3894-25-5|6-Bromo-2-phenylquinoline| Ambeed

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Quality Control of [ 3894-25-5 ] Purity: 95% SDS Specification

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Product Details of [ 3894-25-5 ]

CAS No. :	3894-25-5
Formula :	C₁₅H₁₀BrN
M.W :	284.15
SMILES Code :	BrC1=CC=C2N=C(C3=CC=CC=C3)C=CC2=C1
MDL No. :	MFCD17392928

Safety of [ 3894-25-5 ]

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H302-H315-H319-H335
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 3894-25-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 3894-25-5 ]

[ 3894-25-5 ] Synthesis Path-Downstream 1~35

2
[ 104-55-2 ]
[ 106-40-1 ]
[ 3894-25-5 ]

Yield	Reaction Conditions	Operation in experiment
42%	With Ag(I) exchanged montmorillonite K10; In neat (no solvent); at 120℃; for 3h;Green chemistry;	General procedure: Amine (1.50 mmol) and aldehyde (1.00 mmol) were dissolved in 1.5 mL of Et2O in a reaction vial equipped with a magnetic stirrer bar, followed by the addition of Ag(I)-exchanged Montmorillonite K10 (0.50 g). After 5 min stirring, the solvent was removed in vacuo to obtain a dry powder. The reaction mixture was heated at a temperature of 120 oC for 3 h. After cooling to room temperature, the reaction mixture was filtered through a short silica plug and the solid residues washed well with CH2Cl2. The solvent was removed in vacuo and the crude product purified by column chromatography over silica gel eluting with a mixture of Hexane EtOAc to produce the title compounds (3a-3k). NOTE. For the recycle/reuse study, the crude product was gravity filtered and the clay material washed several times with CH2Cl2, air dried and weighed. This process was repeated for consecutive recycle/reuse reactions.

References: [1]Heterocycles,2016,vol. 92,p. 2213 - 2224.
[2]Tetrahedron Letters,2009,vol. 50,p. 2939 - 2942.

3
[ 1207875-00-0 ]
[ 3894-25-5 ]

References: [1]Journal of Organic Chemistry,2010,vol. 75,p. 1266 - 1270.

4
[ 88-12-0 ]
[ 780-20-1 ]
cis-6-bromo-2-phenyl-4-(2'-oxopyrrolidin-1'-yl)-1,2,3,4-tetrahydroquinoline [ No CAS ]
[ 3894-25-5 ]

References: [1]Synthetic Communications,2010,vol. 40,p. 2220 - 2231.

5
[ 2235-00-9 ]
[ 780-20-1 ]
cis-6-bromo-4-(2-oxoazepan-1-yl)-2-phenyl-1,2,3,4-tetrahydroquinoline [ No CAS ]
[ 3894-25-5 ]

References: [1]Synthetic Communications,2010,vol. 40,p. 2220 - 2231.

6
[ 1013-88-3 ]
[ 3894-25-5 ]
[ 1257303-36-8 ]

Yield	Reaction Conditions	Operation in experiment
	With palladium diacetate; caesium carbonate; triethylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In 1,4-dioxane; at 100℃;	EXAMPLE 47CN-(diphenylmethylene)-2-phenylquinolin-6-amineIn a 20 mL microwave tube was charged cesium carbonate (0.440 mL, 5.50 mmol), palladium(II) acetate (0.018 g, 0.079 mmol), and 9,9-dimethyl-4,5- bis(diphenylphosphino)xanthene (0.068 g, 0.118 mmol) in dioxane (6.0 mL) to give a yellow suspension. The mixture was stirred for 10 minutes and then triethylamine (0.016 mL, 0.118 mmol) was added. The solution was stirred for another 10 minutes; and then8489667 1 <strong>[3894-25-5]6-bromo-2-phenylquinoline</strong> (1.1168 g, 3.93 mmol) and benzophenone imine (0.791 niL, 4.72 mmol) were added as a solution in dioxane (6.0 mL). The mixture was heated at 100 0C overnight. The mixture was cooled to room temperature and dilute with ethyl acetate. The organics were washed 2 x 100 mL with water, dried over magnesium sulfate, filtered, and concentrated onto silica gel. The reaction was purified by flash chromatography using an Argonaut Flashmaster Solo, 20g column (10% ethyl acetate:hexanes for 30 min) to afford a yellow oil. (ES I(+)) m/e 385.0 (M+H)+.

