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Chemical Structure| 1222630-38-7 Chemical Structure| 1222630-38-7

Structure of 1222630-38-7

Chemical Structure| 1222630-38-7

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Product Details of [ 1222630-38-7 ]

CAS No. :1222630-38-7
Formula : C26H25BF4NP
M.W : 469.26
SMILES Code : [NH3+][C@@H](C1=CC=CC=C1)[C@@H](P(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.F[B-](F)(F)F

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Application In Synthesis of [ 1222630-38-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1222630-38-7 ]

[ 1222630-38-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1091606-67-5 ]
  • [ 1222630-38-7 ]
YieldReaction ConditionsOperation in experiment
60% With tetrafluoroboric acid; In dichloromethane; water; at 20℃; for 0.5h;Inert atmosphere; To a solution of <strong>[1091606-67-5](1S,2S)-2-(Diphenylphosphino)1,2-diphenylethylammine</strong> (0.091 g, 0.24 mmol) in CH2Cl2 (5 mL) was added an aqueous solution of HBF4 (0.033 mL, 48 wt %) dropwise via syringe. After stirring for 30 minutes at ambient temperature the organic layer was removed, dried over MgSO4, and then reduced to dryness leaving a white solid (1g). The solid was redissolved in CH2Cl2 (1 mL) and then hexanes was added to afford a white solid which was filtered off and dried in vacuo. Yield 0.067 g (60%). 1H NMR (300 MHz, CD2Cl2): d 4.48 (1br, 1H, CH), 4.68 (1br, 1H, CH), 6.50-7.92 (br m, 20H, Ar). 31P NMR (121.4 MHz, CD2Cl2): d -9.95 (s). 19F NMR (282.3 MHz, CD2Cl2): d -148.0(s).
 

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