Home Cart Sign in  
Chemical Structure| 2932-65-2 Chemical Structure| 2932-65-2

Structure of 2932-65-2

Chemical Structure| 2932-65-2

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 2932-65-2 ]

CAS No. :2932-65-2
Formula : C11H14O
M.W : 162.23
SMILES Code : CC(C1=CC=C(CCC)C=C1)=O
MDL No. :MFCD00041359
InChI Key :ZNBVIYMIVFKTIW-UHFFFAOYSA-N
Pubchem ID :76236

Safety of [ 2932-65-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P280-P305+P351+P338

Application In Synthesis of [ 2932-65-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 2932-65-2 ]

[ 2932-65-2 ] Synthesis Path-Downstream   1~35

  • 3
  • [ 2932-65-2 ]
  • [ 64128-26-3 ]
  • 4
  • [ 103-65-1 ]
  • [ 108-24-7 ]
  • [ 2932-65-2 ]
  • 6
  • [ 2932-65-2 ]
  • [ 75-36-5 ]
  • [ 108298-96-0 ]
  • 7
  • [ 103-65-1 ]
  • [ 75-36-5 ]
  • [ 2932-65-2 ]
YieldReaction ConditionsOperation in experiment
With hydrogenchloride;aluminium chloride; In dichloromethane; water; (a) A solution of n-propylbenzene (24 g) and acetyl chloride (14.5 ml) in dichloromethane (80 ml) was added dropwise with cooling to a suspension of anhydrous aluminium chloride (27 g) in dichloromethane (70 ml). The resulting solution was stirred at room temperature for one hour and poured into ice/water (250 ml) containing concentrated hydrochloric acid (10 ml). The organic layer was separated and the aqueous layer was extracted with dichloromethane (3*50 ml). The combined organic fractions were washed with water and saturated aqueous ammonium chloride, dried (magnesium sulphate) and evaporated under reduced pressure to afford a yellow oil which was distilled under reduced pressure to afford 4-n-propyl acetophenone (26 g), b.p. 98 C. at 3 mm Hg.
aluminium trichloride; In carbon disulfide; Step A1: The production of 4-n-propylacetophenone Crushed anhydrous aluminium trichloride (1.28 mole) was suspended in dry carbon disulphide (348 ml). Acetylchloride (1.1 mole) and n-propylbenzene (1.0 mole) was dissolved in dry carbon disulphide (348 ml) and added to the suspension of aluminium trichloride under anhydrous conditions. The mixture was then left to stir overnight. The solvent was distilled from the reaction mixture and the viscous residue poured onto crushed ice and stirred for 0.5 hours. The product was extracted into ether and the extract washed with water and dried (Na2 SO4). The ether was removed by distillation and the oily residue distilled. The product had mpt 132 C. at 0.1 mm Hg.
  • 8
  • [ 2932-65-2 ]
  • [ 17356-08-0 ]
  • 4-(4-propyl-phenyl)-thiazol-2-ylamine [ No CAS ]
  • 9
  • [ 2932-65-2 ]
  • [ 100-63-0 ]
  • 1-(1-(4-propylphenyl)ethylidene)-2-phenylhydrazine [ No CAS ]
  • 10
  • [ 109-60-4 ]
  • [ 71-43-2 ]
  • [ 2932-65-2 ]
  • 11
  • [ 1121-60-4 ]
  • [ 2932-65-2 ]
  • (E)-1-(4-Propyl-phenyl)-3-pyridin-2-yl-propenone [ No CAS ]
  • 12
  • [ 2932-65-2 ]
  • [ 81423-83-8 ]
  • 1,3-Bis-(4-propyl-phenyl)-propane-1,3-dione [ No CAS ]
  • 13
  • [ 2932-65-2 ]
  • [ 21326-49-8 ]
  • 2-Dimethylimino-2-(4-propyl-phenyl)dithioacetat [ No CAS ]
  • 15
  • [ 2932-65-2 ]
  • [ 14333-93-8 ]
YieldReaction ConditionsOperation in experiment
80% To a solution of SeO2 (2.70 g, 0.02 mol), 1,4-dioxane (20 mL) and H2O (1 mL) (v:v=20:1),<strong>[2932-65-2]1-(4-propylphenyl)ethanone</strong> (2.00 g, 0.01 mol) was added, and the mixture was refluxedunder nitrogen for 9 h. The solid residue was removed by filtration. The solvent was removedunder reduced pressure. Water (20 mL) was added and the resulting mixture was heated toreflux for 5 h. Upon cooling to room temperature, the solution was extracted with ethylacetate and dried over Na2SO4 The organic layer was evaporated to dryness. The cruderesidue was isolated using silica gel chromatography and was eluted with PE/EtOAc (v:v=5:1)to give 2-oxo-2-(4-propylphenyl)acetaldehyde in a yield of 80%. Then 4-aminobenzoic acid(0.50 g, 3.65 mmol) was added to a solution of 2-oxo-2-(4-propylphenyl)acetaldehyde (0.64 g,3.65 mmol) in EtOH (20 mL), and the solution was stirred at room temperature overnight.The precipitated solid was obtained by filtration and purified by recrystallization from EtOHto give 6j as white solid in a yield of 13.6%.
