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Chemical Structure| 35490-05-2 Chemical Structure| 35490-05-2

Structure of 35490-05-2

Chemical Structure| 35490-05-2

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Product Details of [ 35490-05-2 ]

CAS No. :35490-05-2
Formula : C10H16O4
M.W : 200.23
SMILES Code : CC(CCC(C(C)=O)C(OCC)=O)=O

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Application In Synthesis of [ 35490-05-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 35490-05-2 ]

[ 35490-05-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 35490-05-2 ]
  • [ 5751-81-5 ]
YieldReaction ConditionsOperation in experiment
63% Formula (1) as a sign that the compound (0.10 g, 0.50 mmol) in a stirred solution (2.5 mL AcOH solvent) to Mn (OAc) 3.2 H2O (6.7 mg, 0.025 mmol) and CoCl2 (1.3 mg, 0.01 mmol) was added. The reaction mixture and air was vigorously stirred for 3 hours at 25 ° C was added Lawesson's Reagent (0.61 g, 1.5 mmol). The mixture was heated for 1 hour at 90 ° C and cooled to room temperature (room temperature). Quench the mixture with saturated NaHCO3 (saturated NaHCO3) and extracted with CH2Cl2. The organic phase (organic phase) to H2O and brine (brine) wash, dried over anhydrous Na2SO4, filtered and concentrated under reduced pressure. Purification of the crude product by silica gel flash column chromatography to give the compound (54 mg, 0.32 mmol) represented by the formula (8) of a yellow oil type (63percent yield).
 

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