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CAS No. : | 2632-99-7 | MDL No. : | MFCD00129061 |
Formula : | C10H8N4 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | XUPMSLUFFIXCDA-UHFFFAOYSA-N |
M.W : | 184.20 | Pubchem ID : | 238589 |
Synonyms : |
|
Num. heavy atoms : | 14 |
Num. arom. heavy atoms : | 12 |
Fraction Csp3 : | 0.0 |
Num. rotatable bonds : | 2 |
Num. H-bond acceptors : | 4.0 |
Num. H-bond donors : | 0.0 |
Molar Refractivity : | 52.65 |
TPSA : | 50.5 Ų |
GI absorption : | High |
BBB permeant : | Yes |
P-gp substrate : | No |
CYP1A2 inhibitor : | Yes |
CYP2C19 inhibitor : | No |
CYP2C9 inhibitor : | No |
CYP2D6 inhibitor : | No |
CYP3A4 inhibitor : | No |
Log Kp (skin permeation) : | -6.32 cm/s |
Log Po/w (iLOGP) : | 1.91 |
Log Po/w (XLOGP3) : | 1.56 |
Log Po/w (WLOGP) : | 2.89 |
Log Po/w (MLOGP) : | 0.45 |
Log Po/w (SILICOS-IT) : | 2.64 |
Consensus Log Po/w : | 1.89 |
Lipinski : | 0.0 |
Ghose : | None |
Veber : | 0.0 |
Egan : | 0.0 |
Muegge : | 1.0 |
Bioavailability Score : | 0.55 |
Log S (ESOL) : | -2.47 |
Solubility : | 0.628 mg/ml ; 0.00341 mol/l |
Class : | Soluble |
Log S (Ali) : | -2.23 |
Solubility : | 1.08 mg/ml ; 0.00588 mol/l |
Class : | Soluble |
Log S (SILICOS-IT) : | -4.27 |
Solubility : | 0.00998 mg/ml ; 0.0000542 mol/l |
Class : | Moderately soluble |
PAINS : | 1.0 alert |
Brenk : | 1.0 alert |
Leadlikeness : | 1.0 |
Synthetic accessibility : | 2.32 |
Signal Word: | Danger | Class: | 6.1 |
Precautionary Statements: | P261-P264-P270-P271-P280-P301+P310+P330-P302+P352-P304+P340+P312-P305+P351+P338-P332+P313-P337+P313-P403+P233-P405-P501 | UN#: | 2811 |
Hazard Statements: | H301-H315-H319-H335 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
65% | In ethanol; N,N-dimethyl-formamide Zn salt added to a mixt. of DMF and EtOH contg. ligands, sealed, kept at100°C for 24 h; filtered, washed (DMF), dried (air); elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With sodium carbonate In ethanol; water at 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In ethanol |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
76% | In methanol at 80℃; for 2h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | In water; at 70 - 120℃; for 72.5h;High pressure; | The mixtures of <strong>[7500-53-0]o-phenylenediacetic acid</strong> (o-H2pda) (0.1 mmol, 0.018 g), Zn(CH3COO)2·2H2O (0.1 mmol, 0.02 g), 4,4?-azobis(pyridine) (abpy) (0.05 mmol, 0.009 g) and H2O (10 mL) were stirred at 70 C for 30 min. Then clear solution was placed in a Pyrex tube and heated at 120 C for 72 h. After cooling to room temperature, orange crystals of 1 were obtained and washed with 10 mL of water. Yield 56% (based on H2pda). Anal. Calc. for C30H24N4O8Zn2: C, 51.53; H, 3.46; N, 8.01. Found: C, 51.52; H, 3.61; N, 8.21%. IR (KBr, cm-1): 3045 w, 2939 w, 1622 m, 1575 s, 1557 vs 1416s, 1393 vs 1221 m, 1096w, 1048 w, 1014 w, 956 w, 844 m, 724 s, 698 m, 645 m, 571 m. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
