3153-72-8|2,2',4,4'-Tetramethoxy-1,1'-biphenyl| Ambeed

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Quality Control of [ 3153-72-8 ] Purity: 97% SDS Specification

COA

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NMR

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Product Details of [ 3153-72-8 ]

CAS No. :	3153-72-8
Formula :	C₁₆H₁₈O₄
M.W :	274.31
SMILES Code :	COC1=CC=C(C2=CC=C(OC)C=C2OC)C(OC)=C1
MDL No. :	MFCD08692770
InChI Key :	NMMDKMRTHCDPPA-UHFFFAOYSA-N
Pubchem ID :	266847

Safety of [ 3153-72-8 ]

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H302-H315-H319-H335
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 3153-72-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 3153-72-8 ]

[ 3153-72-8 ] Synthesis Path-Downstream 1~35

1
[ 108-30-5 ]
[ 3153-72-8 ]
4,4'-dioxo-4,4'-(4,6,4',6'-tetramethoxy-biphenyl-3,3'-diyl)-di-butyric acid [ No CAS ]

References: [1]Journal of the American Chemical Society,1953,vol. 75,p. 2341,2342.

2
[ 20469-63-0 ]
[ 3153-72-8 ]

References: [1]Monatshefte fur Chemie,1930,vol. 55,p. 342,349.
[2]Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan,1944,vol. 64,p. 41,45.
Chem.Abstr.,1951,p. 2928.
[3]Acta Chemica Scandinavica (1947),1961,vol. 15,p. 1761 - 1764.
[4]Acta Chemica Scandinavica (1947),1962,vol. 16,p. 553 - 558.

3
[ 3153-72-8 ]
[ 35065-24-8 ]

References: [1]Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan,1944,vol. 64,p. 41,45.
Chem.Abstr.,1951,p. 2928.

4
[ 3153-72-8 ]
[ 43042-33-7 ]

References: [1]Journal of the Chemical Society,1958,p. 4569,4573.

5
[ 3153-72-8 ]
[ 4371-31-7 ]

References: [1]Journal of the American Chemical Society,2009,vol. 131,p. 4710 - 4719.
[2]Monatshefte fur Chemie,1930,vol. 55,p. 342,349.
[3]Acta Chemica Scandinavica (1947),1958,vol. 12,p. 147,162.

6
[ 861367-96-6 ]
[ 3153-72-8 ]

References: [1]Tetrahedron,1972,vol. 28,p. 3323 - 3331.

7
[ 16932-44-8 ]
[ 113793-83-2 ]
[ 3153-72-8 ]
[ 113793-84-3 ]

References: [1]Journal of Medicinal Chemistry,1988,vol. 31,p. 1466 - 1471.

8
[ 25245-35-6 ]
[ 113793-83-2 ]
[ 3153-72-8 ]
[ 113793-85-4 ]

References: [1]Journal of Medicinal Chemistry,1988,vol. 31,p. 1466 - 1471.

9
[ 113793-83-2 ]
[ 113793-82-1 ]
[ 3153-72-8 ]
[ 113793-86-5 ]

References: [1]Journal of Medicinal Chemistry,1988,vol. 31,p. 1466 - 1471.

10
[ 109384-40-9 ]
[ 590-17-0 ]
[ 3153-72-8 ]
[ 1891-11-8 ]

References: [1]Synthesis,1987,p. 40 - 42.

11
[ 3153-72-8 ]
[ 23071-37-6 ]

References: [1]Journal of the Indian Chemical Society,1969,vol. 46,p. 444 - 450.

12
[ 3153-72-8 ]
[ 75-36-5 ]
[ 10418-83-4 ]

References: [1]Journal of the Indian Chemical Society,1969,vol. 46,p. 444 - 450.

13
[ 92190-83-5 ]
[ 77-78-1 ]
[ 3153-72-8 ]

References: [1]Chemische Berichte,1963,vol. 96,p. 1568 - 1578.

14
[ 36896-61-4 ]
(2-thienyl)(phenyl)iodonium tetrafluoroborate [ No CAS ]
[ 3153-72-8 ]
2-(2',4'-dimethoxyphenyl)thiophene [ No CAS ]

References: [1]Synthetic Communications,1999,vol. 29,p. 2493 - 2499.

17
[ 20469-63-0 ]
copper-powder [ No CAS ]
[ 3153-72-8 ]

References: [1]Monatshefte fur Chemie,1930,vol. 55,p. 342,349.

18
[ 20469-63-0 ]
[ 5460-32-2 ]
copper-powder [ No CAS ]
[ 3153-72-8 ]
[ 2026-27-9 ]
[ 170649-97-5 ]

References: [1]Monatshefte fur Chemie,1930,vol. 55,p. 342,349.

19
[ 133730-34-4 ]
[ 3153-72-8 ]

References: [1]Chemical and Pharmaceutical Bulletin,1999,vol. 47,p. 1276 - 1283.

20
[ 66177-24-0 ]
[ 3153-72-8 ]

References: [1]Journal of Medicinal Chemistry,1988,vol. 31,p. 1466 - 1471.

