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Nickel
(2,2'-Bipyridine)nickel dichloride
Nickel

[ CAS No. 22775-90-2 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
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There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
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Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 22775-90-2
Chemical Structure| 22775-90-2
Structure of 22775-90-2 * Storage: {[proInfo.prStorage]}
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Quality Control of [ 22775-90-2 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 22775-90-2 ]

SDS Specification
Alternatived Products of [ 22775-90-2 ]

Product Details of [ 22775-90-2 ]

CAS No. :22775-90-2 MDL No. :MFCD00614884
Formula : C10H8Cl2N2Ni Boiling Point : -
Linear Structure Formula :- InChI Key :NSWRSAFGHPRHGG-UHFFFAOYSA-L
M.W : 285.78 Pubchem ID :155293741
Synonyms :

Calculated chemistry of [ 22775-90-2 ]

Physicochemical Properties

Num. heavy atoms : 15
Num. arom. heavy atoms : 12
Fraction Csp3 : 0.0
Num. rotatable bonds : 0
Num. H-bond acceptors : 0.0
Num. H-bond donors : 0.0
Molar Refractivity : 59.17
TPSA : 9.86 Ų

Pharmacokinetics

GI absorption : Low
BBB permeant : No
P-gp substrate : Yes
CYP1A2 inhibitor : No
CYP2C19 inhibitor : Yes
CYP2C9 inhibitor : No
CYP2D6 inhibitor : No
CYP3A4 inhibitor : Yes
Log Kp (skin permeation) : -5.55 cm/s

Lipophilicity

Log Po/w (iLOGP) : 0.0
Log Po/w (XLOGP3) : 3.51
Log Po/w (WLOGP) : -3.85
Log Po/w (MLOGP) : 1.49
Log Po/w (SILICOS-IT) : 0.72
Consensus Log Po/w : 0.37

Druglikeness

Lipinski : 0.0
Ghose : None
Veber : 0.0
Egan : 0.0
Muegge : 0.0
Bioavailability Score : 0.55

Water Solubility

Log S (ESOL) : -4.42
Solubility : 0.011 mg/ml ; 0.0000384 mol/l
Class : Moderately soluble
Log S (Ali) : -3.4
Solubility : 0.114 mg/ml ; 0.000398 mol/l
Class : Soluble
Log S (SILICOS-IT) : -2.29
Solubility : 1.45 mg/ml ; 0.00508 mol/l
Class : Soluble

Medicinal Chemistry

PAINS : 0.0 alert
Brenk : 0.0 alert
Leadlikeness : 1.0
Synthetic accessibility : 2.72

Safety of [ 22775-90-2 ]

Signal Word:Danger Class:9
Precautionary Statements:P501-P273-P260-P270-P264-P280-P391-P314-P337+P313-P305+P351+P338-P301+P312+P330 UN#:3077
Hazard Statements:H302-H319-H372-H410 Packing Group:Ⅲ
GHS Pictogram:

Application In Synthesis of [ 22775-90-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 22775-90-2 ]

