[ CAS No. 1050912-62-3 ] {[proInfo.proName]}

Name: 1050912-62-3|5-((4-Carboxybenzyl)oxy)isophthalic acid|97%
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SKU: A418811
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Quality Control of [ 1050912-62-3 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 1050912-62-3 ]

SDS Specification

Alternatived Products of [ 1050912-62-3 ]

Product Details of [ 1050912-62-3 ]

CAS No. :	1050912-62-3	MDL No. :
Formula :	C₁₆H₁₂O₇	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	GOZATJNCMKPSAV-UHFFFAOYSA-N
M.W :	316.26	Pubchem ID :	45303369
Synonyms :

Safety of [ 1050912-62-3 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1050912-62-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 1050912-62-3 ]

[ 1050912-62-3 ] Synthesis Path-Downstream 1~26

1
[ 1050912-62-3 ]
[ 5743-04-4 ]
poly[bis(5-(((4-oxidocarbonyl)benzyl)oxy)isophthalato)di(μ2-aqua)tricadmium(II) trihydrate] [ No CAS ]

Reference： [1]Inorganic Chemistry Communications,2011,vol. 14,p. 986 - 989

2
[ 1050912-62-3 ]
[ 7732-18-5 ]
[ 5970-45-6 ]
[ 25372-07-0 ]
[Zn₃(5-(4-carboxybenzyloxy)isophthalic acid(-3H))2(1,4-bis(1H-imidazol-1-yl)benzene)2]*5H₂O [ No CAS ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2011,vol. 637,p. 1414 - 1418

3
[ 553-26-4 ]
[ 1050912-62-3 ]
[ 5970-45-6 ]
[Zn(5-(4-carboxybenzyloxy)isophthalic acid(-2H))(4,4'-bipyridine)1.5] [ No CAS ]

Reference： [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2011,vol. 637,p. 1414 - 1418

4
zinc(II) nitrate hexahydrate [ No CAS ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
[ 25372-07-0 ]
0.5C₁₂H₁₀N₄*Zn⁽²⁺⁾*C₁₆H₁₀O₇^(2-)*H₂O [ No CAS ]

Reference： [1]CrystEngComm,2013,vol. 15,p. 8214 - 8221

5
zinc(II) nitrate hexahydrate [ No CAS ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
[ 25372-07-0 ]
3C₁₂H₁₀N₄*3Zn⁽²⁺⁾*2C₁₆H₉O₇^(3-)*8H₂O [ No CAS ]

Reference： [1]CrystEngComm,2013,vol. 15,p. 8214 - 8221

6
zinc(II) nitrate hexahydrate [ No CAS ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
[ 25372-07-0 ]
3C₁₂H₁₀N₄*3Zn⁽²⁺⁾*2C₁₆H₉O₇^(3-)*4H₂O [ No CAS ]

Reference： [1]CrystEngComm,2013,vol. 15,p. 8214 - 8221

7
[ 1050912-62-3 ]
[ 6147-53-1 ]
[Co₂(5-(benzonic-4-ylmethoxy)isophthalic acid-H₃)(OH)(H₂O)]*1.5H₂O [ No CAS ]

Reference： [1]European Journal of Inorganic Chemistry,2014,vol. 2014,p. 6205 - 6211

8
[ 288-88-0 ]
[ 1050912-62-3 ]
[ 6147-53-1 ]
[Co₄(5-(benzonic-4-ylmethoxy)isophthalic acid-H₂)((benzonic-4-ylmethoxy)isophthalic acid-H₃)(1,2,4-triazole)₃(H₂O)]*6H₂O [ No CAS ]

Reference： [1]European Journal of Inorganic Chemistry,2014,vol. 2014,p. 6205 - 6211

9
[ 288-88-0 ]
[ 1050912-62-3 ]
[ 6147-53-1 ]
[Co₃(5-(benzonic-4-ylmethoxy)isophthalic acid-H₂)₂(1,2,4-triazole)₂(H₂O)₂] [ No CAS ]

