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Chemical Structure| 22693-41-0 Chemical Structure| 22693-41-0

Structure of 22693-41-0

Chemical Structure| 22693-41-0

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Product Details of [ 22693-41-0 ]

CAS No. :22693-41-0
Formula : C15H24S
M.W : 236.42
SMILES Code : SC1=C(C(C)C)C=C(C(C)C)C=C1C(C)C
MDL No. :MFCD12026227
InChI Key :QLPCAAJSEQIZOP-UHFFFAOYSA-N
Pubchem ID :613579

Safety of [ 22693-41-0 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302+H312+H332-H314-H227
Precautionary Statements:P501-P261-P270-P210-P271-P264-P280-P370+P378-P362+P364-P303+P361+P353-P301+P330+P331-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405
Class:8
UN#:1760
Packing Group:

Application In Synthesis of [ 22693-41-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 22693-41-0 ]

[ 22693-41-0 ] Synthesis Path-Downstream   1~26

  • 2
  • [ 109-65-9 ]
  • [ 22693-41-0 ]
  • [ 78089-44-8 ]
  • 3
  • [ 22693-41-0 ]
  • [ 106-89-8 ]
  • [ 173912-27-1 ]
  • 4
  • [ 936-59-4 ]
  • [ 22693-41-0 ]
  • 1-Phenyl-3-[(2,4,6-triisopropylphenyl)sulfanyl]propan-1-one [ No CAS ]
  • 5
  • [ 102342-00-7 ]
  • [ 22693-41-0 ]
  • [ 111975-89-4 ]
  • [ 554-68-7 ]
  • 6
  • ammonium hexachlorotechnetate(IV) [ No CAS ]
  • [ 22693-41-0 ]
  • [ 75-05-8 ]
  • [ 113584-54-6 ]
  • 7
  • W(6+)*3Cl(1-)*CC(CH3)3(3-)*CH3OC2H4OCH3 = {Cl3(CH3OC2H4OCH3)WCC(CH3)3} [ No CAS ]
  • [ 22693-41-0 ]
  • [ 111975-83-8 ]
  • [ 554-68-7 ]
  • 8
  • [ 366-18-7 ]
  • [ 22693-41-0 ]
  • [ 7646-85-7 ]
  • [ 112043-96-6 ]
  • 9
  • [ 85129-39-1 ]
  • [ 22693-41-0 ]
  • {AsPh4}{TcO(2,4,6-triisopropylbenzenethiolate)4} [ No CAS ]
  • 10
  • diammonium hexachlorotechnetate(IV) [ No CAS ]
  • [ 22693-41-0 ]
  • Tc(2,4,6-triisopropylbenzenethiolate)3(pyridine)2 [ No CAS ]
  • 11
  • [ 10544-50-0 ]
  • [ 14760-22-6 ]
  • [ 22693-41-0 ]
  • [ 999-97-3 ]
  • ((iron)4(sulfur)4((2,4,6-triisopropylphenyl)thiolate)2((N,N,N',N'-tetramethylthiourea)2)) [ No CAS ]
  • 12
  • [ 22693-41-0 ]
  • mercury dichloride [ No CAS ]
  • [ 124511-91-7 ]
  • 13
  • (Et4N)[MoO2(OSiPh3)(benzene-1,2-dithiolate)] [ No CAS ]
  • [ 22693-41-0 ]
  • (Et4N)[MoO2(SC6H2-2,4,6-Pri3)(benzene-1,2-dithiolate)] [ No CAS ]
  • 14
  • [ 1270-98-0 ]
  • [ 22693-41-0 ]
  • [ 497944-01-1 ]
  • 15
  • [ 32370-42-6 ]
  • [ 22693-41-0 ]
  • [ 166280-37-1 ]
  • 16
  • [ 14760-22-6 ]
  • [ 22693-41-0 ]
  • [ 157590-41-5 ]
  • [ 950892-14-5 ]
  • 17
  • [ 22693-41-0 ]
  • [ 563-76-8 ]
  • S-2,4,6-triisopropylphenyl α-bromothiopropionate [ No CAS ]
  • 18
  • [ 22693-41-0 ]
  • [ 17261-28-8 ]
  • [ 1256639-75-4 ]
  • 19
  • [ 22693-41-0 ]