[ 22775-90-2 ] Synthesis Path-Downstream   1~48

  • 1
  • [ 12080-32-9 ]
  • [ 55425-72-4 ]
  • [ 111-78-4 ]
  • [ 22775-90-2 ]
  • [ 12130-66-4 ]
Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2002,vol. 628,p. 20 - 30
  • 2
  • [ 12080-32-9 ]
  • [ 1295-35-8 ]
  • [ 111-78-4 ]
  • [ 22775-90-2 ]
  • [ 12130-66-4 ]
Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2002,vol. 628,p. 20 - 30
  • 3
  • [ 366-18-7 ]
  • nickel(II) chloride hexahydrate [ No CAS ]
  • [ 22775-90-2 ]
YieldReaction ConditionsOperation in experiment
In methanol; water; at 100.0℃; for 8.0h; Synthesis of [Ni(binol)(bpy)]CH3OH complex. Toa solution of NiCl26H2O (0.235 g, 1 mmol) in 10 mLof water was added 2,2′- bipyridine (0.154g, 1 mmol)in 10 mL of methanol dropwise with continuous stirring.The reaction was stirred at 100C under refl ux for8 h. To the mixture was added a solution of rac-H2binol(0.286 g, 1 mmol) and NaOH (0.08 g, 2 mmol) in 20 mLof water-alcohol (1 : 1 mixture) dropwise with continuousstirring. The reaction mixture was stirred at 50C for5 h. After cooling the yellow-brown colored solid formedwas fi ltered, fi rst washed with water-methanol (1 : 1 mixture)for several times, and then with ether and dried in avacuum. Analytically calculated for NiC31H24O3N2, %:yield 66, C 70.1, H 4.52, N 5.28. Found, %: C 69.98, H4.55, N 5.21. 13C NMR spectrum, 125 MHz DMSO-d6, δ,ppm: 79.5, 116.4, 119.9, 121.4, 124.1, 124.7, 125.2, 127.3127.7, 128.2, 129.1, 134.1, 136.6, 154.4, 160.8, 162.7.
Reference： [1]Journal of Organic Chemistry,2018,vol. 83,p. 15406 - 15414
[2]Russian Chemical Bulletin,2007,vol. 56,p. 935 - 942
[3]New Journal of Chemistry,1996,vol. 20,p. 659 - 667
[4]Green Chemistry,2018,vol. 20,p. 2250 - 2256
[5]Journal of Organic Chemistry,2019,vol. 84,p. 769 - 779
[6]New Journal of Chemistry,2020,vol. 44,p. 1082 - 1089
[7]Russian Journal of Applied Chemistry,2016,vol. 89,p. 63 - 69
    ,2016,vol. 89,p. 63 - 69,7
  • 4
  • [ 22775-90-2 ]
  • [ 106-38-7 ]
  • NiCl((C5H4N)2)(CH3C6H4) [ No CAS ]
Reference： [1]New Journal of Chemistry,1996,vol. 20,p. 659 - 667
  • 5
  • [ 79268-77-2 ]
  • [ 22775-90-2 ]
  • [ 15218-76-5 ]
Reference： [1]Bulletin of the Chemical Society of Japan,1981,vol. 54,p. 2010 - 2016
  • 6
  • [ 79268-77-2 ]
  • [ 107-13-1 ]
  • [ 22775-90-2 ]
  • [ 35025-05-9 ]
  • [ 74-85-1 ]
  • [ 106-97-8 ]
Reference： [1]Bulletin of the Chemical Society of Japan,1981,vol. 54,p. 2010 - 2016
  • 7
  • [ 366-18-7 ]
  • [ 22775-90-2 ]
  • [ 7681-11-0 ]
  • Ni(bip)2(H2O)2I2 [ No CAS ]
Reference： [1]Crystal Research and Technology,
    ,1988,vol. 23,p. 385 - 391
  • 8
  • [ 15218-76-5 ]
  • [ 612-23-7 ]
  • [ 22775-90-2 ]
  • o-Nitrobenzylnickelchlorid-(2,2'-dipyridyl) [ No CAS ]
Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,
    Zeitschrift fuer Anorganische und Allgemeine Chemie,1980,vol. 462,p. 177 - 184
