Home Cart Sign in  
Chemical Structure| 1040196-63-1 Chemical Structure| 1040196-63-1

Structure of 1040196-63-1

Chemical Structure| 1040196-63-1

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 1040196-63-1 ]

CAS No. :1040196-63-1
Formula : C16H18O3
M.W : 258.31
SMILES Code : CC1=CC=C(C2=C(OC)C=C(OC)C=C2OC)C=C1

Safety of [ 1040196-63-1 ]

Application In Synthesis of [ 1040196-63-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1040196-63-1 ]

[ 1040196-63-1 ] Synthesis Path-Downstream   1~9

  • 1
  • [ 570-02-5 ]
  • [ 5720-05-8 ]
  • [ 1040196-63-1 ]
YieldReaction ConditionsOperation in experiment
63% With palladium(II) trifluoroacetate; silver carbonate; glyoxal bis(N-methyl-N-phenylhydrazone); In dimethyl sulfoxide; at 80℃; for 2h; General procedure: To a mixture of arylcarboxylic acid (0.20 mmol), Ag2CO3 (165 mg, 0.60 mmol), Pd(TFA)2 (5.0 mg, 0.015 mmol, 7.5 mol %), and ligand 1d (4.0 mg, 0.015 mmol, 7.5 mol %) in DMSO (1.0 mL) was addedarylboroxin (0.40 mmol) at room temperature under an atmosphere of air.After the mixture was stirred at 80?C for 2 h, the mixture was diluted withethyl acetate and water. The organic layer was washed with brine, dried overMgSO4, and concentrated under reduced pressure. The residue was purified by silica gel chromatography (hexane/EtOAc = 20:1).
  • 2
  • [ 624-31-7 ]
  • [ 135159-25-0 ]
  • [ 1040196-63-1 ]
  • 4
  • [ 570-02-5 ]
  • [ 5084-80-0 ]
  • [ 1040196-63-1 ]
YieldReaction ConditionsOperation in experiment
71% With palladium(II) trifluoroacetate; silver carbonate; glyoxal bis(N-methyl-N-phenylhydrazone); In dimethyl sulfoxide; at 80℃; for 2h; General procedure: To a mixture of arylcarboxylic acid (0.20 mmol), Ag2CO3 (165 mg, 0.60 mmol), Pd(TFA)2 (5.0 mg, 0.015 mmol, 7.5 mol %), and ligand 1d (4.0 mg, 0.015 mmol, 7.5 mol %) in DMSO (1.0 mL) was addedarylboroxin (0.40 mmol) at room temperature under an atmosphere of air.After the mixture was stirred at 80?C for 2 h, the mixture was diluted withethyl acetate and water. The organic layer was washed with brine, dried overMgSO4, and concentrated under reduced pressure. The residue was purified by silica gel chromatography (hexane/EtOAc = 20:1).
  • 5
  • [ 570-02-5 ]
  • [ 18412-57-2 ]
  • [ 1040196-63-1 ]
YieldReaction ConditionsOperation in experiment
66% With palladium(II) trifluoroacetate; C30H30N4; silver fluoride; In N,N-dimethyl acetamide; at 110℃; for 2h; General procedure: To a mixture of aryl(trialkoxy)silane(0.20 mmol), AgF (76.6 mg, 0.60 mmol), Pd(TFA)2 (5.0 mg, 0.015 mmol,7.5 mol %), and ligand 1g (6.7 mg, 0.015 mmol, 7.5 mol %) in DMAc (1.0 mL)was added arylcarboxylic acid (0.40 mmol) at room temperature under an atmosphere of air. After the mixture was stirred at 100?or 110?C for 2-8 h, the mixture was diluted with ethyl acetate and water. The organic layer was washed with brine, dried over MgSO4, and concentrated under reduced pressure. The residue was purified by silica gel chromatography (hexane/EtOAc = 20:1).
  • 6
  • [ 570-02-5 ]
  • [ 17873-01-7 ]
  • [ 1040196-63-1 ]
YieldReaction ConditionsOperation in experiment