Reference： [1]European Journal of Inorganic Chemistry,2014,vol. 2014,p. 6205 - 6211

10
[ 1050912-62-3 ]
cobalt nitrate hydrate [ No CAS ]
[Co(5-(benzonic-4-ylmethoxy)isophthalic acid-H₂)(H₂O)] [ No CAS ]

Reference： [1]European Journal of Inorganic Chemistry,2014,vol. 2014,p. 6205 - 6211

11
[ 66-71-7 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
3Cd⁽²⁺⁾*3C₁₆H₁₀O₇^(2-)*3C₁₂H₈N₂*4.5H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
76%	With nitric acid; In N,N-dimethyl-formamide; at 20 - 100℃; for 15h;pH 4;Sealed tube;	Cd(NO3)24H2O (0.2 mmol, 43.9 mg), H3L (0.1 mmol, 31.6 mg), 1,10-phen (0.15 mmol, 29.7 mg), DMF (3 mL) and H2O (3 mL) were mixed and stirred for 3 h at room temperature. Then, the final mixture was sealed in a Pyrex flask and heated at 100C for 12 h. The reactor was subsequently cooled down to room temperature. Colorless block-like crystals (yield: 76% based on H3L ligand)suitable for X-ray diffraction were obtained after filtration and washing with distilled water. Anal. Calc. for C84H69N6O25.5Cd3(1907.65): C, 52.84; H, 3.62; N, 4.40. Found: C, 52.56; H, 3.18;N, 4.25%. IR data (KBr, cm1): 3473(s), 3089(vw), 3048(vw), 2923(vw), 1680(vs), 1614(s), 1548(vs), 1450(s), 1318(s). UV-Vis data(nm): 216, 262, 301, 334, 469, 1007.

Reference： [1]Inorganica Chimica Acta,2016,vol. 440,p. 69 - 76

12
[ 66-71-7 ]
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 1050912-62-3 ]
C₅₆H₃₈CoN₄O₁₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
88%	With nitric acid; In water; N,N-dimethyl-formamide; at 20 - 100℃; for 14h;pH 4;	A mixture of Co(NO3)26H2O (0.1 mmol, 29.0 mg), 1,10-phen (0.15 mmol, 29.7 mg), H3L ligand (0.1 mmol, 31.6 mg), distilled water (9 mL) and DMF (6 mL) were put in a glass vessel and stirred for 2 h at room temperature. Adjust the pH value with 5 mol/LHNO3 till the solution in the glass vessel become clear liquid (pH4). Then the solution was transferred to a Pyrex flask and kept at 100C for 12 h. After filtration and washing with distilled water, orange crystals were obtained with yield of 88% based on Co(II).Anal. Calc. for C56H38N4O14Co (1049.83): C, 64.01; H, 3.62; N,5.33. Found: C, 64.19; H, 4.05; N, 5.12%. IR data (KBr, cm1):3445(s), 3093(vw), 2929(vw), 1713(vs), 1653(vs), 1581(vs), 1417(s), 1307(v). UV-Vis data (nm): 211, 266, 309, 368.

Reference： [1]Inorganica Chimica Acta,2016,vol. 440,p. 69 - 76

13
[ 51-17-2 ]
[ 1050912-62-3 ]
[ 7440-48-4 ]
[Co(HL)(benzimidazole)] [ No CAS ]

Reference： [1]Inorganic Chemistry Communications,2018,vol. 95,p. 27 - 31

14
[ 51-17-2 ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
[ 7440-48-4 ]
[Co₂(L)(benzimidazole)(OH)]·H₂O [ No CAS ]

Reference： [1]Inorganic Chemistry Communications,2018,vol. 95,p. 27 - 31

15
[ 1050912-62-3 ]
[ 1399248-32-8 ]
silver nitrate [ No CAS ]
2C₁₅H₁₂N₈*3Ag⁽¹⁺⁾*C₁₆H₉O₇^(3-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In water; at 120℃; for 72h;High pressure; Autoclave;	A mixture of AgNO3 (0.051 g, 0.3 mmol), H2L (0.032 g, 0.1 mmol), 2,4′-tmbpt (0.061 g, 0.2 mmol) and 10 mL H2O was sealed in a 20-mL Teflon reactor and heated at 120 C for 3 days. After cooling to room temperature unaffectedly, three kinds of colorless block crystals including compound 2 were collected.

