There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
* Storage: Keep in dark place,Inert atmosphere,Room temperature
* Shipping: Normal
CAS No. : | 123652-95-9 | MDL No. : | MFCD04116360 |
Formula : | C8H10FNO | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | AZHAJNNLBSKSOB-UHFFFAOYSA-N |
M.W : | 155.17 | Pubchem ID : | 14392588 |
Synonyms : |
Signal Word: | Danger | Class: | 8 |
Precautionary Statements: | P264-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P403+P233-P501 | UN#: | 2735 |
Hazard Statements: | H314 | Packing Group: | Ⅲ |
GHS Pictogram: | ![]() |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
2[00319] A solution of compound 8 (2.0 g, 9.6 mmol) in SOd2 was refluxed for 2h. Thenconcentrated and re-dissolved in dichloromethane (10 mL), which was added to another solution of the amine 2(1.2 g, 7.5 mmol) and TEA (0.96 g, 70 mmol) in dichloromethane (15 mL) at 0 C. After stirring overnight at room temperature, the reaction mixture was then poured into water and extracted with dichloromethane. The combined organic extracts were washed with brine, water and dried over Na2SO4, filtered and evaporated in vacuum. The resulting yellow solid was purified by flash colunm chromatography to provide the title compound 9 as a pale white solid(450 mg). ‘H NMR (400 MHz, CDC13): 3 8.45 (t, J = 2.8 Hz, 1H), 7.51 (d, J = 5.2 Hz, 1H), 7.10- 7.06 (m, 2H), 6.92 (dd, J1 = 11.2 Hz, J2 = 8.0 Hz, 1H), 4.58 (d, J = 5.6 Hz, 2H), 3.89 (s, 3H); mlz (ESI+) (M+H)+ = 347.05. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
90% | With Raney-Nickel; In methanol; at 20℃; | Example 2.1.1: Preparation of (3-fluoro-4-methoxyphenyl)methanamine (ICb). (0658) To a solution of <strong>[331-62-4]3-fluoro-4-methoxybenzonitrile</strong> ICa (68.0 g, 450 mmol, 1 eq) in methanol (2 L) was added Raney-Nickel (Raney, Ni; 70.0 g). After completion of addition, the reaction mixture stirred at room temperature overnight. A solid formed, which was removed by filtration, and washed with methanol. The clear filtrate was concentrated at reduced pressure to obtain (3-fluoro-4-methoxyphenyl)methanamine (62.8 g, 90percent) as a yellow oil. |
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