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Chemical Structure| 14444-77-0 Chemical Structure| 14444-77-0

Structure of 14444-77-0

Chemical Structure| 14444-77-0

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Product Details of [ 14444-77-0 ]

CAS No. :14444-77-0
Formula : C11H16O3
M.W : 196.24
SMILES Code : CCOC(OCC)OC1=CC=CC=C1
MDL No. :MFCD00009228
Boiling Point : No data available

Safety of [ 14444-77-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H227-H315-H319
Precautionary Statements:P210-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P370+P378-P403+P235-P501

Application In Synthesis of [ 14444-77-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 14444-77-0 ]

[ 14444-77-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 14444-77-0 ]
  • [ 109-54-6 ]
  • [ 1116-77-4 ]
YieldReaction ConditionsOperation in experiment
72.7% Into a 2L three-necked round bottom flask was added magnesium turnings (25gr) under nitrogen atmosphere and [50ML] of the above benzene solution added to the reaction flask. After adding a small crystal of iodine, reaction mass was heated to reflux temperature. After maintaining for 15 min, reaction got initiated and to the reaction mass remaining quantity of benzene solution was added slowly in 2-3hrs period. After the addition, reaction mass was maintained for lhr and a solution of phenyl diethyl orthoformate (171gr) in benzene [(200ML)] was added slowly over a period of lhr. After maintaining for 2hrs, reaction was cooled to [25C] and filtered on a celite pad. Solvent was removed from the reaction mass and the residue fractionally distilled to get 120gr (72.7%) [OF 4- (N,] N- dimethylamino) butyraldehyde diethyl acetal.
 

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