Reference： [1]Journal of the Iranian Chemical Society,2019,vol. 16,p. 2021 - 2029

16
[ 1050912-62-3 ]
[ 1399248-32-8 ]
manganese(II) acetate [ No CAS ]
2C₁₅H₁₂N₈*2C₁₆H₉O₇^(3-)*3Mn⁽²⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
36%	In water; at 120℃; for 72h;High pressure; Autoclave;	A mixture of Mn(CH3COO)2 (0.026 g, 0.15 mmol), H2L (0.032 g, 0.1 mmol), 2,4′-tmbpt (0.030 g, 0.1 mmol) and10 mL H2O was sealed in a 20-mL Teflon reactor and heated at 120 C for 3 days. After cooling to room temperature unaffectedly, pale yellow block crystals of compound 3 were collected in a 36% yield. Anal. Calcd for C62H42N16O14Mn3 (Mr = 1399.94): C, 53.19; H, 3.03; N, 16.01. Found: C, 53.07; H, 3.01; N, 15.89. IR (υ, cm-1): 3109 (w), 1614 (m), 1542 (s), 1390 (m), 1362 (m), 1271 (s), 1175 (s), 1128 (w), 1061 (w), 1018 (w), 962 (w), 853 (w), 761 (w), 714 (w), 696 (w), 632 (w), 582 (w), 531 (w),418 (w).

Reference： [1]Journal of the Iranian Chemical Society,2019,vol. 16,p. 2021 - 2029

17
[ 553-26-4 ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
[ 33513-42-7 ]
potassium hydroxide [ No CAS ]
[ 7646-85-7 ]
poly[diaquatetrakis(4,4'-bipyridine)bis[μ₆-5-(4-carboxylatobenzyloxy)isophthalato]di-μ₃-formato-di-μ₃-hydroxidopentazinc(II)] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
60%	at 160℃; for 72h;Autoclave; High pressure;	A mixture of H3L (0.10 mmol, 31.6 mg), ZnCl2(0.15 mmol, 20.5 mg), 4,40-bipyridine (bpy; 0.2 mmol, 31.2 mg)and KOH (1 ml, 0.2 M) in H2O/DMF (8 ml, 3:1 v/v) wasplaced in a 25 ml Teflon-lined stainless steel vessel and heatedat 160 C for 3 d. Colourless rod-shaped crystals were washedwith distilled water and vacuum dried to give (III) in 60%yield. The pH value was close to 7 for the final reactionsystem. Elemental analysis calculated (%) for C74H58N8-O22Zn5: C 51.08, H 3.34, N 6.44; found: C 50.10, H 3.27, N 6.30.FT-IR (KBr pellet, cm1), selected bands: 3553 (m), 3284 (m),1622 (w), 1607 (s), 1575 (s), 1488 (m), 1444 (w), 1413 (m),1369 (s), 1219 (m), 1162 (m), 1093 (w), 1062 (m), 993 (m),906 (m), 856 (w), 812 (m), 775 (m), 712 (m), 662 (w), 618 (m),581 (w), 543 (w)

Reference： [1]Acta Crystallographica Section C: Structural Chemistry,2019,vol. 75,p. 1286 - 1298