72% | In ethanol; acetonitrile; for 0.0666667h; | In a manner analogous to 1 and 2, the synthesis of 3 was achieved by dissolving 25 mg of 4,4?-azopyridine in 2 mL of ethanol within a vial that was mixed with a 1 mL acetonitrile solution containing 14 mg of <strong>[2386-52-9]silver methanesulfonate</strong> (1:1 molar ratio). As seen previously, an immediate precipitate formed upon combining the two solutions. As a result, an additional 5 mL of acetonitrile and 1 mL of deionized water were added to dissolve the entire solid. The light reddish color solution was allowed to slowly evaporate which resulted in crystals suitable for X-ray diffraction after four days. Crystals of 3 were again removed from the remaining solvent and then dried in air to a constant mass of 28 mg a 72% yield. It is important to note that single crystals of 3 lose crystallinity within a few hours after being removed from the bulk solution. This fact made room temperature X-ray diffraction studies impossible. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
44% | In methanol; N,N-dimethyl-formamide; at 80 - 120℃; for 34h;Autoclave; High pressure; | A mixture of Ni(NO3)2·6H2O (150 mg, 0.5 mmol), <strong>[4251-21-2]1,4-phenylenedipropionic acid</strong> (220 mg, 1 mmol), 4,4?-azodipyridine (180 mg, 1 mmol) and 9 ml of mixed H2O/DMF/MeOH (1:1:1 v/v) was placed in a 25 ml Teflon-lined stainless steel. The vessel was sealed and heated at 80 C for 10 h and then continuously heated at 120 C for 24 h. After the mixture was slowly cooled to room temperature, greenish brown crystals of 1 were obtained. Yield: 112 mg (44%) based on Ni salt. Anal. Calc. For C22H22N4NiO6: C, 53.00; H, 4.46; N, 11.27%. Found: C, 52.91; H, 4.50; N, 11.12%. IR spectrum (KBr, cm-1): 3386s, 3210m, 2961m, 2914m, 2631s, 1956m, 1574s, 1552s, 1415s, 1383s, 1415s, 1383s, 1308s, 1227m, 1161m, 1017m, 985m, 957m, 865s, 846s, 799m, 676m, 620s, 571m, 551m, 480m. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
93% | In water; at 70 - 120℃; for 72.5h; | The mixture of H2ppda (0.1 mmol, 0.018 g), Zn(O2CMe)22H2O(0.1 mmol, 0.02 g), abpy (0.2 mmol, 0.018 g) and H2O (10 mL) wasstirred at 70 C for 30 min. Then clear solution was placed in a Pyrextube and heated at 120 C for 72 h. After cooling to room temperature,red crystals of 1 were obtained in 93% yield based on H2ppda(0.018 g). Anal. calcd. for C15H12N2O4Zn: C 51.53, H 3.46, N 8.01.Found: C 51.52, H 3.61, N 8.21. IR (KBr, cm-1): 3045 w, 2939 w, 1620s, 1525 s, 1380 vs, 1299 m, 1230 m, 1059 w, 1019 w, 951 w, 860 m,757 m. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
88% | at 70 - 120℃; for 72.5h; | The mixture of H2opda (0.1 mmol, 0.018 g), Cd(O2CMe)22H2O(0.1 mmol, 0.03 g), abpy (0.2 mmol, 0.018 g) and H2O (10 mL) wasstirred at 70 C for 30 min. Then clear solution was placed in a Pyrextube and heated at 120 C for 72 h. After cooling to room temperature,red crystals of 2 were obtained in 88% yield based on H2opda(0.018 g). Anal. calcd. for C15H14N2O5Cd: C 43.44, H 3.40, N 6.76.Found: C 43.50, H 3.63, N 6.80. IR (KBr, cm-1): 3335b, 3060 m,3032 m, 2904w, 1570vs, 1392vs, 1289 m, 1220 m,1161 m, 941 m,845 m, 730 s. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