[2]Zeitschrift fur Anorganische und Allgemeine Chemie,
    Zeitschrift fuer Anorganische und Allgemeine Chemie,1980,vol. 462,p. 177 - 184
  • 9
  • [ 15218-76-5 ]
  • [ 507-20-0 ]
  • [ 22775-90-2 ]
  • [ 74-84-0 ]
  • [ 75-28-5 ]
  • [ 115-11-7 ]
  • [ 106-97-8 ]
Reference： [1]Bulletin of the Chemical Society of Japan,1983,vol. 56,p. 2147 - 2153
  • 10
  • [ 15218-76-5 ]
  • [ 100-44-7 ]
  • [ 22775-90-2 ]
Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,
    Zeitschrift fuer Anorganische und Allgemeine Chemie,1980,vol. 462,p. 177 - 184
  • 11
  • [ 22775-90-2 ]
  • [ 53356-73-3 ]
  • [Ni(2,2'-bipyridine)(P2(2,4,6-triisopropylphenyl)2))] [ No CAS ]
Reference： [1]Russian Chemical Bulletin,2007,vol. 56,p. 935 - 942
  • 12
  • [ 108-86-1 ]
  • [ 22775-90-2 ]
  • C6H5Ni(bpy)Cl [ No CAS ]
Reference： [1]New Journal of Chemistry,1996,vol. 20,p. 659 - 667
  • 13
  • [ 22775-90-2 ]
  • [ 644-97-3 ]
  • [Ni(2,2'-bipyridine)(P2Ph2))] [ No CAS ]
Reference： [1]Russian Chemical Bulletin,2007,vol. 56,p. 935 - 942
  • 14
  • [ 366-18-7 ]
  • [ 22775-90-2 ]
  • [ 15186-68-2 ]
Reference： [1]Russian Chemical Bulletin,2007,vol. 56,p. 935 - 942
  • 15
  • [ 366-18-7 ]
  • nickel dichloride [ No CAS ]
  • [ 22775-90-2 ]
YieldReaction ConditionsOperation in experiment
81.93% In ethanol; General procedure: The complexes, Cu(Bipy)Cl2,Ni(Bipy)Cl2, Co(Bipy)Cl2 were prepared by mixing one equivalent of 2,2′-bipyridine in 30 mL of ethanol to one equivalent of respective metal chlorides in 15 mL of ethanol.
Reference： [1]Organometallics,1996,vol. 15,p. 2633 - 2639
[2]Organic Letters,2021,vol. 23,p. 7482 - 7486
[3]Asian Journal of Chemistry,2019,vol. 31,p. 1905 - 1912
[4]Organometallics,2010,vol. 29,p. 6002 - 6011
[5]Russian Chemical Bulletin,2005,vol. 54,p. 942 - 947
  • 16
  • Ni(2,2'-bipyridyl)3Cl2 [ No CAS ]
  • [ 22775-90-2 ]
  • Ni(bip)2Cl2 [ No CAS ]
  • Ni(bip)1.33Cl2 [ No CAS ]
Reference： [1]Crystal Research and Technology,
    ,1988,vol. 23,p. 385 - 391
  • 17
  • [ 12107-56-1 ]
  • [ 55425-72-4 ]
  • [ 111-78-4 ]
  • [ 57811-65-1 ]
  • [ 22775-90-2 ]
Reference： [1]Journal of Organometallic Chemistry,2006,vol. 691,p. 4868 - 4873
  • 18
  • [ 366-18-7 ]
  • [ 1295-35-8 ]
  • [ 12107-56-1 ]
  • [ 111-78-4 ]
  • [ 57811-65-1 ]
  • [ 22775-90-2 ]
Reference： [1]Journal of Organometallic Chemistry,2006,vol. 691,p. 4868 - 4873
  • 19
  • [ 366-18-7 ]
  • [ 1295-35-8 ]
  • [ 12145-47-0 ]
  • [ 111-78-4 ]
  • [ 57811-65-1 ]
  • [ 22775-90-2 ]
Reference： [1]Journal of Organometallic Chemistry,2006,vol. 691,p. 4868 - 4873
  • 20
  • [ 41114-50-5 ]
  • [ 22775-90-2 ]
Reference： [1]Journal of the Chemical Society. Chemical communications,1972,p. 1208
  • 21
  • C6H5CH2Ni(bpy)Cl [ No CAS ]
  • [ 22775-90-2 ]
  • [ 7440-02-0 ]
Reference： [1]Zeitschrift fur Chemie,1975,vol. 15,p. 32 - 32