  • [ 79-04-9 ]
  • [ 1262984-79-1 ]
YieldReaction ConditionsOperation in experiment
89% With pyridine; dmap; In dichloromethane; at 0 - 20℃;Inert atmosphere; General procedure: Pyridine (2.5 mL, 5% v/v) was added dropwise to a stirred solution of chloroacetyl chloride (1.80 mL, 22.6 mmol), benzenethiol (2.0 mL, 19.5 mmol) and a catalytic amount of DMAP in CH2Cl2 (50 mL) at 0 C. The mixture was stirred at 0 C for 15 min, then warmed to rt and allowed to stir overnight. The reaction was quenched by the addition of saturated aqueous NH4Cl (15 mL), diluted in EtOAC (200 mL), H2O added to just dissolve the formed precipitate (5 mL), organic phase washed with H2O (2 x 10 mL), brine, dried over MgSO4 and evaporated. Flash chromatography over silica gel, using 5:95 EtOAc-hexanes gave 13 (3.45 g; 95%) as a pure, white solid. Spectroscopic data was identical to that previously reported {1,2}. S-(2,4,6-triisopropyl)phenyl α-chlorothioacetate (15). Flash chromatography over silica gel, using 3:97 EtOAc-hexanes gave 15 (0.353 g; 89%) as a pure, pale yellow solid.
  • 20
  • [ 14760-22-6 ]
  • [ 22693-41-0 ]
  • [ 108-88-3 ]
  • Fe3(N(SiMe3)2)2(μ-S(2,4,6-(i)Pr3C6H3)4*toluene [ No CAS ]
  • 21
  • [ 22693-41-0 ]
  • [ 190121-82-5 ]
  • 22
  • [ 32775-95-4 ]
  • [ 22693-41-0 ]
  • S-(2,4,6-triisopropylphenyl) (E)-hexa-3,5-dienethioate [ No CAS ]
  • 23
  • [ 144-49-0 ]
  • [ 22693-41-0 ]
  • S-(2,4,6-triisopropylphenyl) 2-fluoroethanethioate [ No CAS ]
YieldReaction ConditionsOperation in experiment
73% With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0℃; for 10h;Inert atmosphere; General procedure: Under a N2 atmosphere, dicyclohexylcarbodiimide (1.2 mmol) in DCM (10 mL) was added dropwisely to a mixture of the specific thiol (1.0 mmol), 2-fluoroacetic acid (1.2 mmol), 4-dimethylaminopyridine (0.2 mmol) at 0 C. The reaction mixture was kept stirring for 10 h at 0 C and concentrated under a reduced pressure. The residue was purified by flash column chromatography on silica gel (petroleum ether/ethyl acetate = 30:1) to give the corresponding 2-fluorothioesters 2. Caution: the reaction should be carried out in a well-ventilated hood because of the highly toxic nature of 2-fluoroacetic acid derivatives.
  • 24
  • [ 872-85-5 ]
  • [ 22693-41-0 ]
  • C21H27NOS [ No CAS ]
  • 25
  • [ 247043-59-0 ]
  • [ 1211417-77-4 ]
  • [ 22693-41-0 ]
  • (4-benzamido-4-oxobutan-2-yl)(1,3-dimethyl-1H-imidazol-3-ium-2-yl)dihydroborate [ No CAS ]
  • 26
  • [ 22693-41-0 ]
  • [ 814-68-6 ]
  • thioacrylic acid 2,4,6-triisopropyl-phenyl ester [ No CAS ]
 

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