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Chemical Structure| 32634-68-7 Chemical Structure| 32634-68-7
Chemical Structure| 32634-68-7

Di-p-toluoyl-D-tartaric Acid

CAS No.: 32634-68-7

4.5 *For Research Use Only !

Cat. No.: A274172 Purity: 98%

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Product Citations

Product Citations

Freeman, Stephan ; Landwehr, Eleanor ; Rojas, Juan ; Tanaka, Riku ; Bailey, Jake ; Gembicky, Milan , et al.

Abstract: The Galbulimima affect nervous system function in mammals but have proven challenging to study and optimize due to their low and variable abundance in plant matter. Here, we synthesized 12.97 g of the alkaloid GB13 to investigate its conversion to diverse congeners. These divergent transformations required understanding and control of aza-Michael ring-chain tautomerism, which influenced scaffold reactivity profoundly. A series of chemoselective oxidations, including an unusual iodoamine rearrangement, and a C–H amination catalyzed by OsO4, allowed us to identify a single general solution to the class II, III and IV Galbulimima .

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Product Details of Di-p-toluoyl-D-tartaric Acid

CAS No. :32634-68-7
Formula : C20H18O8
M.W : 386.35
SMILES Code : O=C(O)[C@@H](OC(C1=CC=C(C)C=C1)=O)[C@H](OC(C2=CC=C(C)C=C2)=O)C(O)=O
MDL No. :MFCD00008552
InChI Key :CMIBUZBMZCBCAT-HOTGVXAUSA-N
Pubchem ID :263211

Safety of Di-p-toluoyl-D-tartaric Acid

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of Di-p-toluoyl-D-tartaric Acid

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 32634-68-7 ]

[ 32634-68-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 10421-85-9 ]
  • [ 32634-68-7 ]
  • C8H6ClO3(1-)*C20H17O8(1-)*Ca(2+) [ No CAS ]
  • C8H6ClO3(1-)*C20H17O8(1-)*Ca(2+) [ No CAS ]
 

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