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Chemical Structure| 13675-18-8 Chemical Structure| 13675-18-8
Chemical Structure| 13675-18-8

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Synonyms: Hypodiboric acid

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Product Citations

Product Citations

Lim, Taeho ; Ryoo, Jeong Yup ; Han, Min Su ;

Abstract: In this study, we developed a simple transition-metal-free borylation reaction of aryl bromides. Bis-boronic acid (BBA), was used, and the borylation reaction was performed using a simple procedure at a mild temperature. Under mild conditions, aryl bromides were converted to arylboronic acids directly without any deprotection steps and purified by conversion to trifluoroborate salts. The functional group tolerance was considerably high. The mechanism study suggested that this borylation reaction proceeds via a radical pathway.

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Product Details of Tetrahydroxydiboron

CAS No. :13675-18-8
Formula : B2H4O4
M.W : 89.65
SMILES Code : OB(O)B(O)O
Synonyms :
Hypodiboric acid
MDL No. :MFCD05663888
InChI Key :SKOWZLGOFVSKLB-UHFFFAOYSA-N
Pubchem ID :10986154

Safety of Tetrahydroxydiboron

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302+H332-H315-H319-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312+P330-P302+P352-P304+P340+P312-P305+P351+P338-P332+P313-P337+P313-P403+P233-P405-P501

Application In Synthesis of Tetrahydroxydiboron

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 13675-18-8 ]
  • Downstream synthetic route of [ 13675-18-8 ]

[ 13675-18-8 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 1279123-63-5 ]
  • [ 13675-18-8 ]
  • [ 108-43-0 ]
  • [ 871231-45-7 ]
References: [1] Journal of the American Chemical Society, 2012, vol. 134, # 28, p. 11667 - 11673.
 

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