Structure of 10257-28-0
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The BI-3802 was designed by Boehringer Ingelheim and could be obtained free of charge through the Boehringer Ingelheim open innovation portal opnMe.com, associated with its negative control.
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Batch number can be found on the product's label following the word 'Batch'.
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CAS No. : | 10257-28-0 |
Formula : | C6H12O6 |
M.W : | 180.16 |
SMILES Code : | OC1[C@@H]([C@H]([C@H]([C@@H](CO)O1)O)O)O |
MDL No. : | MFCD00006969 |
GHS Pictogram: |
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Signal Word: | Warning |
Hazard Statements: | H319 |
Precautionary Statements: | P264-P280-P305+P351+P338-P337+P313 |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
88% | With toluene-4-sulfonic acid; at 100℃; for 24h; | 10241] To a stirred suspension of D-galactose 12 (22.2 g, 123 mmol) in allyl alcohol (250 mE) was added para-toluenesulfonic acid (2.3 g, 12.09 mmol). The mixture was heated to 1000 C. and stirred for 24 h after which it was cooled to r.t. and quenched by the addition of NEt3. The solvent was removed in vacuo and the crude product was co-evaporated twice with toluene and purified by flash column chromatography on silica gel (gradient CH2Cl2/MeOH9: 1 -4: 1). Recrystalization from EtOAc yielded galactoside 13 (22.2 g, 88%) as a white solid. |