References: [1]Patent: WO2010/138578,2010,A1 .Location in patent: Page/Page column 84-85.

7
[ 100-52-7 ]
[ 79-10-7 ]
[ 106-40-1 ]
[ 3894-25-5 ]

References: [1]Angewandte Chemie - International Edition,2012,vol. 51,p. 7292 - 7296.

8
[ 29124-57-0 ]
[ 536-74-3 ]
[ 3894-25-5 ]

References: [1]Chemical Communications,2013,vol. 49,p. 570 - 572.

9
[ 3894-25-5 ]
[ 1416892-69-7 ]

References: [1]Chemical Communications,2013,vol. 49,p. 570 - 572.

10
[ 3894-25-5 ]
[ 1613133-65-5 ]

References: [1]Organic Letters,2014,vol. 16,p. 3244 - 3247.

11
[ 98-86-2 ]
[ 20712-12-3 ]
[ 3894-25-5 ]

Yield	Reaction Conditions	Operation in experiment
83%	With potassium tert-butylate; cobalt(II) diacetate tetrahydrate; In toluene; at 110℃; for 12h;Inert atmosphere;	The reaction vessel was charged with 2-amino-5-bromobenzyl alcohol 1s (202.0 mg, 1.0 mmol), acetophenone 2a (120.2 mg, 1.0 mmol), Co(OAc)2 4H2O (19.9 mg, 0.08 mmol) and KOtBu (112.0 mg, 1.0 mmol).Under an argon atmosphere, 2 mL of toluene was added and heated at 110 C for 12 h.After cooling to room temperature, 10 mL of water was added, and the mixture was extracted with EtOAc (3 x 10 mL).The combined organic phases were concentrated under reduced pressure.The residue was then purified by flash column chromatography (petroleum ether:ethyl acetate 100:1, v/v) to give 3s as a white solid (234.9 mg, 83% yield).
80%	With C22H24N6O2Ru(1+)*Cl(1-); potassium hexamethylsilazane; In toluene; at 110℃; for 12h;Inert atmosphere;	Add 2-amino-5-bromobenzyl alcohol 2q (201.0mg, 1.0mmol), acetophenone 3a (120.2mg, 1.0 mmol), complex 1a (10.8mg, 0.02mmol) and KHMDS (1mL, 1.0mmol). Under a nitrogen atmosphere, 2 mL of toluene was added and heated at 110 C. for 12 h. After cooling to room temperature, 10 mL of water was added, and the mixture was extracted with EtOAc (3×10 mL). The combined organic phase was concentrated under reduced pressure. The residue was then purified by flash column chromatography (petroleum ether: ethyl acetate 100:1, v/v) to obtain 4q (226 mg, 80%) as a white solid.
	With C22H24N6O2Ru(1+)*Cl(1-); potassium hexamethylsilazane; In tetrahydrofuran; toluene; at 110℃; for 12h;Inert atmosphere;	General procedure: A mixture of 2-aminophenylmethanol (2a) (123.2 mg, 1.0 mmol),acetophenone (3a) (120.2 mg, 1.0 mmol), complex 1a (10.8 mg,0.02 mmol), and KHMDS (1.0 mL, 1.0 M in THF) in 2 mL of toluene wasstirred at 110 C for 12 h under a nitrogen atmosphere. After cooling toambient temperature, 10 mL water was added and the mixture wasextracted with EtOAc (3 × 10 mL). The combined organic layer wasdried over anhydrous Na2SO4 and concentrated under reduced pressure.The resulting residue was subjected to purification by flash columnchromatography on alumina (petroleum ether: ethyl acetate 100: 1, v/v)to afford 4a as a white solid (190.9 mg, 93% yield), which was identifiedby NMR analysis.

