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Chemical Structure| 32634-68-7 Chemical Structure| 32634-68-7
Chemical Structure| 32634-68-7

Di-p-toluoyl-D-tartaric Acid

CAS No.: 32634-68-7

4.5 *For Research Use Only !

Cat. No.: A274172 Purity: 98%

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Product Citations

Product Citations

Freeman, Stephan ; Landwehr, Eleanor ; Rojas, Juan ; Tanaka, Riku ; Bailey, Jake ; Gembicky, Milan , et al.

Abstract: The Galbulimima alkaloids affect nervous system function in mammals but have proven challenging to study and optimize due to their low and variable abundance in plant matter. Here, we synthesized 12.97 g of the alkaloid GB13 to investigate its conversion to diverse congeners. These divergent transformations required understanding and control of aza-Michael ring-chain tautomerism, which influenced scaffold reactivity profoundly. A series of chemoselective oxidations, including an unusual iodoamine rearrangement, and a C–H amination catalyzed by OsO4, allowed us to identify a single general solution to the class II, III and IV Galbulimima alkaloids.

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Product Details of Di-p-toluoyl-D-tartaric Acid

CAS No. :32634-68-7
Formula : C20H18O8
M.W : 386.35
SMILES Code : O=C(O)[C@@H](OC(C1=CC=C(C)C=C1)=O)[C@H](OC(C2=CC=C(C)C=C2)=O)C(O)=O
MDL No. :MFCD00008552
InChI Key :CMIBUZBMZCBCAT-HOTGVXAUSA-N
Pubchem ID :263211

Safety of Di-p-toluoyl-D-tartaric Acid

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of Di-p-toluoyl-D-tartaric Acid

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 32634-68-7 ]

[ 32634-68-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 10421-85-9 ]
  • [ 32634-68-7 ]
  • C8H6ClO3(1-)*C20H17O8(1-)*Ca(2+) [ No CAS ]
  • C8H6ClO3(1-)*C20H17O8(1-)*Ca(2+) [ No CAS ]
 

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