18
[ 1050912-62-3 ]
[ 7732-18-5 ]
potassium hydroxide [ No CAS ]
[ 7646-85-7 ]
poly[[pentaaquabis[μ₃-5-(4-carboxybenzyloxy)isophthalato]bis[μ₆-5-(4-carboxylatobenzyloxy)isophthalato]di-μ₃-hydroxidohexazinc(II)] trihydrate] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
30%	at 160℃; for 72h;Autoclave; High pressure;	Amixture of H3L (0.10 mmol, 31.6 mg), ZnCl2 (0.15 mmol,20.5 mg), H2O (8 ml) and KOH (0.2 M, 1 ml) was placed in a25 ml Teflon-lined stainless steel vessel, which was heated at160 C for 3 d. After slow cooling to room temperature,colourless sheet-like crystals of (I) were obtained in 30% yield(based on the ZnII salt). The pH value was close to 6 for thefinal reaction system. Elemental analysis calculated (%) forC64H56O38Zn6: C 42.08, H 3.07; found: C 40.90, H 2.89. FT-IR(KBr pellet, cm1), selected bands: 3434 (m), 1607 (s), 1569(s), 1456 (m), 1375 (s), 1244 (s), 1169 (m), 1118 (w), 1056 (w),1012 (m), 906 (w), 850 (m), 768 (s), 724 (m), 674 (m), 606 (w),549 (w), 524 (w).

Reference： [1]Acta Crystallographica Section C: Structural Chemistry,2019,vol. 75,p. 1286 - 1298

19
[ 66-71-7 ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
[ 7646-85-7 ]
catena-poly[[[aqua(1,10-phenanthroline)zinc(II)]-μ₂-5-(4-carboxybenzyloxy)isophthalato] dihydrate] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
42%	With potassium hydroxide; at 160℃; for 72h;Autoclave; High pressure;	General procedure: Amixture of H3L (0.10 mmol, 31.6 mg), ZnCl2 (0.15 mmol,20.5 mg), H2O (8 ml) and KOH (0.2 M, 1 ml) was placed in a25 ml Teflon-lined stainless steel vessel, which was heated at160 C for 3 d. After slow cooling to room temperature,colourless sheet-like crystals of (I) were obtained in 30% yield(based on the ZnII salt). The pH value was close to 6 for thefinal reaction system.

Reference： [1]Acta Crystallographica Section C: Structural Chemistry,2019,vol. 75,p. 1286 - 1298

20
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 1050912-62-3 ]
[ 845712-67-6 ]
2C₁₆H₁₁O₇^(1-)*C₂₄H₂₂N₄*Co⁽²⁺⁾ [ No CAS ]

Reference： [1]New Journal of Chemistry,2020,vol. 44,p. 14896 - 14905

21
[ 4916-57-8 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
[ 33513-42-7 ]
[Cd(HL)(1,2-di(4-pyridyl)ethane)•H₂O]•H₂O•DMF}_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
48.5%	at 80℃; for 72h;Autoclave;	For the complex 1, we mixed 0.1 mmol and 0.0315 g H3L with 0.1 mmol and 0.0308 g Cd(NO3)2•4H2O and 0.1 mmol and 0.0156 g bpy to generate a mixture, and dissolved the obtained mixture into the 6 mL H2O and DMF solution (with the volume rate of 3:3), the above mixed solutions were then kept into the 25 mL stainless steel vessel lined with Teflon. After reaction for 72 hours under the pressure of autogenous at 80C, the above mixtures were cooled slowly to the ambient temperature. Thus, the crystals with block were filtrated, cleaned through utilizing the water and then dried, with 48.5% yield on the basis of H3L. Anal. calcd for the C31H34N3O10Cd, calcd.: N, 5.83 %; H, 4.75 and C, 51.64. Found: N 5.49%, H 4.37 and C 12.54. IR (KBr pellet: cm-1): 439(w), 492(w), 632(m), 696(w), 729(m), 779(m), 812(m), 1009(w), 1070(w), 1092(w), 1254(s), 1372(m), 1414(m), 1552(s), 1605(m), 1672(s), 3400(m).