References: [1]Journal of Organic Chemistry,2018,vol. 83,p. 2309 - 2316.
[2]Patent: CN113861119,2021,A .Location in patent: Paragraph 0011; 0053.
[3]Patent: CN112209916,2021,A .Location in patent: Paragraph 0104-0106; 0139-0140.
[4]RSC Advances,2014,vol. 4,p. 52911 - 52914.
[5]Molecular catalysis,2021,vol. 514.

12
[ 30293-62-0 ]
[ 3894-25-5 ]

References: [1]Advanced Synthesis and Catalysis,2016,vol. 358,p. 459 - 465.

13
[ 17708-39-3 ]
[ 3894-25-5 ]

References: [1]Advanced Synthesis and Catalysis,2016,vol. 358,p. 459 - 465.

14
[ 17708-39-3 ]
[ 106-40-1 ]
[ 3894-25-5 ]

References: [1]Advanced Synthesis and Catalysis,2016,vol. 358,p. 459 - 465.

15
[ 17708-39-3 ]
[ 104-94-9 ]
[ 3894-25-5 ]
[ 4789-73-5 ]

References: [1]Advanced Synthesis and Catalysis,2016,vol. 358,p. 459 - 465.

16
[ 3894-25-5 ]
[ 98-80-6 ]
[ 94878-29-2 ]

References: [1]Chemistry - A European Journal,2016,vol. 22,p. 4036 - 4045.

17
[ 3894-25-5 ]
[ 1765-93-1 ]
[ 1605333-25-2 ]

References: [1]Chemistry - A European Journal,2016,vol. 22,p. 4036 - 4045.

18
[ 29124-57-0 ]
[ 98-86-2 ]
[ 3894-25-5 ]

References: [1]Chemistry - A European Journal,2016,vol. 22,p. 4036 - 4045.

19
[ 123-91-1 ]
[ 100-52-7 ]
[ 106-40-1 ]
[ 3894-25-5 ]

Yield	Reaction Conditions	Operation in experiment
65%	With trifluorormethanesulfonic acid; copper(l) chloride; at 90℃; for 12h;Sealed tube;	In a Schlenk tube with a screw cap, washed added benzaldehyde (0.2mmol, 21.2mg), bromine aniline (0.4mmol, 68.0mg), copper (0.04mmol, 2.69mg) chloride, 4.0mL 1,4 dioxane, trifluoromethanesulfonate (0.1mmol, 15.0mg), and finally under air conditions, the sealed reactor tube placed in an oil bath at 90 pot heated with stirring for about 12 hours.Distillation under reduced pressure, to remove unreacted 1,4-dioxane, the final product was purified by column chromatography, and then dried to give a white solid solid powder 36.9 mg, 65% yield
65%	With trifluorormethanesulfonic acid; copper dichloride; at 90℃; for 0.12h;Schlenk technique; Sealed tube;	In a Schlenk tube with a screw cap, add benzaldehyde (0.2mmol, 21.2mg), p-bromoaniline (0.4mmol, 68.0mg), copper chloride (0.04mmol, 2.69mg), 4.0mL of 1,4- Dioxane, trifluoromethanesulfonic acid (0.1mmol, 15.0mg), and finally under air conditions, place the sealed reaction tube in an oil bath at 90C and heat and stir for about 12 hours.Under reduced pressure distillation, the unreacted 1,4-dioxane was removed, and finally the product was separated and purified by column chromatography, and then dried to obtain 36.9 mg of white solid powder with a yield of 65%.Melting point: 112-113C.

References: [1]Patent: CN105801478,2016,A .Location in patent: Paragraph 0045; 0046.
[2]Patent: CN111471009,2020,A .Location in patent: Paragraph 0020; 0046-0047.

