (5 ml) was added to the solution under a blanket of nitrogen. The solution, which quickly becomes red-brown in colour, was stirred at room temperature under nitrogen for 15 hours. The red-brown solid which precipitated was filtered off under vacuum and washed with diethyl ether (2 cm3). The product was dried under vacuum over P2O5 to constant weight. (0.27 g, 36%) Positive-ion FAB: m/z 1369 ([Cu2(L4)2(PF6)]+), 1224 ([Cu2(L4)2]+) 1H NMR (CD2Cl2, 400 MHz, 298K) : d 8.50 (1H, s, Him), 8.26 (1H, t, J=7.8 Hz, H4), 8.12 (1H, d, J=7.8 Hz, H3), 7.89 (1H, d, J=7.8 Hz, H5), 7.14 (1H, s, HPh), 6. 58 (1H, s, HPh), 4.35 (1H, dd, J=14.1, 4.1 Hz CH2OH), 3.95 (1H, br d, J=13.8 Hz CH2OH), 3.92 (1H, s, CH2spacer), 3.07 (1H, br s, OH) 2.59 (2H, m, CH2Me), 1.91 (2H, m, CH2Me), 1.03 (3H, t, J=7.4 Hz, Me), 0.64 (3H, t, J=7.3 Hz, Me) ppm. lmax/nm (MeCN) 466 (e/mol-1dm-3cm-1 3x104) MLCT nmax/cm-1 3500-3000w, 2962m, 1615m, 1583m, 1461m, 1428m, 1399m, 1339m, 1316m, 1194m, 1140m, 1083m, 1003m, 979m, 920m, 880m, 844s, 789m, 735m, 648M, 607m

Reference： [1]Patent: WO2005/33119,2005,A1 .Location in patent: Page/Page column 20

30
[ 64443-05-6 ]
[ 75-09-2 ]
[ 118949-61-4 ]
[Cu₂(2,6-bis[4'-(S)-isopropyloxazolin-2'-yl]pyridine)2][PF₆]2*CH₂Cl₂ [ No CAS ]

Reference： [1]Inorganic Chemistry,2009,vol. 48,p. 11147 - 11160

31
[ 64443-05-6 ]
[ 75-09-2 ]
[ 128249-70-7 ]
[Cu₂(2,6-bis[4'-(R)-phenyloxazolin-2'-yl]pyridine)2][PF₆]2*CH₂Cl₂ [ No CAS ]

Reference： [1]Inorganic Chemistry,2009,vol. 48,p. 11147 - 11160

32
[ 64443-05-6 ]
[ 33527-91-2 ]
[ 201230-82-2 ]
[ 1240262-10-5 ]

Reference： [1]Inorganic Chemistry,2010,vol. 49,p. 7521 - 7529

33
[ 64443-05-6 ]
[ 1245-13-2 ]
[Cu(bicinchoninic acid^(2-))₂]^3- [ No CAS ]

Reference： [1]Inorganic Chemistry,2011,vol. 50,p. 1378 - 1391

34
[ 64443-05-6 ]
mb-Met [ No CAS ]
[ 1245-13-2 ]
[Cu(bicinchoninic acid^(2-))₂]^3- [ No CAS ]
Cu((CH₃)2CHCH₂COC₃NO₂CSNHCH₂CONHCH(CH₂OH)CONHC₁₇H₁₈O₅N₅S₃(CH₂C₆H₄OH)(CH₂OH)COO)^(2-) [ No CAS ]

Reference： [1]Inorganic Chemistry,2011,vol. 50,p. 1378 - 1391

35
[ 64443-05-6 ]
FL-mb [ No CAS ]
[ 1245-13-2 ]
[Cu(bicinchoninic acid^(2-))₂]^3- [ No CAS ]
Cu((CH₃)2CHCH₂COC₃NO₂CSNHCH₂CONHCH(CH₂OH)CONHC₁₇H₁₈O₅N₅S₃(CH₂C₆H₄OH)(CH₂OH)CONHCH(COO)CH₂CH₂SCH₃)^(2-) [ No CAS ]

Reference： [1]Inorganic Chemistry,2011,vol. 50,p. 1378 - 1391

36
[ 3973-08-8 ]
[ 64443-05-6 ]
[ 1270159-30-2 ]