Reference： [1]Journal of Molecular Structure,2021,vol. 1229

22
cobalt(II) nitrate hexahydrate [ No CAS ]
[ 1050912-62-3 ]
[ 56643-83-5 ]
[ 7732-18-5 ]
[Co(HL)(1,4-bis(imidazol-1-ylmethyl)benzene)]•2H₂O}_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
47.34%	In N,N-dimethyl-formamide; at 70 - 120℃; for 94.5h;	For the complex 2, we mixed 0.30 mmol and 0.095 g H3L with 0.30 mmol and 0.072 g pbix and 0.60 mmol and 0.178 g Co(NO3)2•6H2O to produce a mixture, and stirred the acquired mixture for half an hour at 70C in DMF and H2O mixture (with the volume rate of 2:8, mL). The above mixture was then kept in the glass bottle (25 mL) and heated for 94 hours at 120C, and after that, we cooled this mixture to the ambient temperature with 10C/h rate. Thus, we can gain the pink crystals of the complex 2 (with 47.34% and 0.089 g yield and on the basis of H3L). Anal. calcd for the C30H29N5O8Co: N, 10.83; H, 4.52 and C, 55.73; %. Found: N, 10.12%; H, 3.98 and C, 55.44. IR (KBr, cm-1): 731(m), 785(m), 1097(m), 1275(s), 1352(s), 1416(m), 1522(m), 1578(vs), 1618(m), 1678(m), 2910(w), 3016(w), 3134(m), 3383(m), 3529 (vs).

Reference： [1]Journal of Molecular Structure,2021,vol. 1229

23
[ 51-17-2 ]
copper(II) nitrate trihydrate [ No CAS ]
[ 1050912-62-3 ]
Cu⁽²⁺⁾*C₁₆H₁₀O₇^(2-)*C₇H₆N₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
41.2%	With sodium hydroxide; In water; at 150℃; for 72h;Autoclave;	For the synthesis of CP 2, a mixture of Cu(NO3)2·3H2O (0.50mmol, 0.12g), H3L (0.35mmol, 0.11g), biz (41mg, 0.35mmol), NaOH (14mg, 0.35mmol) and H2O (14mL) was sealed into the stainless steel container of 25mL lined with Teflon, the mixture was heated for 72h at 150C and then cooled at 5C·h-1 rate to the ambient temperature. Blue crystals with block-shape of CP 2 were harvested and cleaned by the distilled water and then dried in the air to obtain product; the yield is 41.2% (on the basis of CuII salts). Elemental analyses calcd (%) for C23H16N2O7Cu (495): C, 55.70; H, 3.25; N, 5.65. Found C, 55.59; H, 3.22; N, 5.57. IR (KBr pellet, cm-1): 2965 (w), 1734 (s), 1690 (s), 1598 (s), 1460 (m), 1285 (s), 1206 (s), 1121 (m), 1057 (m), 889 (w), 765 (m), 664 (w), 531 (w).

Reference： [1]Journal of Inorganic Biochemistry,2021,vol. 220

24
[ 288-88-0 ]
copper(II) nitrate trihydrate [ No CAS ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
2.5Cu⁽²⁺⁾*C₁₆H₉O₇^(3-)*2C₂H₂N₃^(1-)*4H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
36%	With sodium hydroxide; at 150℃; for 72h;Autoclave;	For the synthesis of CP 1, a mixture of Cu(NO3)2·3H2O (0.50mmol, 0.12g), H3L (0.35mmol, 0.11g), Htrz (0.35mmol, 0.024g), NaOH (0.50mmol and 0.20g) and H2O (14mL) was sealed into the stainless steel container of 25mL lined with Teflon, the mixture was heated for 72h at 150C and then cooled at 5C·h-1 rate to the ambient temperature. Blue crystals with block-shape of the CP 1 were harvested and cleaned by the distilled water and then dried in the air to obtain product; the yield is 36% (on the basis of CuII salts). Elemental analyses calcd (%) for C40H42N12O22Cu5 (1360): C, 35.31; H, 3.11; N, 12.35. Found C, 35.41; H, 3.02; N, 12.13. IR (KBr pellet, cm-1): 3320 (s), 3080 (w), 1766 (s), 1649 (s), 1551 (m), 1420 (w), 1250 (s), 1200 (s), 1055 (m), 1026 (m), 910 (m), 750 (s), 650 (w).