[2]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Ni: Org.Verb.1, 1.1.1.1.1, page 10 - 26
  • 22
  • [ 22775-90-2 ]
  • [ 5144-89-8 ]
  • {Nibpyphan2}Cl2*6H2O [ No CAS ]
Reference： [1]Australian Journal of Chemistry,1962,vol. 15,p. 453 - 456
[2]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Ni: MVol.C1, 187, page 425 - 427
  • 23
  • [ 22775-90-2 ]
  • [ 1076-44-4 ]
  • [ 38192-72-2 ]
Reference： [1]Journal of Organometallic Chemistry,1964,vol. 2,p. 455 - 460
[2]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Ni: Org.Verb.1, 1.1.1.2.4.2, page 92 - 97
  • 24
  • [ 22775-90-2 ]
  • (η-5C5H5)Ni(bipy) [ No CAS ]
Reference： [1]Journal of the American Chemical Society,1981,vol. 103,p. 6219 - 6222
  • 25
  • [ 22775-90-2 ]
  • [ 53053-73-9 ]
  • 2,3,5,6-bis(o-carborano)-1,1-α,α'-dipyridylnickelous-4,4-dimethylsilacyclohexane [ No CAS ]
Reference： [1]Bulletin of the Academy of Sciences of the USSR Division of Chemical Science,1984,vol. 33,p. 2572 - 2573
    Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.),1984,vol. 33,p. 2807 - 2808
  • 26
  • [ 22775-90-2 ]
  • [ 66080-22-6 ]
  • 2,2'-bipyridylbis(pentafluorophenyl)nickel(II) [ No CAS ]
Reference： [1]Australian Journal of Chemistry,1983,vol. 36,p. 43 - 54
  • 27
  • [ 22775-90-2 ]
  • [ 72728-58-6 ]
  • 2,2'-bipyridylbis(2,3,5,6-tetrafluorophenyl)nickel(II) [ No CAS ]
Reference： [1]Australian Journal of Chemistry,1983,vol. 36,p. 43 - 54
  • 28
  • [ 366-18-7 ]
  • {NiCl(CClCCl2)(P(C6H5)3)2} [ No CAS ]
  • [ 22775-90-2 ]
  • [ 89486-79-3 ]
Reference： [1]Organometallics,1984,vol. 3,p. 996 - 1002
  • 29
  • [ 79354-84-0 ]
  • [ 22775-90-2 ]
  • [ 802294-64-0 ]
Reference： [1]Bulletin of the Chemical Society of Japan,1981,vol. 54,p. 2161 - 2168
  • 30
  • [ 22775-90-2 ]
  • [ 106-38-7 ]
  • [ 380231-02-7 ]
Reference： [1]Russian Chemical Bulletin,2002,vol. 51,p. 269 - 274
    Izvestiya Akademi Nauk, Seriya Khimicheskaya,2002,p. 256 - 261
  • 31
  • [ 22775-90-2 ]
  • [ 141-52-6 ]
  • [ 119327-18-3 ]
  • [ 436154-27-7 ]
Reference： [1]European Journal of Inorganic Chemistry,2002,p. 826 - 833
  • 32
  • [ 366-18-7 ]
  • [ 1295-35-8 ]
  • [ 90-13-1 ]
  • [ 22775-90-2 ]
  • [ 466645-96-5 ]
Reference： [1]Inorganica Chimica Acta,2002,vol. 334,p. 149 - 158
  • 33
  • [ 7647-01-0 ]
  • [ 225530-75-6 ]
  • [ 22775-90-2 ]
Reference： [1]Bulletin of the Chemical Society of Japan,2002,vol. 75,p. 1997 - 2009
  • 34
  • [ 22775-90-2 ]
  • [ 105858-66-0 ]
  • [ 177279-27-5 ]
Reference： [1]Organometallics,1996,vol. 15,p. 2633 - 2639
  • 35
  • [ 22775-90-2 ]
  • [ 576-83-0 ]
  • [ 104049-88-9 ]
Reference： [1]New Journal of Chemistry,1996,vol. 20,p. 659 - 667
  • 36
  • [ 22775-90-2 ]
  • [ 107658-48-0 ]
  • [ 685142-49-8 ]
Reference： [1]Inorganica Chimica Acta,2004,vol. 357,p. 1198 - 1204
  • 37
  • [ 12107-56-1 ]
  • [ 55425-72-4 ]
  • [ 111-78-4 ]
