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Chemical Structure| 34905-07-2 Chemical Structure| 34905-07-2

Structure of 34905-07-2

Chemical Structure| 34905-07-2

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Product Details of [ 34905-07-2 ]

CAS No. :34905-07-2
Formula : C10H12O2
M.W : 164.20
SMILES Code : OCC1=CC=CC(OCC=C)=C1
MDL No. :MFCD08753020

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Application In Synthesis of [ 34905-07-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 34905-07-2 ]

[ 34905-07-2 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 40359-32-8 ]
  • [ 34905-07-2 ]
YieldReaction ConditionsOperation in experiment
With sodium borohydrid; In methanol; acetic acid; (B) To a solution of <strong>[40359-32-8]3-allyloxybenzaldehyde</strong> (7.2 g) in methanol (50 ml) at 0 C. was added sodium borohydride (1 g) in portions. The mixture was stirred for 30 minutes, evaporated dissolved in 5% acetic acid and extracted with diethyl ether (3*100 ml), washed with water (2*100 ml), and sodium bicarbonate (2*100 ml), dried (magnesium sulphate), filtered and evaporated to give 3-allyloxybenzyl alcohol (7.26 g).
  • 2
  • [ 34905-07-2 ]
  • [ 40359-32-8 ]
YieldReaction ConditionsOperation in experiment
83% With C6H4MoNO7(1-)*C19H42N(1+); oxygen; In water; at 100℃; for 18h;Green chemistry; General procedure: A mixture of alcohol (0.75 mmol), and catalyst Mo1 (13 mg,3.0 mol%) taken in 0.5 mL of water was stirred at 100 C under oxygenatmosphere (O2 bladder) and the stirring was continued for16-24 h as per requirement. The progress of reaction was monitoredby TLC. After completion of the reaction, ethyl acetate was added to the mixture. The aqueous phase was extracted with ethyl acetate 2-3 times. Then the combined organic extracts were driedover anhydrous sodium sulfate and the solvent was removed under reduced pressure. The crude product so obtained was purified by column chromatography using hexane-ethyl acetate as eluent. While the known products were characterized by spectroscopic techniques and compared with reported data and the new products 22b and 36b were characterized completely. The characterization detail is provided in supporting information section.
 

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