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Chemical Structure| 7613-19-6 Chemical Structure| 7613-19-6

Structure of 7613-19-6

Chemical Structure| 7613-19-6

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Product Details of [ 7613-19-6 ]

CAS No. :7613-19-6
Formula : C9H6N2O3
M.W : 190.16
SMILES Code : O=[N+](C1=CC=CC2=[N+]([O-])C=CC=C12)[O-]
MDL No. :MFCD00234499
InChI Key :CMZRGZILWKLDMH-UHFFFAOYSA-N
Pubchem ID :82085

Safety of [ 7613-19-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302+H312+H332-H350
Precautionary Statements:P501-P261-P270-P202-P201-P271-P264-P280-P308+P313-P362+P364-P301+P312+P330-P302+P352+P312-P304+P340+P312-P405
Class:6.1
UN#:2811
Packing Group:

Application In Synthesis of [ 7613-19-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 7613-19-6 ]

[ 7613-19-6 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 7613-19-6 ]
  • [ 13067-94-2 ]
YieldReaction ConditionsOperation in experiment
42% With trichlorophosphate; for 3.0h;Cooling with ice; Reflux; Synthesis of 79 To 78 (4.94 g, 26 mmol), phosphorus oxyschloride (22 ml) was added dropwise under ice cooling and stirring, and the mixture was heated at reflux for 3 hours. The reaction solution was ice-cooled and ice water was added, and then the solution was made basic with ammonia water and extracted with chloroform. The extraction liquid was washed with saturated saline and dried, and then the solvent was distilled off under reduced pressure. The residue was purified by silica gel flash column chromatography (eluting solvent: n-hexane/methylene chloride = 2/1, 1/1, 1/2) and then washed with n-hexane to obtain 79 (2.25 g, 42%) as a pale yellow solid. APCI-MS m/z 209/211[M+H]+
 

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