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Chemical Structure| 13603-62-8 Chemical Structure| 13603-62-8

Structure of 13603-62-8

Chemical Structure| 13603-62-8

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Product Details of [ 13603-62-8 ]

CAS No. :13603-62-8
Formula : C9H12O2
M.W : 152.19
SMILES Code : OC(C1=CC=C(C)C=C1)CO
MDL No. :MFCD09743653

Safety of [ 13603-62-8 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501

Application In Synthesis of [ 13603-62-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 13603-62-8 ]

[ 13603-62-8 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 13603-62-8 ]
  • [ 4079-54-3 ]
YieldReaction ConditionsOperation in experiment
89% With N-Bromosuccinimide; In methanol; water; at 20℃; for 5.5h;Green chemistry; General procedure: Aromatic alcohol (1-2 mmol) was dissolved in methanol (or acetone in somecases, 2-4 mL) at room temperature, followed by addition of the aqueous solutionof N-bromosuccinimide (1.5 eq.=alcohol) with continuous stirring. GMP-b-CD (3,100mg=mmol of alcohol) were added in the reaction mixture and stirring was continued.Progress of the reaction was monitored by TLC until the reaction was completed(4-6 h). GMP was separated by filtration after completion of the reaction. Thereaction mixture was extracted with ethyl acetate (45 mL), combined organiclayers were dried over Na2SO4, and solvent was removed under reduced pressure.The product was further purified by flash column chromatography and analyzedby NMR spectroscopy.
  • 3
  • [ 13603-62-8 ]
  • [ 4079-54-3 ]
  • [ 139016-20-9 ]
 

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