21
[ 151-10-0 ]
[ 3153-72-8 ]

References: [1]Journal of Medicinal Chemistry,1988,vol. 31,p. 1466 - 1471.

22
[ 3153-72-8 ]
4,4'-dioxo-4,4'-(4,4'-dihydroxy-6,6'-dimethoxy-biphenyl-3,3'-diyl)-di-butyric acid [ No CAS ]

References: [1]Journal of the American Chemical Society,1953,vol. 75,p. 2341,2342.

23
[ 3153-72-8 ]
[ 36140-13-3 ]

References: [1]Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan,1944,vol. 64,p. 41,45.
Chem.Abstr.,1951,p. 2928.

24
[ 3153-72-8 ]
[ 23071-36-5 ]

References: [1]Journal of the Indian Chemical Society,1969,vol. 46,p. 444 - 450.

25
[ 3153-72-8 ]
[ 13559-75-6 ]

References: [1]Journal of the Indian Chemical Society,1969,vol. 46,p. 444 - 450.

26
[ 3934-97-2 ]
[ 3153-72-8 ]

References: [1]Chemische Berichte,1963,vol. 96,p. 1568 - 1578.

27
[ 3843-79-6 ]
[ 3153-72-8 ]

References: [1]Chemische Berichte,1963,vol. 96,p. 1568 - 1578.

28
[ 93533-92-7 ]
[ 3153-72-8 ]

References: [1]Chemische Berichte,1963,vol. 96,p. 1568 - 1578.

29
[ 96077-98-4 ]
[ 3153-72-8 ]

References: [1]Chemische Berichte,1963,vol. 96,p. 1568 - 1578.

30
[ 17715-69-4 ]
[ 133730-34-4 ]
[ 3153-72-8 ]

References: [1]Journal of the American Chemical Society,2009,vol. 131,p. 4710 - 4719.

31
[ 3153-72-8 ]
[ 1141898-24-9 ]

References: [1]Journal of the American Chemical Society,2009,vol. 131,p. 4710 - 4719.

32
[ 3153-72-8 ]
[ 1141898-32-9 ]

References: [1]Journal of the American Chemical Society,2009,vol. 131,p. 4710 - 4719.

33
[ 17715-69-4 ]
[ 3153-72-8 ]
[ 151-10-0 ]

References: [1]Synlett,2009,p. 2919 - 2923.

34
[ 552-16-9 ]
[ 91-52-1 ]
[ 2436-96-6 ]
[ 3153-72-8 ]
[ 92200-30-1 ]

References: [1]European Journal of Organic Chemistry,2011,p. 5787 - 5790.

35
[ 6280-88-2 ]
[ 91-52-1 ]
[ 3153-72-8 ]
[ 1352638-57-3 ]
[ 56978-50-8 ]

References: [1]European Journal of Organic Chemistry,2011,p. 5787 - 5790.

Historical Records

Technical Information

• Benzylic Oxidation • Birch Reduction • Blanc Chloromethylation • Friedel-Crafts Reaction • Hydrogenolysis of Benzyl Ether • Nomenclature of Ethers • Preparation of Alkylbenzene • Preparation of Ethers • Reactions of Benzene and Substituted Benzenes • Reactions of Ethers • Vilsmeier-Haack Reaction

Related Functional Groups of
[ 3153-72-8 ]

Aryls

A526091 [796866-40-5]

2-Methoxy-3-methyl-[1,1'-biphenyl]-4-ol

Similarity: 1.00

A202943 [17715-56-9]

2,4-Dimethoxy-1,1'-biphenyl

Similarity: 1.00

A957198 [13732-86-0]

2,6-Dimethoxy-1,1'-biphenyl

Similarity: 1.00

A136059 [19491-10-2]

2,2',6,6'-Tetramethoxy-1,1'-biphenyl

Similarity: 1.00

A331991 [70388-58-8]

2,2',6-Trimethoxy-1,1'-biphenyl

Similarity: 1.00

Ethers

A526091 [796866-40-5]

2-Methoxy-3-methyl-[1,1'-biphenyl]-4-ol

Similarity: 1.00

A202943 [17715-56-9]

2,4-Dimethoxy-1,1'-biphenyl

Similarity: 1.00

A957198 [13732-86-0]

2,6-Dimethoxy-1,1'-biphenyl

Similarity: 1.00

A136059 [19491-10-2]

2,2',6,6'-Tetramethoxy-1,1'-biphenyl

Similarity: 1.00

A331991 [70388-58-8]

2,2',6-Trimethoxy-1,1'-biphenyl

Similarity: 1.00

Precautionary Statements-General
Code	Phrase
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Code	Phrase
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Response
Code	Phrase
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P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
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P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
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P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
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P401
P402	Store in a dry place.
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P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
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H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
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H250	Catches fire spontaneously if exposed to air
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H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
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Health hazards
Code	Phrase
H300	Fatal if swallowed
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H311	Toxic in contact with skin
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H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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CAS No.: 3153-72-8

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