Reference： [1]European Journal of Inorganic Chemistry,2011,p. 539 - 548

37
[ 64443-05-6 ]
[ 4062-60-6 ]
[ 3383-21-9 ]
(N₁,N₂-di-tert-butylethane-1,2-diamine)(3,5-di-tert-butylsemiquinone)copper(II) hexafluorophosphate [ No CAS ]

Reference： [1]Inorganic Chemistry,2011,vol. 50,p. 9816 - 9825

38
[ 64443-05-6 ]
[ 850566-91-5 ]
[ 1179-06-2 ]
[(Au₃Cu₂(C₂C₆H₄-4-NH₂)6)Au₃(1,4-bis(diphenylphosphino)benzene)3](PF₆)2 [ No CAS ]

Reference： [1]Dalton Transactions,2010,vol. 39,p. 2676 - 2683

39
[ 64443-05-6 ]
[ 1224188-78-6 ]
[ 1179-06-2 ]
[(Au₃Cu₂(C₂C₆H₄-3-NH₂)6)Au₃(1,4-bis(diphenylphosphino)benzene)3](PF₆)2 [ No CAS ]

Reference： [1]Dalton Transactions,2010,vol. 39,p. 2676 - 2683

40
[ 26042-63-7 ]
[ 64443-05-6 ]
[ 1179-06-2 ]
silver(I) (4-methoxyphenyl)acetylide [ No CAS ]
8Ag⁽¹⁺⁾*2Cu⁽¹⁺⁾*6C₂C₆H₄OCH₃^(1-)*6(C₆H₅)2PC₆H₄P(C₆H₅)2*4PF₆^(1-)=Ag₈Cu₂(C₆H₄OCH₃C₂)6((C₆H₅)2PC₆H₄P(C₆H₅)2)6(PF₆)4 [ No CAS ]

Reference： [1]Dalton Transactions,2010,vol. 39,p. 2395 - 2403

41
[ 26042-63-7 ]
[ 64443-05-6 ]
[ 1179-06-2 ]
silver(I) [4-(dimethylamino)phenyl]acetylide [ No CAS ]
8Ag⁽¹⁺⁾*2Cu⁽¹⁺⁾*6C₂C₆H₄N(CH₃)2^(1-)*6(C₆H₅)2PC₆H₄P(C₆H₅)2*4PF₆^(1-)=Ag₈Cu₂(C₆H₄N(CH₃)2C₂)6((C₆H₅)2PC₆H₄P(C₆H₅)2)6(PF₆)4 [ No CAS ]

Reference： [1]Dalton Transactions,2010,vol. 39,p. 2395 - 2403
[2]Dalton Transactions,2010,vol. 39,p. 2395 - 2403

42
[ 26042-63-7 ]
[ 64443-05-6 ]
[ 33440-88-9 ]
[ 1179-06-2 ]
8Ag⁽¹⁺⁾*2Cu⁽¹⁺⁾*6C₆H₅C₂^(1-)*6(C₆H₅)2PC₆H₄P(C₆H₅)2*4PF₆^(1-)=Ag₈Cu₂(C₆H₅C₂)6((C₆H₅)2PC₆H₄P(C₆H₅)2)6(PF₆)4 [ No CAS ]

Reference： [1]Dalton Transactions,2010,vol. 39,p. 2395 - 2403

43
[ 64443-05-6 ]
[ 4129-44-6 ]
[Cu₂(4,4'-bis(diphenylphosphino)biphenylene)2(MeCN)4][BF₄]2 [ No CAS ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2012,vol. 638,p. 415 - 422

44
[ 64443-05-6 ]
[ 1179-06-2 ]
[Cu2(μ-1,4-bis(diphenylphosphino)benzene)2(acetonitrile)4](BF4)2 [ No CAS ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2012,vol. 638,p. 415 - 422

45
[ 64443-05-6 ]
[ 4733-39-5 ]
[ 166330-10-5 ]
[ 1421057-27-3 ]

Reference： [1]Organic Letters,2017,vol. 19,p. 3576 - 3579
[2]Chimia,2018,vol. 72,p. 621 - 629
[3]Angewandte Chemie - International Edition,2013,vol. 52,p. 419 - 423
Angew. Chem.,2013,vol. 125,p. 437 - 441,5
[4]Journal of the American Chemical Society,2016,vol. 138,p. 4354 - 4357

46
[ 12150-46-8 ]
[ 64443-05-6 ]
[ 4733-39-5 ]
[ 1421057-32-0 ]