With selenium(IV) oxide; In 1,4-dioxane; water; for 9h;Reflux; Inert atmosphere; Add selenium dioxide (2.7g, 0.02mol), 1-(4-propylphenyl) ethanone (2g, 0.01mol) to 1,4-dioxane (20mL) and water (1mL) ( v: v = 20: 1), reflux for 9 hours under nitrogen protection.After the reaction, cool to room temperature, remove the solid residue by filtration, spin-dry the solvent under reduced pressure, add 20mL of distilled water, and reflux under nitrogen for 5h. After the reaction, cool to room temperature, It was extracted three times with ethyl acetate, dried over anhydrous sodium sulfate, and the solvent was evaporated under reduced pressure. and purify the residue by silica gel column chromatography, petroleum ether: acetone (v: v = 5: 1) to obtain the crude product 2-oxo-2- (4-propylphenyl) acetaldehyde (13-1), yield 80%.The obtained 2-oxo-2- (4-propylphenyl) acetaldehyde (0.64g, 3.65mmol), 4-aminobenzoic acid (0.5g, 3.65mmol) was added to 20mL ethanol solution at room temperature overnight The reaction was filtered and the filter cake was recrystallized from ethanol to obtain a white solid with a yield of 13.6%.
  • 17
  • [ 2932-65-2 ]
  • [ 107-14-2 ]
  • 3-Methyl-3-(4-propyl-phenyl)-oxirane-2-carbonitrile [ No CAS ]
  • 18
  • [ 2932-65-2 ]
  • [ 141-78-6 ]
  • 1-(4-Propyl-phenyl)-butane-1,3-dione [ No CAS ]
  • 19
  • [ 2932-65-2 ]
  • [ 298-12-4 ]
  • [ 107549-80-4 ]
  • 20
  • [ 2932-65-2 ]
  • [ 109-94-4 ]
  • Sodium; (E)-3-oxo-3-(4-propyl-phenyl)-propen-1-olate [ No CAS ]
  • 22
  • [ 2932-65-2 ]
  • [ 75-31-0 ]
  • α-Isopropylamino-4-propyl-acetophenon [ No CAS ]
  • 24
  • [ 2932-65-2 ]
  • [ 33513-42-7 ]
  • [(Z)-3-Chloro-3-(4-propyl-phenyl)-allylidene]-dimethyl-ammonium; perchlorate [ No CAS ]
  • 25
  • [ 2932-65-2 ]
  • (S)-1-(p-n-propylphenyl)ethylamine [ No CAS ]
  • (R)-1-(4-Propyl-phenyl)-ethylamine [ No CAS ]
  • 26
  • [ 2932-65-2 ]
  • [ 52659-18-4 ]
  • <i>N</i>-[1,3-dioxo-2-(4-propyl-benzoyl)-indan-4-yl]-acetamide [ No CAS ]
  • 27
  • [ 454-31-9 ]
  • [ 2932-65-2 ]
  • 4,4-difluoro-1-(4-propyl-phenyl)-butane-1,3-dione [ No CAS ]
  • 28
  • [ 110-91-8 ]
  • [ 2932-65-2 ]
  • 2-(4-propylphenyl)-1-morpholin-4-yl-ethanethione [ No CAS ]
  • 29
  • [ 17745-45-8 ]
  • [ 99-90-1 ]
  • [ 2932-65-2 ]
  • 31
  • [ 2932-65-2 ]
  • [ 108-91-8 ]
  • Cyclohexyl-[1-(4-propyl-phenyl)-eth-(Z)-ylidene]-amine [ No CAS ]
  • 32
  • [ 2932-65-2 ]
  • [ 64328-67-2 ]
YieldReaction ConditionsOperation in experiment
44% With copper(ll) bromide; In ethyl acetate; for 8h;Reflux; To a solution of CuBr2 (6.88 g, 0.031 mol) in EtOAc(20 mL), 1-(4-propylphenyl) ethanone (2.00g, 0.012 mol) was added, and the mixture was refluxed for 8 h. The solid residue wasremoved by filtration. The solvent was washed with 5% H3PO4, water and brine, while theorganic layer was dried over Na2SO4. The crude residue was isolated using silica gelchromatography and was eluted with PE/ CH3COCH3 (v:v=200:1) to give2-bromo-<strong>[2932-65-2]1-(4-propylphenyl)ethanone</strong> in a yield of 44%. Then 4-aminobenzoic acid (0.50 g,3.65 mmol) was added to a solution of 2-bromo-<strong>[2932-65-2]1-(4-propylphenyl)ethanone</strong> (0.88 g, 3.65mmol) in EtOH (20 mL), and the solution was stirred at room temperature overnight. Theprecipitated solid was obtained by filtration to give 8b as yellow solid in a yield of 20%.
4.7 g With bromine; In chloroform; at 0℃; for 0.5h; To the stirred solution of <strong>[2932-65-2]4-propyl acetophenone</strong> (5.0 g, 30.0 mmol) in CHC13 (50 mL) was added bromine (4.9 g, 30.0 mmol) in CHC13 (10 mL) at 0 C and the mixture was stirred for another 30 mm at the same temperature. The reaction was monitored by TLC and aftercompletion of the reaction, sodium thiosulphate solution was added and was then subjected to a standard CH2C12 work-up to yield crude residue which was purified by column chromatography on silica gel using hexane: ethyl acetate (9: 1) to give 4.7 g of the desired product as a liquid.
With copper(ll) bromide; In ethyl acetate; for 8h;Reflux; Copper bromide (6.88g, 0.031mol), 1-(4-propylphenyl) ethanone (2g, 0.012mol) was added to ethyl acetate (20mL) and refluxed for 8 hours.After the reaction, the solution was cooled to room temperature, and the solid residue was removed by filtration. The filtrate was washed with 5% phosphoric acid solution, distilled water, and brine. The organic layer was dried over anhydrous sodium sulfate, filtered, and the organic solvent was spin-dried under reduced pressure. The residue was subjected to silica gel column chromatography Purification, petroleum ether: acetone (v: v = 200: 1) to give crude product 2-bromo-1- (4-propylphenyl) ethanone (27-1), yield 44%.The obtained 2-bromo-1- (4-propylphenyl) ethanone (0.88g, 3.65mmol) and 4-aminobenzoic acid (0.5g, 3.65mmol) were added to 20mL ethanol solution and reacted at room temperature overnight And filtered to obtain a yellow solid with a yield of 20%.
  • 33
  • [ 2932-65-2 ]
  • C19H27NO5 [ No CAS ]
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 2932-65-2 ]

