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Chemical Structure| 913836-26-7 Chemical Structure| 913836-26-7

Structure of 913836-26-7

Chemical Structure| 913836-26-7

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Product Details of [ 913836-26-7 ]

CAS No. :913836-26-7
Formula : C12H15BClNO4
M.W : 283.52
SMILES Code : CC1(C)C(C)(C)OB(C2=CC=C(Cl)C([N+]([O-])=O)=C2)O1
MDL No. :MFCD08235086
InChI Key :VEIRGLFECZUCTI-UHFFFAOYSA-N
Pubchem ID :44119859

Safety of [ 913836-26-7 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 913836-26-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 913836-26-7 ]

[ 913836-26-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 913836-26-7 ]
  • [ 850567-56-5 ]
YieldReaction ConditionsOperation in experiment
94% With iron; ammonium chloride; In ethanol; water; at 105℃; for 2.0h; Compound 1 (55.0 g, 190 mmol) was added to a three-neck flask.Ethanol (500 mL),Water (100 mL) andAmmonium chloride (20.4 g, 390 mmol);Iron powder (49 g, 880 mmol) was slowly added with stirring at room temperature.The reaction solution was heated to reflux at 105 C for 2 hours.After cooling to room temperature, Celite was filtered to remove excess iron; ethanol was distilled off under reduced pressure, and water (100 mL) and saturated aqueous sodium bicarbonate solution (150 mL) were added.Extraction with ethyl acetate (200 mL x 3); the organic phases were combined, washed with saturated aqueous sodium bicarbonate (150 mL) and saturated brine (150 mL), dried over sodium sulfate and filtered.The filtrate was spin-dried to give a yellow liquid, compound 2 (45.5 g, 179 mmol, 94%)
 

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