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Chemical Structure| 19102-92-2 Chemical Structure| 19102-92-2

Structure of 19102-92-2

Chemical Structure| 19102-92-2

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Product Details of [ 19102-92-2 ]

CAS No. :19102-92-2
Formula : C19H36O4
M.W : 328.49
SMILES Code : O=C(OC)CCCCCCCCCCCCCCCC(OC)=O

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Application In Synthesis of [ 19102-92-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 19102-92-2 ]

[ 19102-92-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 19102-92-2 ]
  • [ 72849-42-4 ]
YieldReaction ConditionsOperation in experiment
83.7% With methanol; barium(II) hydroxide; at 10 - 25℃; for 34.0h;Inert atmosphere; To a suspension of compound 10b (3.02 g, 9.19 mmol) in MeOH (12.0 mL ) was added a solution of Ba(OH)2 (866 mg, 5.05 mmol) in MeOH (12 mL ) at 10-20 C under N2 atmosphere and kept stirred at 15-25 C for 22 hou rs under N2 atmosphere. 1 H NMR showed the compound 10b was retained (one drop reaction solution was added to a drop 12 M HCI, then determined by 1 H NMR). The reaction mixture was stirred at 15-25 C for 12 hours under N2 atmosphere. 1 H NMR showed the most compound 10c was found (one drop reaction solution was added to a drop 12 M HCI, then determined by 1 H NMR). The reaction mixture was filtered and the filter cake was suspension in 4 M HCI solution (15 mL ) at 15-25 C and kept stirred at 15-25 C for 30 mins, then the mixt ure was filtered and filter cake was dried under reduced pressure to give compound 10c (2.42 g, 7.70 mmol, 83.7% yield) as a white solid, which was confirmed by 1 H NMR. 1H NMR: 400 MHz, CDCI3 δ 3.60 (s, 3H), 2.19-2.33 (m, 4H), 1.48-1.63 (m, 4H), 1.12-1.33 (m, 22H).
 

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