20
[ 5332-25-2 ]
[ 98-80-6 ]
[ 3894-25-5 ]
[ 861872-54-0 ]

Yield	Reaction Conditions	Operation in experiment
35 mg; 45 mg	With ammonium peroxodisulfate; zinc trifluoromethanesulfonate; silver nitrate; In dichloromethane; water; at 20℃; for 4h;	General procedure: Ammonium persulfate (3 equiv, 342 mg), phenylboronic acid (1.5 equiv, 91 mg), silver nitrate (0.2 equiv, 17 mg), and zinc trifluoromethanesulfonate (0.2 equiv, 36 mg) were combined ina 10 mL round bottom flask. A heterocycle (1 equiv, 0.5 mmol) was then added to the same flask and solvated with water (0.4 mL) and CH2Cl2 (1.6 mL). The resulting mixture was sonicated for 10 sec and placed on a stir plate to stir vigorously at room temperature for 4 h. The reaction was quenched with 28% ammonium hydroxide (2 mL), diluted with water (10 mL), and extracted with CH2Cl2 (3 x 10 mL). The organic layer was dried over sodium sulfate, filtered through cotton, and evaporated en vacuo. The products were purified by column chromatography (SiO2, 5-20% EtOAc/hexanes). Products 3b, 3c, and 3d required further purification by crystallization as the trifluoromethanesulfonic acid salts and recrystallization from THF/hexanes.

References: [1]Heterocycles,2016,vol. 92,p. 1687 - 1697.

21
[ 300-57-2 ]
[ 106-40-1 ]
[ 3894-25-5 ]

References: [1]Journal of Organic Chemistry,2016,vol. 81,p. 12189 - 12196.

22
[ 20357-20-4 ]
[ 98-86-2 ]
[ 3894-25-5 ]

Yield	Reaction Conditions	Operation in experiment
64%		General procedure: Iron powder (0.4 eq.) was added to a solution of o-nitrobenzaldehyde (11a-11g, 1.0 eq.) in EtOH(2.0 mL) followed by HCl (0.05 eq.) [19]. The reaction mixture was refluxed for 40 min followedby cooling to room temperature. The corresponding aldehyde or ketone (1.2 eq.) was added to thereaction mixture followed by KOH (1.2 eq.). The reaction mixture was stirred at RT for 30 min andrefluxed for an additional 3 h. The reaction mixture was filtered, the filtrate was neutralized (HCl),extracted with EtOAc, and the combined extracts were dried and concentrated to dryness. The residuewas subjected to FCC (EtOAc-hexane, 3:7) to afford substituted quinolines 5a-7g.

References: [1]Molecules,2017,vol. 22.

23
[ 104-54-1 ]
[ 106-40-1 ]
[ 3894-25-5 ]

References: [1]RSC Advances,2017,vol. 7,p. 36242 - 36245.

24
C₁₀H₉BrNO⁽¹⁺⁾*BF₄^(1-) [ No CAS ]
[ 98-80-6 ]
[ 3894-25-5 ]
[ 861872-54-0 ]

Yield	Reaction Conditions	Operation in experiment
63%	With sodium persulfate; silver nitrate; trifluoroacetic acid; In dichloromethane; water; at 25℃; for 0.5h;	General procedure: A dried glass reaction tube equipped with a magnetic stir bar was charged with 1a (1.5 mmol, 3.0 equiv), Na2S2O8 (0.5 mmol, 1.0 equiv) and AgNO3 (0.15 mmol, 0.3 equiv), 2a (0.5 mmol, 1.0 equiv), DCM:H2O = 1:1 (4.0 mL). The resulting mixture was then stirred at 25C for 0.5 h. The crude production was diluted with EA and Na2CO3 aqueous solution (1 mol/L) and then the resulting mixture was filtered through a pad of Celite. The filtrate was extracted with Na2CO3 aqueous solution (1 mol/L, 20 mL), and the aqueous layer was extracted with EA (3 × 10 mL). The combined organic layers dried over anhydrous Na2SO4, concentrated in vacuo, and purified by flash column chromatograph to give the pure products. The products were characterized by 1H NMR, 13C NMR, LC-MS.

References: [1]Tetrahedron Letters,2018,vol. 59,p. 1065 - 1068.

25
[ 6563-11-7 ]
[ 3894-25-5 ]
[ 861872-54-0 ]

References: [1]Tetrahedron Letters,2018,vol. 59,p. 1065 - 1068.