41% | In methanol; N,N-dimethyl-formamide; at 20℃; for 72h;Sealed tube; | Compound 2 was synthesized by solvent diffusion method at room temperature. A dimethylformamide solution (3ml) of <strong>[4251-21-2]1,4-phenylenedipropionic acid</strong> (220mg, 1mmol) was layered on the solution (3ml) of Cu(NO3)2·3H2O (150mg, 0.5mmol). Then a methanol solution (3ml) of 4, 4-azobipyridyl (180mg, 1mmol) was layered on the mixture layer. Then, the vial was sealed and allowed to stand undisturbed at room temperature. After 3 days, greenish-brown block-shaped crystals were obtained. The crystals were separated, washed with water and dried in air. Yield: 125mg (41%) based on copper salt. Anal. Calcd for C22H24CuN4O6: C, 52.43; H, 4.80; N, 11.12%. Found: C, 52.47; H, 4.67; N, 11.10%. IR (KBr, cm-1): 1656(w), 1562(s), 1512(w), 1443(w), 1403(s), 1330(s), 1309(w), 1289(s), 1225(s), 1152(w), 1108(w), 1065(s), 873(w), 843(s), 823(w). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
71% | In water; N,N-dimethyl-formamide at 95℃; for 72h; Autoclave; High pressure; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
84% | at 110.0℃; for 48h; | Weigh H3TCA (4.1mg, 0.012mmol),Abp (4.6 mg, 0.025 mmol) and Cd(NO3)2·4H2O (17.2 mg, 0.056 mmol) in 10 ml screw glass vials,Add 5 ml of ethanol, and then place the glass vial in a hydrothermal synthesis reactor of polytetrafluoroethylene.The hydrothermal synthesis reactor was placed in a constant temperature drying oven and reacted at 110 C for 48 h.After the reaction was completed, it was cooled to obtain orange bulk crystals, which were filtered and washed with ethanol 5 times.Drying at 90 C for 7 h, a metal-organic framework material Cd-TCAA was obtained, yield: 84%.Its crystal structure is shown in Figure 1.It can be seen that the structure is a three-dimensional network structure with holes. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
82% | Stage #1: silver(l) oxide With ammonia; water In methanol for 0.5h; Stage #2: 1,2-bis(5-methylisoxazol-3-yl)hydrazine; nitrilotriacetic acid; water In methanol for 0.5h; | 2.3.1. Synthesis for [Ag3(nta)(azpy)3(H2O)]n·5H2O, (1) To a suspension of silver oxide (0.035 g, 0.15 mmol) in a mixture of water and methanol (2:5), an aqueous NH3 solution (0.5 ml, 25%) was added dropwise and stirred for 30 min to obtain a clear colourless solution. To this solution, nitrilotriacetic acid (0.019 g, 0.10 mmol) and 4,4′-azopyridine (0.055 g, 0.30 mmol) were added respectively. The reaction mixture was further stirred for 30 min and the clear red solution was kept for crystallization in dark. After a week, red, rectangular crystals were obtained. The crystals were filtered, washed (water and methanol) and dried under vacuum. Yield: 0.097 g, (82%). Calcd for C36H42N13O12Ag3: Calc(%) C 36.88; H 3.61; N 15.53, Found: C 36.37; H3.49; N 16.12. IR (cm-1): 3443(s, broad), 1640(s), 1588(s), 1411(s),1325(w), 1221(w), 1135(w), 1050(w), 992(w), 906(w), 834(m),572(m), 520(m). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
