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Chemical Structure| 5084-80-0 Chemical Structure| 5084-80-0

Structure of 5084-80-0

Chemical Structure| 5084-80-0

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Product Details of [ 5084-80-0 ]

CAS No. :5084-80-0
Formula : C21H21B3O3
M.W : 353.82
SMILES Code : CC1=CC=C(C=C1)B2OB(OB(O2)C3=CC=C(C=C3)C)C4=CC=C(C=C4)C
MDL No. :MFCD06797737

Safety of [ 5084-80-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335-H413
Precautionary Statements:P261-P301+P312-P302+P352-P304+P340-P305+P351+P338-P501

Application In Synthesis of [ 5084-80-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 5084-80-0 ]

[ 5084-80-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 570-02-5 ]
  • [ 5084-80-0 ]
  • [ 1040196-63-1 ]
YieldReaction ConditionsOperation in experiment
71% With palladium(II) trifluoroacetate; silver carbonate; glyoxal bis(N-methyl-N-phenylhydrazone); In dimethyl sulfoxide; at 80℃; for 2h; General procedure: To a mixture of arylcarboxylic acid (0.20 mmol), Ag2CO3 (165 mg, 0.60 mmol), Pd(TFA)2 (5.0 mg, 0.015 mmol, 7.5 mol %), and ligand 1d (4.0 mg, 0.015 mmol, 7.5 mol %) in DMSO (1.0 mL) was addedarylboroxin (0.40 mmol) at room temperature under an atmosphere of air.After the mixture was stirred at 80?C for 2 h, the mixture was diluted withethyl acetate and water. The organic layer was washed with brine, dried overMgSO4, and concentrated under reduced pressure. The residue was purified by silica gel chromatography (hexane/EtOAc = 20:1).
 

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