57% With palladium(II) trifluoroacetate; C30H30N4; silver fluoride; In N,N-dimethyl acetamide; at 100℃; for 2h; General procedure: To a mixture of aryl(trialkoxy)silane(0.20 mmol), AgF (76.6 mg, 0.60 mmol), Pd(TFA)2 (5.0 mg, 0.015 mmol,7.5 mol %), and ligand 1g (6.7 mg, 0.015 mmol, 7.5 mol %) in DMAc (1.0 mL)was added arylcarboxylic acid (0.40 mmol) at room temperature under an atmosphere of air. After the mixture was stirred at 100?or 110?C for 2-8 h, the mixture was diluted with ethyl acetate and water. The organic layer was washed with brine, dried over MgSO4, and concentrated under reduced pressure. The residue was purified by silica gel chromatography (hexane/EtOAc = 20:1).
  • 7
  • [ 570-02-5 ]
  • [ 195062-57-8 ]
  • [ 1040196-63-1 ]
YieldReaction ConditionsOperation in experiment
29% With palladium(II) trifluoroacetate; silver carbonate; glyoxal bis(N-methyl-N-phenylhydrazone); In dimethyl sulfoxide; at 80℃; for 2h; General procedure: To a mixture of arylcarboxylic acid (0.20 mmol), Ag2CO3 (165 mg, 0.60 mmol), Pd(TFA)2 (5.0 mg, 0.015 mmol, 7.5 mol %), and ligand 1d (4.0 mg, 0.015 mmol, 7.5 mol %) in DMSO (1.0 mL) was addedarylboroxin (0.40 mmol) at room temperature under an atmosphere of air.After the mixture was stirred at 80?C for 2 h, the mixture was diluted withethyl acetate and water. The organic layer was washed with brine, dried overMgSO4, and concentrated under reduced pressure. The residue was purified by silica gel chromatography (hexane/EtOAc = 20:1).
  • 8
  • [ 570-02-5 ]
  • potassium (4-methylphenyl)trifluoroborate [ No CAS ]
  • [ 1040196-63-1 ]
YieldReaction ConditionsOperation in experiment
23% With palladium(II) trifluoroacetate; silver carbonate; glyoxal bis(N-methyl-N-phenylhydrazone); In dimethyl sulfoxide; at 80℃; for 2h; General procedure: To a mixture of arylcarboxylic acid (0.20 mmol), Ag2CO3 (165 mg, 0.60 mmol), Pd(TFA)2 (5.0 mg, 0.015 mmol, 7.5 mol %), and ligand 1d (4.0 mg, 0.015 mmol, 7.5 mol %) in DMSO (1.0 mL) was addedarylboroxin (0.40 mmol) at room temperature under an atmosphere of air.After the mixture was stirred at 80?C for 2 h, the mixture was diluted withethyl acetate and water. The organic layer was washed with brine, dried overMgSO4, and concentrated under reduced pressure. The residue was purified by silica gel chromatography (hexane/EtOAc = 20:1).
  • 9
  • 4-methyl-8-(4-methylphenyl)-2,6-dioxotetrahydro[1,3,2]oxazaborolo[2,3-b][1,3,2]oxazaborol-4-ium-8-uide [ No CAS ]
  • [ 570-02-5 ]
  • [ 1040196-63-1 ]
YieldReaction ConditionsOperation in experiment
6% With palladium(II) trifluoroacetate; silver carbonate; glyoxal bis(N-methyl-N-phenylhydrazone); In dimethyl sulfoxide; at 80℃; for 2h; General procedure: To a mixture of arylcarboxylic acid (0.20 mmol), Ag2CO3 (165 mg, 0.60 mmol), Pd(TFA)2 (5.0 mg, 0.015 mmol, 7.5 mol %), and ligand 1d (4.0 mg, 0.015 mmol, 7.5 mol %) in DMSO (1.0 mL) was addedarylboroxin (0.40 mmol) at room temperature under an atmosphere of air.After the mixture was stirred at 80?C for 2 h, the mixture was diluted withethyl acetate and water. The organic layer was washed with brine, dried overMgSO4, and concentrated under reduced pressure. The residue was purified by silica gel chromatography (hexane/EtOAc = 20:1).
 

Historical Records