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Chemical Structure| 94084-75-0 Chemical Structure| 94084-75-0

Structure of 94084-75-0

Chemical Structure| 94084-75-0

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Product Details of [ 94084-75-0 ]

CAS No. :94084-75-0
Formula : C11H10N2O2
M.W : 202.21
SMILES Code : O=C(O)C1=CC=C(CN2C=CN=C2)C=C1
MDL No. :MFCD09736739
InChI Key :PBTHRDAMTTXZFL-UHFFFAOYSA-N
Pubchem ID :10330479

Safety of [ 94084-75-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis of [ 94084-75-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 94084-75-0 ]

[ 94084-75-0 ] Synthesis Path-Downstream   1~14

  • 1
  • [ 64-17-5 ]
  • [ 94084-75-0 ]
  • [ 56643-80-2 ]
  • 2
  • [ 101184-10-5 ]
  • [ 94084-75-0 ]
  • [ 108035-42-3 ]
  • 3
  • [ 112809-54-8 ]
  • [ 94084-75-0 ]
  • 4
  • 4-Imidazol-1-ylmethyl-benzoyl chloride [ No CAS ]
  • [ 94084-75-0 ]
  • 5
  • [ 288-32-4 ]
  • [ 6232-88-8 ]
  • [ 94084-75-0 ]
  • 6
  • [ 876-08-4 ]
  • [ 94084-75-0 ]
  • 7
  • [ 94084-75-0 ]
  • [ 139277-57-9 ]
  • 8
  • [ 17201-43-3 ]
  • [ 94084-75-0 ]
  • 9
  • [ 94084-75-0 ]
  • [ 203521-17-9 ]
  • 1-(6-chloronaphthalene-2-sulfonyl)-4-[4-(1H-imidazol-1-ylmethyl)benzoyl]piperazine [ No CAS ]
  • 10
  • [ 207798-96-7 ]
  • [ 94084-75-0 ]
  • 1-(6-bromonaphthalene-2-sulfonyl)-4-[4-(1H-imidazol-1-ylmethyl)benzoyl]piperazine [ No CAS ]
  • 12
  • [ 114985-63-6 ]
  • [ 94084-75-0 ]
  • 1-Acetyl-3-{1-hydroxy-1-[4-(imidazol-1-yl-methyl)-phenyl]-methylidene}-5-nitro-2-indolinone [ No CAS ]
YieldReaction ConditionsOperation in experiment
89% O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; In N,N-dimethyl-formamide; (a) 1-Acetyl-3-{1-hydroxy-1-[4-(imidazol-1-yl-methyl)-phenyl]-methylidene}-5-nitro-2-indolinone Prepared analogously to Example 10(a) from 1-acetyl-5-nitro-indolinone and 4-(imidazol-1-ylmethyl)benzoic acid in dry DMF in the presence of TBTU, HOBT and Hunig's base. Yield: 89% of theory; Melting point: 235-237 C.; C21 H16 N4 O5 (404.39); Calc.: molar peak (M-H)- =403; Found: molar peak (M-H)- =403.
  • 13
  • silver nitrate [ No CAS ]
  • [ 94084-75-0 ]
  • Ag(1+)*C11H10N2O2*C11H9N2O2(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
Ca. 58% In water; at 120.0℃; for 240.0h;Autoclave; High pressure; A mixture of AgNO3 (0.034 g, 0.20 mmol), Himbz(0.025 g, 0.10mmol), with a mole ratio of 2:1 was dissolved in 8mL H2O and stirredfor 15 min. The final mixture was placed in a Teflon-lined stainless steel vessel(20 mL) under autogenous pressure and heated at 120 C for 10 days. After slowly cooling to the room temperature, the mixture was washed with distilled water and colourless-block crystals were filtered off and dried at room temperature (yield ca.58%, based on Himbz). Elemental analysis (%): Calc. for C22H19AgN4O4 (Mr: 511.28):C, 51.68; N, 10.96; H, 3.75. Found: C, 51.70; N, 10.99; H, 3.76%. IR (cm-1): 3555 (br,s), 3102 (w), 2921 (w), 1710 (vs), 1605 (vs), 1530 (vs), 1381 (s), 1307 (m), 1120(m), 785 (vs), 773 (s), 638 (w), 520 (w), 479 (w). 1H NMR (DMSO-d6, 400 MHz)δ(ppm): 10.18 (s, 1H, Himbz-COOH), 7.82 (m, 8H, Himbz-H2,3,5,6), 7.69(d, 4H,Himbz-H9,10), 7.22(s, 2H, Himbz-H8), 5.33(s, 4H, -CH2).
  • 14
  • 2-(piperidin-1-ylmethyl)-1H-benzo[d]imidazol-5-amine [ No CAS ]
  • [ 94084-75-0 ]
  • 4-((1H-imidazol-1-yl)methyl)-N-(2-(piperidin-1-ylmethyl)-1H-benzo[d]imidazol-5-yl)benzamide [ No CAS ]
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 94084-75-0 ]

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Related Parent Nucleus of
[ 94084-75-0 ]

Imidazoles

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