  • [ 22775-90-2 ]
  • [ 917346-04-4 ]
Reference： [1]Journal of Organometallic Chemistry,2006,vol. 691,p. 4868 - 4873
  • 38
  • [ 366-18-7 ]
  • [ 1295-35-8 ]
  • [ 12107-56-1 ]
  • [ 111-78-4 ]
  • [ 22775-90-2 ]
  • [ 917346-04-4 ]
Reference： [1]Journal of Organometallic Chemistry,2006,vol. 691,p. 4868 - 4873
  • 39
  • [ 498-66-8 ]
  • [ 12107-56-1 ]
  • [ 55425-72-4 ]
  • [ 22775-90-2 ]
  • [ 57205-95-5 ]
Reference： [1]Journal of Organometallic Chemistry,2006,vol. 691,p. 4868 - 4873
  • 40
  • [ 366-18-7 ]
  • nickel(II) dichloride hydrate [ No CAS ]
  • [ 22775-90-2 ]
Reference： [1]Zeitschrift fur Naturforschung, B: Chemical Sciences,2010,vol. 65,p. 1121 - 1127
  • 41
  • [ 22775-90-2 ]
  • [ 17148-97-9 ]
  • [ 1258938-68-9 ]
Reference： [1]Zeitschrift fur Naturforschung, B: Chemical Sciences,2010,vol. 65,p. 1121 - 1127
  • 42
  • [ 67-56-1 ]
  • [ 22775-90-2 ]
  • [ 602-09-5 ]
  • [Ni(1,1'-bi-2-naphtholate)(2,2-bipyridine)]*CH3OH [ No CAS ]
YieldReaction ConditionsOperation in experiment
With sodium hydroxide; In water; at 50.0℃; for 5.0h; Synthesis of [Ni(binol)(bpy)]CH3OH complex. Toa solution of NiCl26H2O (0.235 g, 1 mmol) in 10 mLof water was added 2,2′- bipyridine (0.154g, 1 mmol)in 10 mL of methanol dropwise with continuous stirring.The reaction was stirred at 100C under refl ux for8 h. To the mixture was added a solution of rac-H2binol(0.286 g, 1 mmol) and NaOH (0.08 g, 2 mmol) in 20 mLof water-alcohol (1 : 1 mixture) dropwise with continuousstirring. The reaction mixture was stirred at 50C for5 h. After cooling the yellow-brown colored solid formedwas fi ltered, fi rst washed with water-methanol (1 : 1 mixture)for several times, and then with ether and dried in avacuum. Analytically calculated for NiC31H24O3N2, %:yield 66, C 70.1, H 4.52, N 5.28. Found, %: C 69.98, H4.55, N 5.21. 13C NMR spectrum, 125 MHz DMSO-d6, δ,ppm: 79.5, 116.4, 119.9, 121.4, 124.1, 124.7, 125.2, 127.3127.7, 128.2, 129.1, 134.1, 136.6, 154.4, 160.8, 162.7.
Reference： [1]Russian Journal of Applied Chemistry,2016,vol. 89,p. 63 - 69
    ,2016,vol. 89,p. 63 - 69,7
  • 43
  • [ 22775-90-2 ]
  • [ 6117-80-2 ]
  • C14H15N2NiO2 [ No CAS ]
Reference： [1]Journal of Organic Chemistry,2018,vol. 83,p. 15406 - 15414
  • 44
  • [ 350-03-8 ]
  • [ 22775-90-2 ]
Reference： [1]Journal of Organic Chemistry,2019,vol. 84,p. 769 - 779
  • 45
  • [ 22775-90-2 ]
  • [ 100-51-6 ]
  • C17H15N2NiO [ No CAS ]
Reference： [1]Journal of Organic Chemistry,2019,vol. 84,p. 769 - 779
  • 46
  • [ 22775-90-2 ]
  • [ 5351-71-3 ]
  • [ 7732-18-5 ]
  • Ni(2,2'-bipyridine)(2-acetylthiophene thiosemicarbazone)*0.5H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