47% | In acetonitrile; at 120℃; for 72h;High pressure; | A mixture of Co(NO3)2·6H2O (29.1mg, 0.1mmol), 5-Br-H2ip (12.1mg, 0.05mmol), azpy (9.2mg, 0.05mmol), CH3CN (4mL) and H2O (4mL) was sealed in a 15mL Teflon-lined reactor and heated at 120C for 72h. Upon cooling to room temperature at a rate of 10Ch-1, red crystals were obtained in 47% yield based on 5-Br-H2ip. Anal. calcd for C36H26Br2Co2N8O10: C, 42.88; H, 2.59; N, 11.11. Found: C, 44.01; H, 2.20; N, 11.59%. IR (KBr, cm-1): 3218(w), 3140(w, nu FontWeight="Bold" FontSize="10" -H), 1625(m), 1581(s,nuas,OCO), 1381(s,nus,OCO), 1205(m), 1070(m), 987(m), 759(s, gamma FontWeight="Bold" FontSize="10" -H), 720(s, gamma FontWeight="Bold" FontSize="10" -H). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
60% | Stage #1: copper(II) nitrate trihydrate; 4,4′,4′′-[benzene-1,3,5-triyltris(ethyne-2,1-diyl)]tribenzoic acid In N,N-dimethyl-formamide for 0.166667h; Sonication; Stage #2: 1,2-bis(5-methylisoxazol-3-yl)hydrazine In N,N-dimethyl-formamide at 85℃; for 24h; Sealed tube; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
10% | Stage #1: copper(II) nitrate trihydrate; 4,4′,4′′-[benzene-1,3,5-triyltris(ethyne-2,1-diyl)]tribenzoic acid In N,N-dimethyl-formamide for 0.166667h; Sonication; Stage #2: 1,2-bis(5-methylisoxazol-3-yl)hydrazine In N,N-dimethyl-formamide at 85℃; for 8h; Sealed tube; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
89% | In water; at 90℃; for 72h;Autoclave; | A mixture of H2tda (0.100 mmol, 0.0172 g), azopy (0.200 mmol, 0.0368g) and Zn(NO3)2.6H2O (0.100 mmol, 0.0297 g) in 4 mL DMF and 2 mL H2O was sealed in a 23 mL Teflon-lined stainless autoclave and heated at 90 C for 3 days and subsequently cooled to room temperature at a rate of 2.5 C h-1. Pink block crystals of 1 were collected by washing with DMF several times and dried in air. Yield: 89% based on Zn. Anal. Calcd for C35H27N9O9Zn2S2: C 46.06; N 13.81; H 2.98. Found: C 46.48; N 13.47; H 3.24%. IR (KBr, cm-1): 3369w, 3041s, 2807s, 1641vs, 1563vs, 1382vs, 1306vs, 1162s, 1018m, 780s, 561m. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In methanol; acetonitrile at 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In tetrahydrofuran at 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
37% | In ethanol; water; N,N-dimethyl-formamide at 120℃; for 24h; | Preparation and characterization (pzdc)(dpe)2]NO3}n (1) and [Cu5(HPO4)2(pzdc)2(dpe)3](H2O)5}n (2) The mixture solution of Cu(NO3)23H2O (0.5mmol,0.1208 g), 1,2-di(pyridin-4-yl)diazene (0.5mmol, 0.092 g) andpyrazole-3,5-dicarboxylic acid (0.5mmol, 0.0871 g) in ethanol(2mL), DMF (2mL) and H2O (13mL) was sealed in a 25mLglass vial. The mixture solution was heated at 120 C for1 day and then slowly cooled down to room temperature.Blue crystals of 1 were obtained. Yield: 66mg (37%) based oncopper salt. Anal. Calcd for C25H17Cu2N11O7: C, 42.26; H,2.41; N, 21.68. Found: C, 42.36; H, 2.10; N, 21.55%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
26% | In ethanol; N,N-dimethyl-formamide at 120℃; for 24h; | Preparation and characterization (pzdc)(dpe)2]NO3}n (1) and [Cu5(HPO4)2(pzdc)2(dpe)3](H2O)5}n (2) The mixture solution of Cu3(PO4)22H2O (0.5mmol,0.2080 g), 1,2-di(pyridin-4-yl)diazene (0.5mmol, 0.092 g) andpyrazole-3,5-dicarboxylic acid (0.5mmol, 0.0871 g) in ethanol(2mL), DMF (2mL) and H2O (13mL) was sealed in a 25mLglass vial. The mixture solution was heated at 120 C for1 day and then slowly cooled down to room temperature.Blue crystals of 2 were obtained. Yield: 29mg (26%) based oncopper salt. Anal. Calcd for Cu5C46H44N10O21P2: C, 35.11; H,2.06; N, 16.38. Found: C, 35.72; H, 2.36; N, 16.67%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