26
[ 20357-20-4 ]
[ 3894-25-5 ]

References: [1]Journal of Organic Chemistry,2018,vol. 83,p. 5177 - 5186.
[2]Journal of Organic Chemistry,2018,vol. 83,p. 13036 - 13044.
[3]Chinese Journal of Chemistry,2020,vol. 38,p. 1691 - 1695.

27
[ 98-86-2 ]
[ 3894-25-5 ]

28
(E)-3-(2-amino-5-bromophenyl)-1-phenylprop-2-en-1-one [ No CAS ]
[ 3894-25-5 ]

References: [1]Journal of Organic Chemistry,2018,vol. 83,p. 5177 - 5186.
[2]Journal of Organic Chemistry,2018,vol. 83,p. 13036 - 13044.
[3]Journal of Organic Chemistry,2018,vol. 83,p. 12486 - 12495.
[4]Chinese Journal of Chemistry,2020,vol. 38,p. 1691 - 1695.

29
(E)-3-(5-bromo-2-nitrophenyl)-1-phenylprop-2-en-1-one [ No CAS ]
[ 3894-25-5 ]

References: [1]Journal of Organic Chemistry,2018,vol. 83,p. 5177 - 5186.
[2]Journal of Organic Chemistry,2018,vol. 83,p. 13036 - 13044.

30
[ 597554-03-5 ]
[ 3894-25-5 ]
2-phenyl-6-(10-(naphthalen-7-yl)anthracen-9-yl)quinoline [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
67%	With tetrakis(triphenylphosphine) palladium(0); sodium carbonate; In ethanol; water; toluene; for 3h;Reflux;	General procedure: 9-(naphthalen-2-yl)anthracen-10-yl-10-boronic acid(1.7 mmol) and the corresponding aryl bromides(1.4 mmol), Pd(PPh34 (0.06 mmol), aqueous 2.0 M Na2CO3 (7 mL), ethanol, and toluene were mixed in aflask. The mixture was refluxed for 3 h. After the reactionwas completed, water was added to quench the reaction.After being cooled, the solutions were extracted twice withethyl acetate. The combined organic solution layers werewashed with brine and MgSO4. After filtration and concentrationthe solvents, the crude solutions were purified bycolumn chromatography (silica gel, hexane: ethyl acetate)and recrystallization with ethanol and dichloromethane.

References: [1]Journal of Nanoscience and Nanotechnology,2018,vol. 18,p. 7105 - 7109.

31
[ 3894-25-5 ]
(S)-6-bromo-2-phenyl-1,2,3,4-tetrahydroquinoline [ No CAS ]

References: [1]Journal of Organic Chemistry,2018,vol. 83,p. 12486 - 12495.

32
[ 13323-81-4 ]
[ 20712-12-3 ]
[ 3894-25-5 ]

References: [1]Journal of Catalysis,2019,vol. 373,p. 93 - 102.

33
[ 79-24-3 ]
[ 100-52-7 ]
[ 106-40-1 ]
[ 3894-25-5 ]

References: [1]Organic and Biomolecular Chemistry,2019,vol. 17,p. 7907 - 7917.

34
(E)-3-(2-amino-5-bromophenyl)acrylonitrile [ No CAS ]
[ 98-80-6 ]
[ 3894-25-5 ]

References: [1]Journal of Organic Chemistry,2019,vol. 84,p. 13604 - 13614.

35
C₉H₇BrN₂ [ No CAS ]
[ 100-63-0 ]
[ 3894-25-5 ]

References: [1]RSC Advances,2020,vol. 10,p. 8586 - 8593.

Historical Records

Technical Information

• Alkyl Halide Occurrence • General Reactivity • Grignard Reaction • Hiyama Cross-Coupling Reaction • Kinetics of Alkyl Halides • Kumada Cross-Coupling Reaction • Reactions of Alkyl Halides with Reducing Metals • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Reactions of Dihalides • Stille Coupling • Substitution and Elimination Reactions of Alkyl Halides • Suzuki Coupling

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[ 3894-25-5 ]

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P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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CAS No.: 3894-25-5

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