Home Cart 0 Sign in  

[ CAS No. 89490-05-1 ]

{[proInfo.proName]} ,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 89490-05-1
Chemical Structure| 89490-05-1
Structure of 89490-05-1 * Storage: {[proInfo.prStorage]}

Quality Control of [ 89490-05-1 ]

Related Doc. of [ 89490-05-1 ]

SDS
Alternatived Products of [ 89490-05-1 ]
Alternatived Products of [ 89490-05-1 ]

Product Details of [ 89490-05-1 ]

CAS No. :89490-05-1 MDL No. :MFCD02179497
Formula : C6H11BO2 Boiling Point : 261.9°C at 760 mmHg
Linear Structure Formula :- InChI Key :N/A
M.W :125.96 g/mol Pubchem ID :3862902
Synonyms :

Safety of [ 89490-05-1 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P280-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H332-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 89490-05-1 ]

  • Upstream synthesis route of [ 89490-05-1 ]
  • Downstream synthetic route of [ 89490-05-1 ]

[ 89490-05-1 ] Synthesis Path-Upstream   1~5

  • 1
  • [ 2044-08-8 ]
  • [ 1195-66-0 ]
  • [ 89490-05-1 ]
YieldReaction ConditionsOperation in experiment
81% With iodine; magnesium In tetrahydrofuran at 40 - 55℃; Inert atmosphere Under the protection of nitrogen, adding magnesium metal in the reaction bottle 8.0g (0.33mol) and several grain of iodines, prior to dropping funnel in the uniformly mixed methoxy boronic acid frequency that alcohol ester 56.9g (0.36mol), cyclohexene-1-polybromide 48.3g (0.3mol) and anhydrous tetrahydrofuran 300 ml, the temperature rising to outside bath 40-45 degrees, to a first 25 ml mixed solution, after color treats the iodine triggered evanishment standard, the oven-keeping 40-55 degrees between the completion of the dropping of the remaining mixed solution, then subsequently gradually heated up to reflow to continue reaction 2-3 hours, disappearance of the raw material after detection GC, to the reaction liquid 0-10 degree, slowly adding saturated NH4Cl quenching, adjusting for PH 5-6, separating the organic layer, the water layer using MTBE 150 ml extraction a, combined with the organic layer, the saturated salt water washing, solvent evaporation to dryness of the organic layer is concentrated under reduced pressure, then replace the high vacuum pump, collecting 80-83 °C fraction, get colorless transparent liquid 50.5g, yield 81percent
Reference: [1] Patent: CN104788481, 2016, B, . Location in patent: Paragraph 0024
  • 2
  • [ 212127-64-5 ]
  • [ 89490-05-1 ]
Reference: [1] Journal of the American Chemical Society, 1998, vol. 120, # 31, p. 7995 - 7996
  • 3
  • [ 141091-37-4 ]
  • [ 89490-05-1 ]
Reference: [1] Angewandte Chemie - International Edition, 2012, vol. 51, # 31, p. 7799 - 7803
  • 4
  • [ 18448-47-0 ]
  • [ 89490-05-1 ]
Reference: [1] Patent: CN104788481, 2016, B,
  • 5
  • [ 89490-05-1 ]
  • [ 1230487-00-9 ]
Reference: [1] Patent: WO2013/113915, 2013, A1,
[2] Patent: WO2013/113915, 2013, A1,
[3] Patent: WO2017/120124, 2017, A1,
Historical Records

Related Functional Groups of
[ 89490-05-1 ]

Alkenyls

Chemical Structure| 850036-28-1

[ 850036-28-1 ]

Cyclopent-1-en-1-ylboronic acid

Similarity: 0.94

Chemical Structure| 141091-37-4

[ 141091-37-4 ]

2-(Cyclohex-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Similarity: 0.62

Chemical Structure| 1310384-24-7

[ 1310384-24-7 ]

4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)cyclohex-3-enol

Similarity: 0.61

Chemical Structure| 859217-67-7

[ 859217-67-7 ]

2-(4,4-Dimethyl-1-cyclohexen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Similarity: 0.61

Chemical Structure| 859217-85-9

[ 859217-85-9 ]

4,4,5,5-Tetramethyl-2-(3,3,5,5-tetramethylcyclohex-1-en-1-yl)-1,3,2-dioxaborolane

Similarity: 0.60

Organoboron

Chemical Structure| 850036-28-1

[ 850036-28-1 ]

Cyclopent-1-en-1-ylboronic acid

Similarity: 0.94

Chemical Structure| 40276-63-9

[ 40276-63-9 ]

(2-Benzylphenyl)boronic acid

Similarity: 0.68

Chemical Structure| 90002-36-1

[ 90002-36-1 ]

2-Ethylphenylboronic acid

Similarity: 0.67

Chemical Structure| 103986-53-4

[ 103986-53-4 ]

4-Methyl-1-naphthaleneboronic acid

Similarity: 0.65

Chemical Structure| 1373393-41-9

[ 1373393-41-9 ]

(2-Cyclopropylphenyl)boronic acid

Similarity: 0.65

Aliphatic Cyclic Hydrocarbons

Chemical Structure| 850036-28-1

[ 850036-28-1 ]

Cyclopent-1-en-1-ylboronic acid

Similarity: 0.94

Chemical Structure| 141091-37-4

[ 141091-37-4 ]

2-(Cyclohex-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Similarity: 0.62

Chemical Structure| 1310384-24-7

[ 1310384-24-7 ]

4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)cyclohex-3-enol

Similarity: 0.61

Chemical Structure| 859217-67-7

[ 859217-67-7 ]

2-(4,4-Dimethyl-1-cyclohexen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Similarity: 0.61

Chemical Structure| 859217-85-9

[ 859217-85-9 ]

4,4,5,5-Tetramethyl-2-(3,3,5,5-tetramethylcyclohex-1-en-1-yl)-1,3,2-dioxaborolane

Similarity: 0.60

Organoboron

Chemical Structure| 850036-28-1

[ 850036-28-1 ]

Cyclopent-1-en-1-ylboronic acid

Similarity: 0.94

Chemical Structure| 40276-63-9

[ 40276-63-9 ]

(2-Benzylphenyl)boronic acid

Similarity: 0.68

Chemical Structure| 90002-36-1

[ 90002-36-1 ]

2-Ethylphenylboronic acid

Similarity: 0.67

Chemical Structure| 103986-53-4

[ 103986-53-4 ]

4-Methyl-1-naphthaleneboronic acid

Similarity: 0.65

Chemical Structure| 1373393-41-9

[ 1373393-41-9 ]

(2-Cyclopropylphenyl)boronic acid

Similarity: 0.65