86% | at 160℃; for 72h; High pressure; | 2.3.1. Synthesis of compound [Cd2(L1)2(L2)0.5(H2O)]n (1) [Cd2(L1)2(L2)0.5(H2O)]n (1) was synthesized hydrothermally bymixing Cd(NO3)24H2O (0.077 g, 0.25 mmol), L1 (pyrazole-3,5-dicarboxylicacid) (0.043 g, 0.25 mmol) and L2 (4,4-azopyridine) (0.046 g,0.25 mmol) in 3-4 mL of water. Then the mixture was transferred to a20 mL of teflon-lined Parr type acid digestion bomb. The desired compoundwas obtained as orange-colored crystals in a teflon-lined Parr aciddigestion bomb, at 160 C for 3 days followed by slow cooling at the rateof 5 C/h to room temperature. Yield ca: 0.086 g, 86% based on themetal. Anal calcd: for C15H8Cd2N6O9 in %: C, 28.07; H, 1.25; N, 13.10;Found: C, 28.09; H, 1.31; N, 13.06. IR (KBr disk, ν, cm 1): 1593 and1518 [νas(COO-)], 1411 [νs(COO-)], 1345 [νs(C-O)], 3248 [ν(N-H)],3400 [ν(N- -N)], 3069-3498 s.br [νs(O-H)] (Figs. S1, S2; see SupportingInformation). Experimentally measured powder X-ray diffractionpatterns matched well with the simulated ones indicating excellentphase purity of compound 1 (Fig. S3; see Supporting Information). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
82% | In N,N-dimethyl-formamide at 120℃; for 72h; High pressure; | 2.3.2. Synthesis of compound [Cd3(L1a)2(L2)2]H2O}n (2) Another Cd-based compound [Cd3(L1a)2(L2)2]H2O}n (2) has alsobeen synthesized by solvothermal synthesis. First, Cd(NO3)24H2O(0.077 g, 0.25 mmol), L1 (pyrazole-3,5 dicarboxylic acid) (0.043 g, 0.25mmol) and L2 (4,4-azopyridine) (0.046 g, 0.25 mmol) were mixed wellin ~ 4 mL of DMF-H2O (1:1) and then the mixture was transferred to a20 mL of teflon-lined Parr type acid digestion bomb. Yellowish whiteblock crystalline product was obtained by heating the mixture at 120 Ctemperature for 3 days followed by slow cooling to room temperature at5 C/h rate. Yield ca: 0.082 g, 82% based on the metal. Anal. calcd: forC30H18Cd3N12O9 in %: C, 34.95; H, 1.94; N, 16.31; Found: C, 34.91; H,1.92; N 16.41. IR (KBr disk, ν, cm 1): 1606 and 1523 [νas(COO-)], 1411[νs(COO-)], 1360 [νs(C-O)], 3269 [ν(N- -N)], 3103-3524 s.br[νs(O-H)] (Fig. S4; see Supporting Information). Experimentallymeasured powder X-ray diffraction patterns matched well with thesimulated ones indicating excellent phase purity of compound 2 (Fig. S5;see Supporting Information). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
65% | at 115℃; for 72h; Sealed tube; | Syntheses of [Co(azpy) (bps) (H2O)]DMF2.3H2O}n (1) A mixture of Co(NO3)26H2O (0.2 mmol, 0.058 g), 4,40-azopyridine(0.2 mmol, 0.036 g), H2bps 4, 40- bibenzoic acid-2, 20-sulfone(0.2 mmol, 0.061 g) and 4 mL of DMF and 2 ml of H2O was stirred for10 min. The mixture was then transferred and sealed into a Teflon reactor(23 mL), and heated at 115 C for 72 h. After that, the mixture was cooledto room temperature. Pink block crystals of 1 were washed by ethanol(3 10 mL), and dried in air at room temperature (yield: 65% based onCo). Anal. Calc. (%) for C27H296CoN5O103S: C 47.58, H 4.38, N 10.28;found (%): C 47.52, H 4.36, N 10.31. IR (KBr, cm1): 3375(w), 2360(w),1610(s), 1386(s), 1300(m), 1219(m), 1173(m), 1126(w), 1014(w), 928(w), 842(m), 742(w), 662(m), 597(w), 543(w), 443(w) |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