Aryls

Chemical Structure| 785-78-4

A838037 [785-78-4]

1-(4-Phenethylphenyl)ethanone

Similarity: 1.00

Chemical Structure| 793-06-6

A391264 [793-06-6]

1,1'-(Ethane-1,2-diylbis(4,1-phenylene))diethanone

Similarity: 1.00

Chemical Structure| 37920-25-5

A514158 [37920-25-5]

4'-Butylacetophenone

Similarity: 0.96

Chemical Structure| 51772-30-6

A600794 [51772-30-6]

3'-Methylpropiophenone

Similarity: 0.96

Chemical Structure| 56147-30-9

A187960 [56147-30-9]

1-(4-Propylphenyl)propan-1-one

Similarity: 0.96

Ketones

Chemical Structure| 785-78-4

A838037 [785-78-4]

1-(4-Phenethylphenyl)ethanone

Similarity: 1.00

Chemical Structure| 793-06-6

A391264 [793-06-6]

1,1'-(Ethane-1,2-diylbis(4,1-phenylene))diethanone

Similarity: 1.00

Chemical Structure| 37920-25-5

A514158 [37920-25-5]

4'-Butylacetophenone

Similarity: 0.96

Chemical Structure| 51772-30-6

A600794 [51772-30-6]

3'-Methylpropiophenone

Similarity: 0.96

Chemical Structure| 56147-30-9

A187960 [56147-30-9]

1-(4-Propylphenyl)propan-1-one

Similarity: 0.96