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Chemical Structure| 37026-85-0 Chemical Structure| 37026-85-0

Structure of 37026-85-0

Chemical Structure| 37026-85-0

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Product Details of [ 37026-85-0 ]

CAS No. :37026-85-0
Formula : C12H28BrN
M.W : 266.26
SMILES Code : CCCCN(CCCC)CCCC.[H]Br

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Application In Synthesis of [ 37026-85-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 37026-85-0 ]

[ 37026-85-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 5683-33-0 ]
  • [ 37026-85-0 ]
  • [ 26163-07-5 ]
YieldReaction ConditionsOperation in experiment
72.0% With sodium thiosulfate; In chloroform; water; Example 191-1 Synthesis of 5-bromo-2-dimethylaminopyridine 2-Dimethylaminopyridine (1.0 ml) was dissolved in chloroform (60 ml). After adding tributylammonium bromide (3.88 g) thereto, the resultant mixture was stirred for 7 min. Then the reaction solution was washed with an aqueous solution of sodium thiosulfate and water, dried over anhydrous sodium sulfate and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (hexane/ethyl acetate-methanol system) to give the title compound (1.097 g) as yellow crystals (yield: 72.0%). 1H-NMR (400 MHz, CDCl3): delta(ppm) 3.05(6H, s), 6.40(1H, dd, J=0.8, 8.8Hz), 7.48(1H, dd, J=2.8, 8.8Hz), 8.16(1H, dd, J=0.8, 2.8Hz).
 

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