81% | With acetic acid In N,N-dimethyl-formamide at 110℃; for 48h; Autoclave; | Synthesis of [Ni(azobipy)(H2O)4](btdc) (II). A mixtureof Ni(NO3)26H2O (58.2 mg, 0.2 mmol), H2btdc(50.8 mg, 0.2 mmol), 4,4'-azobipyridyl (azobipy)(36.8 mg, 0.2 mmol), DMF (2.5 mL), water (2.5 mL),and glacial acetic acid (22 μL) was sealed in a Teflonreactor and heated in a steel autoclave at 110°C for48 h. The formed red crystals were washed with DMF(3 × 5 mL) and dried in air. The yield was 108 mg(81%). The composition and structure of the productwere determined by XRD.IR (ν, cm-1): 3291 br.m νs(O-H); 1603 m, 1564 sνas(C=O); 1514 m γ(-); 1439 s νs(C=O); 1420 m,1366 s νs(C=O); 1225 w, 1190 w, 1117 w, 1038 m,1038 m, 1022 w, 885 m, 845 m, 827 m, 781 s δoop(C-H); 696 m, 648 m, 575 s, 554 m, 532 w, 521 w, 498 w,461 w. For C20H20N4O8S2Ni Anal. calcd., %: C, 42.3 H, 3.6 N, 9.9Found, %: , 42.2 , 3.6 N, 9.9 |
Tags: 2632-99-7 synthesis path| 2632-99-7 SDS| 2632-99-7 COA| 2632-99-7 purity| 2632-99-7 application| 2632-99-7 NMR| 2632-99-7 COA| 2632-99-7 structure
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P315 | Get immediate medical advice/attention. |
P320 | |
P302 + P352 | IF ON SKIN: wash with plenty of soap and water. |
P321 | |
P322 | |
P330 | Rinse mouth. |
P331 | Do NOT induce vomiting. |
P332 | IF SKIN irritation occurs: |
P333 | If skin irritation or rash occurs: |
P334 | Immerse in cool water/wrap n wet bandages. |
P335 | Brush off loose particles from skin. |
P336 | Thaw frosted parts with lukewarm water. Do not rub affected area. |
P337 | If eye irritation persists: |
P338 | Remove contact lenses, if present and easy to do. Continue rinsing. |
P340 | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P341 | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P342 | If experiencing respiratory symptoms: |
P350 | Gently wash with plenty of soap and water. |
P351 | Rinse cautiously with water for several minutes. |
P352 | Wash with plenty of soap and water. |
P353 | Rinse skin with water/shower. |
P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. |
P361 | Remove/Take off immediately all contaminated clothing. |
P362 | Take off contaminated clothing and wash before reuse. |
P363 | Wash contaminated clothing before reuse. |
P370 | In case of fire: |
P371 | In case of major fire and large quantities: |
P372 | Explosion risk in case of fire. |
P373 | DO NOT fight fire when fire reaches explosives. |
P374 | Fight fire with normal precautions from a reasonable distance. |
P376 | Stop leak if safe to do so. Oxidising gases (section 2.4) 1 |
P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. |
P378 | |
P380 | Evacuate area. |
P381 | Eliminate all ignition sources if safe to do so. |
P390 | Absorb spillage to prevent material damage. |
P391 | Collect spillage. Hazardous to the aquatic environment |
P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301 + P312 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
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