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Chemical Structure| 1445085-55-1 Chemical Structure| 1445085-55-1
Chemical Structure| 1445085-55-1

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Product Details of Xphos Pd G3

CAS No. :1445085-55-1
Formula : C46H62NO3PPdS
M.W : 846.45
SMILES Code : NC1=CC=CC=C1C2=CC=CC=C2[Pd+].O=S([O-])(C)=O.CC(C)C3=CC(C(C)C)=CC(C(C)C)=C3C4=C(P(C5CCCCC5)C6CCCCC6)C=CC=C4
MDL No. :MFCD22417234

Safety of Xphos Pd G3

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of Xphos Pd G3

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1445085-55-1 ]

[ 1445085-55-1 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 1445085-50-6 ]
  • [ 1445085-55-1 ]
  • 2
  • di(2-(2′-amino-1,1′-biphenyl))palladium(II) methanesulfonate dimer [ No CAS ]
  • [ 564483-18-7 ]
  • [ 1445085-55-1 ]
YieldReaction ConditionsOperation in experiment
92% In tetrahydrofuran; at 20.0℃; for 0.75h;Inert atmosphere; A 300-mL round-bottomed flask equipped with a stir bar and rubber septum was charged with mu-OMs dimer 3 (11.92 g, 15.25 mmol, 0.50 eq) and XPhos (14.52 g, 30.5 mmol, 1.00 eq). The flask was evacuated under vacuum and backfilled with argon (this procedure was repeated twice), after which THF (120 mL) was added. The reaction mixture was stirred at room temperature for 45 min. After removal of 90% of the solvent under vacuum the product was precipitated from pentane to afford the title compound as an off-white solid as the 1:1 THF complex. THF could be removed by dissolving the solid in DCM and reprecipitating with pentane. Yield: 25.5 g, 92%. FIG. 7. [0295] FIG. 8 tabulates the % yield of various precatalysts formed using the procedures outlined above.
  • 3
  • potassium iodomethyltrifluoroborate [ No CAS ]
  • [ 1445085-55-1 ]
  • C30H47BF3PPd [ No CAS ]
 

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