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Chemical Structure| 952431-30-0 Chemical Structure| 952431-30-0

Structure of 952431-30-0

Chemical Structure| 952431-30-0

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Product Details of [ 952431-30-0 ]

CAS No. :952431-30-0
Formula : C36H34BNO2
M.W : 523.47
SMILES Code : CC1(C)C(C)(C)OB(C2=CC=C(N(C3=CC=C(C4=CC=CC=C4)C=C3)C5=CC=C(C6=CC=CC=C6)C=C5)C=C2)O1
MDL No. :MFCD29089353
InChI Key :PESBFNLGEMHNAM-UHFFFAOYSA-N
Pubchem ID :67523594

Safety of [ 952431-30-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis of [ 952431-30-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 952431-30-0 ]

[ 952431-30-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 39073-07-9 ]
  • [ 952431-30-0 ]
  • N-([1,1'-biphenyl]-4-yl)-N-(4-(7-bromodibenzo[b,e][1,4]dioxin-2-yl)phenyl)-[1,1'-biphenyl]-4-amine [ No CAS ]
YieldReaction ConditionsOperation in experiment
69% With tetrakis(triphenylphosphine) palladium(0); sodium carbonate; In water; toluene; for 8.0h;Heating; N-([1,1'-biphenyl]-4-yl)-N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-[1,1'-biphenyl]-4-amine (10.5g, 20.0mmol), 2,7- dibromodibenzo [b, e] [1,4] dioxine (6.8g, 20.0mmol) and Pd (PPh 3 ) 4 (1.1g, 1.0mmol) and the mixture in the flask 2M Na 2 CO 3 was dissolved into a saturated aqueous solution of Toluene and 200 30 was stirred under heating for 8 hours. After completion of the reaction distilled water and extracted with ethyl acetate. The resulting organic layer was Na 2 SO 4 dried and evaporated under reduced pressure and then purified by column chromatography to the compound N - ([1,1'-biphenyl] -4-yl) -N- (4- (7-bromodibenzo [b, e] [1,4] dioxin-2 -yl) phenyl) - [1,1'-biphenyl] -4-amine ( to give the 9.1g, yield 69%).
 

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