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Chemical Structure| 70069-04-4 Chemical Structure| 70069-04-4

Structure of 2-Hydroxymethyl-18-crown-6
CAS No.: 70069-04-4

Chemical Structure| 70069-04-4

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Gaurav K. Pande ; Brian P. Radka ; Joselle M. McCracken ; Timothy J. White ;

Abstract: The selective reflection inherent to the cholesteric liquid crystal (CLC) phase (in the planar orientation) can be tuned or broadened by the incorporation of polymer stabilizing networks (PSCLC). Prior reports detail that the mechanism is ion-mediated deformation of the polymer stabilizing network, which retains structural chirality. The structural chirality of the polymer stabilizing effectively overpowers the chirality of the CLC mixture. Here, we incorporate monomers containing groups known to trap cationic metal halide ions, into the polymer stabilizing network. Specifically, we incorporate monofunctional control monomers as well as monofunctional acrylate monomers 4-acryloxyhexylterpyridine (TPy-Ac), 4-((6-(acryloyloxy)hexyl)oxy)benzoic-15-crown-5 (OBA-15C5), and 4-((6-(acryloyloxy)hexyl)oxy)benzoic-18-crown-6 (OBA-18C6). The electro-optic response is enhanced only by the inclusion of OBA-15C5 which previously has been shown to selectively trap and interact with sodium (Na+) ions.

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Product Details of [ 70069-04-4 ]

CAS No. :70069-04-4
Formula : C13H26O7
M.W : 294.34
SMILES Code : OCC1OCCOCCOCCOCCOCCOC1
MDL No. :MFCD00188046
InChI Key :HFRGASADQCZXHH-UHFFFAOYSA-N
Pubchem ID :3611393

Safety of [ 70069-04-4 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 70069-04-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 70069-04-4 ]
 

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