Reference： [1]Journal of Inorganic Biochemistry,2021,vol. 220

25
[ 553-26-4 ]
copper(II) nitrate trihydrate [ No CAS ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
potassium hydroxide [ No CAS ]
[Cu₅(L)₂(4,4'-bipyridine)₄(μ₂-OH)₂(μ₃–HCOO)₂(H₂O)₂]n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
60%	at 160℃; for 72h;Autoclave; High pressure;	The mixture generated via 0.1 mmol, 24 mg of Cu(NO 3 ) 2 •3H 2 O, 31.6 mg and 0.10 mmol H 3 L, 0.2 mmol and 31.2 mg of 4,4 - bi -pyridine (bpy) and 0.2 M and 1 ml of KOH in 8 ml of H 2 O (with the rate of 3:1) was stored in a stainless steel container lin- ing by Teflon (25 mL), and subsequently, heating it for seventy- two hours at 160 C. In the end, distilled water was utilized to clean blue crystals with rod-shape, which was then dried in vac- uum to acquire 1 with 60 percent of yield. The value of pH for the ultimate reaction system was close to 7. Elemental analysis calcu- lated (%) for the C 74 H 58 N 8 O 22 Cu 5 (1): N, 6.48%; C, 51.40% and H, 3.38%; found: N 6.30%, C 50.10% and H 3.27%. IR (KBr, cm -1 , Fig. S1): 557 m, 596 m, 649 w, 706 m, 741 s, 807 m, 837 s, 976 m, 1031s, 1112s, 1151 m, 1224 m, 1285 w, 1325 m, 1397 w, 1436 w, 1454 m, 1485 w, 1522 m, 1562 w, 1634s, 2371s, 2854 m, 2918 w, 3054 w, 3416 m.

Reference： [1]Journal of Molecular Structure,2022,vol. 1254

26
[ 51-17-2 ]
copper(II) nitrate trihydrate [ No CAS ]
[ 1050912-62-3 ]
[ 7732-18-5 ]
[ 1310-73-2 ]
[Cu₂(L)(benzimidazole)(OH)]•H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
45%	at 150℃; for 72h;pH 7.5;Autoclave; High pressure;	The mixture generated via 0.35 mmol, 111 mg H 3 L, 120 mg, 0.5 mmol Cu(NO 3 ) 2 •3H 2 O, 10 mL H 2 O and 41 mg and 0.35 mmol biz was adjusted to the pH value of 7.5 through using the NaOH solution (1 M). Afterwards, the resulting mixture was stored in the stainless steel container lining by Teflon (25 mL), which was sub- sequently heated for 3 days at 150 C temperature. After cooling the product naturally to ambient temperature with 5 C/h descent rate, the blue crystals for complex 2 could be gained, distilled wa- ter was used to clean it, which was then dried in the air to gain the product; with 45 percent of yield, (according to the Cu II salts). Elemental analyses calcd (%) for the C 30 H 24 N 4 O 9 Cu 2 : N, 7.87%, C, 50.63% and H, 3.40%. Found N, 7.65%, C, 50.46% and H, 3.23%. IR (KBr, cm -1 , Fig. S1): 620 m, 644 m, 702 m, 750 s, 788 m, 851 s, 984 w, 996 m, 1030 m, 1146 m, 1208 m, 1271 m, 1334 w, 1372s, 1435 w, 1454 w, 1503 m, 1532s, 1570s, 1633s, 2337 m, 2309 m, 2926 m, 3065 m, 3335 m.

Reference： [1]Journal of Molecular Structure,2022,vol. 1254

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P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 1050912-62-3 ] {[proInfo.proName]}

Quality Control of [ 1050912-62-3 ]

Related Doc. of [ 1050912-62-3 ]

Product Details of [ 1050912-62-3 ]

Safety of [ 1050912-62-3 ]

Application In Synthesis of [ 1050912-62-3 ]

[ 1050912-62-3 ] Synthesis Path-Downstream 1~26

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry