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Chemical Structure| 39929-21-0 Chemical Structure| 39929-21-0

Structure of 39929-21-0

Chemical Structure| 39929-21-0

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Product Details of [ 39929-21-0 ]

CAS No. :39929-21-0
Formula : C4H8AuClS
M.W : 320.59
SMILES Code : [Cl-][Au+][S]1CCCC1
MDL No. :MFCD28411665

Safety of [ 39929-21-0 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314
Precautionary Statements:P501-P260-P264-P280-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P405
Class:8
UN#:1759
Packing Group:

Application In Synthesis of [ 39929-21-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 39929-21-0 ]

[ 39929-21-0 ] Synthesis Path-Downstream   1~9

  • 1
  • [ 288-16-4 ]
  • [ 39929-21-0 ]
  • [ 1493-13-6 ]
  • [Au(CCH=CHN(H)S)2]CF3SO3 [ No CAS ]
  • 2
  • [ 288-16-4 ]
  • [ 39929-21-0 ]
  • [ 333-27-7 ]
  • [Au(CCH=CHN(Me)S)2]CF3SO3 [ No CAS ]
  • 3
  • [ 288-16-4 ]
  • [ 39929-21-0 ]
  • [ 167637-07-2 ]
  • 4
  • [ 109-99-9 ]
  • [ 39929-21-0 ]
  • [ 3347-62-4 ]
  • [Au(μ-3-Me-5-Ph-pz)]3*THF [ No CAS ]
  • 7
  • [ 39929-21-0 ]
  • [ 131274-22-1 ]
  • [ 69550-28-3 ]
  • 8
  • [ 39929-21-0 ]
  • [ 39657-39-1 ]
  • [ 224311-51-7 ]
  • gold(I)(4,4,5,5-tetramethylimidazoline-3-oxide-1-oxyl)(2-(di-tert-butylphosphino)biphenyl) [ No CAS ]
  • 9
  • [ 39929-21-0 ]
  • [ 2848-01-3 ]
  • 3-(diphenylphosphino)propionic acid-gold(I)chloride [ No CAS ]
YieldReaction ConditionsOperation in experiment
1393 mg In acetone; at 20℃; for 2h; [AuCl(tht)] (906 mg, 2.8 mmol, 1.0 eq.) was dissolved in acetone (80.0 ml) and a solution ofdiphenyphosphine propionic acid (730 mg, 2.8 mmol, 1.0 eq.) in acetone (5.0 ml) was added dropwise.The mixture was stirred for 2 h at room temperature and then concentrated under reduced pressure. Acolourless solid (1393 mg, 2.8 mmol, 82%) was obtained.Molecular formula: C15H15AuClO2.Rf: 0.56 (DCM:MeOH, 98:3 + 0.05 v/v % HCOOH).1H-NMR (400 MHz, DMSO-d6): δ/ppm: 12.53 (s, 1 H, COOH) 7.81 - 7.76 (m, 4H, CHo-Phenyl), 7.62 -7.55 (m, 6H, CHm-Phenyl + p-Phenyl), 3.00 - 2.93 (m, 2H, COCH2), 2.46 - 2.39 (m, 2H, CH2P).31P-NMR (162 MHz, DMSO-d6): δ/ppm: 30.3.ESI-HRMS (MeOH) (m/z): calculated for [C15H15AuClO2+Na]+: 513.0056, found 513.0074.
 

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