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Chemical Structure| 2463-45-8 Chemical Structure| 2463-45-8

Structure of 2463-45-8

Chemical Structure| 2463-45-8

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Product Citations

Product Citations

Abraha, Yuel W. ; Jacobs, Francois J. F. ; Brink, Alice ; Langner, Ernst H. G. ;

Abstract: Direct mixing (de novo) and Solvent Assisted Ligand Exchange (SALE) are the main methods used for the synthesis of Mixed-Linker Zeolitic Imidazolate Frameworks (ML-ZIFs). ML-ZIFs with combined -NO2 and -Br/-Cl functionalities were prepared via both synthetic routes. Thereafter the CO2 uptake of the ML-ZIFs were compared, as well as their abilities to fixate CO2 with epoxide substrates. The de novo synthesis resulted in ML-ZIFs with SOD topologies, 60: 40 (-NO2: -Br/-Cl) functionality ratios, higher porosities, better thermal stability and higher CO2 uptake than equivalent SALE products. SALE resulted in smaller ML-ZIF crystallites, only ∼ 10% incorporation of -Br/-Cl functionalized imidazolate linkers, and phase change during activation. ML-ZIF-7Cl, obtained from direct mixing, resulted in the highest CO2 uptake (90 cm3 g-1), in line with its higher porosity. ML-ZIF-7Cl, in combination with tetrabutylammonium bromide (TBAB), showed a high catalytic activity (TOF of 446 h-1) for the fixation of CO2 with propylene oxide and was reusable for up to 4 cycles without loss in activity.

Keywords: Zeolitic imidazolate frameworks (ZIFs) ; Solvent assisted ligand exchange (SALE) ; De Novo synthesis ; CO2 uptake ; CO2 fixation

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Product Details of [ 2463-45-8 ]

CAS No. :2463-45-8
Formula : C4H5ClO3
M.W : 136.53
SMILES Code : O=C1OCC(CCl)O1
MDL No. :MFCD00022483
InChI Key :LFEAJBLOEPTINE-UHFFFAOYSA-N
Pubchem ID :253297

Safety of [ 2463-45-8 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H301-H335-H314
Precautionary Statements:P260-P264-P270-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P403+P233-P405-P501
Class:8(6.1)
UN#:2922
Packing Group:

Application In Synthesis of [ 2463-45-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

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