86.26% With sodium hydroxide; In ethanol; for 1.0h;Reflux; General procedure: A 1.2 g of ATT ligand (0.006 mol) was dissolved in 15 mL of 0.05 N NaOH in ethanol solvent in 100 mL beaker. A 1.0 g Cu(Bipy)Cl2 (0.003 mol) was dissolved in 15 mL of ethanol solvent in 100 mL beaker. Ligand solution and Cu(Bipy)Cl2 solution were transferred into 100 mL round bottom flask andheated under reflux for 1 h. On cooling the contents of flask,dark green coloured complex was formed. It was collected byfiltration, washed with small quantities of ethanol and driedin air. Ni(Bipy)ATT and Co(Bipy)ATT complexes are prepared similarly.
Reference： [1]Asian Journal of Chemistry,2019,vol. 31,p. 1905 - 1912
  • 47
  • [ 366-18-7 ]
  • nickel chloride monohydrate [ No CAS ]
  • [ 22775-90-2 ]
YieldReaction ConditionsOperation in experiment
88% In ethanol; for 4.5h;Reflux; Dissolve 1.48g of nickel chloride monohydrate in 25ml of ethanol with a mass concentration of 95%, place in a flask, heat to reflux, and dissolve 1.56g of 2,2'-bipyridine in 20ml of ethanol with a mass concentration of 95%, and add it with a dropping funnel For the above nickel chloride solution, the dropping time is controlled to 1.5h, and the reflux reaction is continued for 4h. The reaction mixture was cooled to room temperature and concentrated to 20ml. The solid that appeared was collected by filtration.And recrystallized in ethanol to obtain 2.51 g of precursor Ni(bpy)Cl2, with a yield of 88%.
Reference： [1]Patent: CN110787838,2021,B .Location in patent: Paragraph 0051; 0053
  • 48
  • [ 22775-90-2 ]
  • C20H18N4 [ No CAS ]
  • C40H34Cl4N8Ni2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
In ethanol; dichloromethane; at 50.0℃; for 10.0h; Dissolve 1.48g of nickel chloride monohydrate in 25ml of ethanol with a mass concentration of 95%, place in a flask, heat to reflux, and dissolve 1.56g of 2,2'-bipyridine in 20ml of ethanol with a mass concentration of 95%, and add it with a dropping funnel For the above nickel chloride solution, the dropping time is controlled to 1.5h, and the reflux reaction is continued for 4h. The reaction mixture was cooled to room temperature and concentrated to 20ml. The solid that appeared was collected by filtration.And recrystallized in ethanol to obtain 2.51 g of precursor Ni(bpy)Cl2, with a yield of 88%.Put 0.858g (3mmol) of Ni(bpy)Cl2 in a two-necked flask, add 50ml of absolute ethanol; dissolve the aforementioned ligand L0.377g (1.2mmol) in 20ml of dichloromethane, and add dropwise to the flask with a dropping funnel. Control the dripping time for 2h,Heat to 50C and stir for 8 hours, concentrate on a rotary evaporator to about 25ml, filter, wash with cold ethanol, and dry in the air. Recrystallize in ethanol/water mixed solution to obtain binuclear nickel complex [Ni(bpy)]2LCl4 (as shown in the structure of formula I, M is a nickel atom).
Reference： [1]Patent: CN110787838,2021,B .Location in patent: Paragraph 0045; 0047

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