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Chemical Structure| 716-53-0 Chemical Structure| 716-53-0

Structure of 9-Chloroanthracene
CAS No.: 716-53-0

Chemical Structure| 716-53-0

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Product Details of [ 716-53-0 ]

CAS No. :716-53-0
Formula : C14H9Cl
M.W : 212.67
SMILES Code : ClC1=C2C=CC=CC2=CC2=C1C=CC=C2
MDL No. :MFCD00001245
InChI Key :KULLJOPUZUWTMF-UHFFFAOYSA-N
Pubchem ID :69744

Safety of [ 716-53-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302
Precautionary Statements:P280-P305+P351+P338

Application In Synthesis of [ 716-53-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 716-53-0 ]

[ 716-53-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 716-53-0 ]
  • [ 62-53-3 ]
  • [ 15424-38-1 ]
YieldReaction ConditionsOperation in experiment
85% With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; for 2h;Reflux; Tri-tert-butylphosphine (3 mL of a 1.0 M solution in toluene, 7.32 mmol), palladium acetate (0.4 g, 1.83 mmol) and sodium tert- butoxide (22.8 g, 238 mmol) were added to 9- chloroanthracene ) And aniline (17.0 g, 183 mmol) in degassed toluene (500 mL) and the mixture heated at reflux for 2 h. The reaction mixture was cooled to room temperature, diluted with toluene and passed through diatomsSoil filtration. The filtrate was diluted with water and extracted with toluene, and the organic phases were combined and carried under vacuum evaporation. This residue was filtered through silica gel and recrystallized to give Intermediate A-1 (41.8 g, yield 85%).
 

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