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Chemical Structure| 26885-42-7 Chemical Structure| 26885-42-7

Structure of 26885-42-7

Chemical Structure| 26885-42-7

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Product Details of [ 26885-42-7 ]

CAS No. :26885-42-7
Formula : C16H9Br
M.W : 281.15
SMILES Code : BrC1=CC2=CC=CC(C3=CC=CC=C34)=C2C4=C1

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Application In Synthesis of [ 26885-42-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 26885-42-7 ]

[ 26885-42-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 867044-33-5 ]
  • [ 26885-42-7 ]
  • C35H22N2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
71% With palladium diacetate; caesium carbonate; XPhos; In 1,4-dioxane; at 90℃; for 8h;Inert atmosphere; Under an argon atmosphere, 2-bromofluoranthene (5.00 g, 17.8 mmol),[4- (2-phenylbenzimidazol-1-yl) phenyl] boronic acid (6.16 g, 19.6 mmol),Palladium acetate (0.160 g, 0.712 mmol),XPhos (2-dicyclohexylphosphino-2 ', 4', 6'-triisopropyl-1,1'-biphenyl)(0.678 g, 1.42 mmol),Cesium carbonate (11.6 g, 35.6 mmol),A mixture of 1,4-dioxane (70 mL) was stirred at 90 C. for 8 h. After completion of the reaction, the reaction mixture was cooled to room temperature, and the solvent was concentrated under reduced pressure.The crude product was purified by silica gel column chromatography,Compound 1 was obtained (5.95 g, yield 71%).
 

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