Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 89892-38-6 Chemical Structure| 89892-38-6

Structure of 89892-38-6

Chemical Structure| 89892-38-6

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 89892-38-6 ]

CAS No. :89892-38-6
Formula : C8H5Br2N
M.W : 274.94
SMILES Code : N#CC1=CC=C(CBr)C=C1Br
MDL No. :MFCD09261043
InChI Key :FOVQCPSLQZIRSB-UHFFFAOYSA-N
Pubchem ID :53425521

Safety of [ 89892-38-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302-H314
Precautionary Statements:P280-P305+P351+P338-P310
Class:8
UN#:1759
Packing Group:

Application In Synthesis of [ 89892-38-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 89892-38-6 ]

[ 89892-38-6 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 5932-27-4 ]
  • [ 89892-38-6 ]
  • [ 1034188-51-6 ]
YieldReaction ConditionsOperation in experiment
With potassium tert-butylate; In ethanol; at 60℃; Description 43; Ethyl 1 -[(3-bromo-4-cyanophenyl)methyl]-1 H-pyrazole-3-carboxylate (D43); A suspension of ethyl 1 H-pyrazole-3-carboxylate (D1 ) (3.298g, 0.024 mol), 4- (bromomethyl)-2-bromobenzonitrile (D42) (6.48g, 0.024 mol) and potassium t- butoxide (2.903g, 0.026 mol), in ethanol (250ml) was heated at 6O0C overnight. The reaction mixture was concentrated in vacuo and dissolved in water (~250ml) and ethylacetate (-25OmI), the layers were partitioned and the aq was washed twice with ethylacetate (2x 100ml). The combined organics were passed through a phase separating cartridge to dry and concentrated in vacuo. The residue was scratched down and stirred in ethylacetate (~50ml) and the resultant solid was filtered off. The mother liquors were concentrated in vacuo and purified by Biotage SP4 with 4OM cartridge and 30-70percent ethylacetate/hexane as eluant. The product containing fractions were combined and concentrated. This product was combined with the first crop to yield the title compound as a white solid (1.55g, 4.6 mmol). MS (ES+): requires C14H1279BrN3O2 333; found 334 (M+H+).
  • 2
  • [ 78581-99-4 ]
  • [ 89892-38-6 ]
  • 2-bromo-4-((5,6-difluoro-1H-benzo[d]imidazol-1-yl)methyl)benzonitrile [ No CAS ]
YieldReaction ConditionsOperation in experiment
39% With potassium carbonate; In acetonitrile; at 25℃; for 12h; A solution of 5,6-difluoro-1 H-benzo[d]imidazole (1.4 g, 9 mmol), 2-bromo-4-(bromomethyl) benzonitrile (2.5 g, 9 mmol) [see Example 1 Step A] and K2C03 (3.8 g, 27 mmol) in CH3CN (50 mL) was heated at 25C for 12 hours. The reaction mixture was cooled to 25C, filtered and concentrated under reduced pressure. The residue was purified by silica gel chromatography using Petroleum ether:EtOAc (30: 1-3:1 ) as eluting solvents to afford 2-bromo-4-((5,6-difluoro-1 H- benzo[d]imidazol-1-yl)methyl)benzonitrile as a yellow solid (1.3 g, 39%). MS (ESI) m/z: 348 [M+H]+.
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 89892-38-6 ]

Aryls

Chemical Structure| 1032822-10-8

A173733 [1032822-10-8]

2-Bromo-5-(bromomethyl)benzonitrile

Similarity: 0.97

Chemical Structure| 1086429-87-9

A315332 [1086429-87-9]

2-Bromo-3-(bromomethyl)benzonitrile

Similarity: 0.94

Chemical Structure| 89892-39-7

A754884 [89892-39-7]

3-Bromo-4-(bromomethyl)benzonitrile

Similarity: 0.94

Chemical Structure| 190197-86-5

A509956 [190197-86-5]

4-Bromo-3-(bromomethyl)benzonitrile

Similarity: 0.91

Chemical Structure| 1243536-87-9

A541753 [1243536-87-9]

2-Bromo-6-(bromomethyl)benzonitrile

Similarity: 0.89

Bromides

Chemical Structure| 1032822-10-8

A173733 [1032822-10-8]

2-Bromo-5-(bromomethyl)benzonitrile

Similarity: 0.97

Chemical Structure| 1086429-87-9

A315332 [1086429-87-9]

2-Bromo-3-(bromomethyl)benzonitrile

Similarity: 0.94

Chemical Structure| 89892-39-7

A754884 [89892-39-7]

3-Bromo-4-(bromomethyl)benzonitrile

Similarity: 0.94

Chemical Structure| 190197-86-5

A509956 [190197-86-5]

4-Bromo-3-(bromomethyl)benzonitrile

Similarity: 0.91

Chemical Structure| 1243536-87-9

A541753 [1243536-87-9]

2-Bromo-6-(bromomethyl)benzonitrile

Similarity: 0.89

Benzyl Bromides

Chemical Structure| 1032822-10-8

A173733 [1032822-10-8]

2-Bromo-5-(bromomethyl)benzonitrile

Similarity: 0.97

Chemical Structure| 1086429-87-9

A315332 [1086429-87-9]

2-Bromo-3-(bromomethyl)benzonitrile

Similarity: 0.94

Chemical Structure| 89892-39-7

A754884 [89892-39-7]

3-Bromo-4-(bromomethyl)benzonitrile

Similarity: 0.94

Chemical Structure| 190197-86-5

A509956 [190197-86-5]

4-Bromo-3-(bromomethyl)benzonitrile

Similarity: 0.91

Chemical Structure| 1243536-87-9

A541753 [1243536-87-9]

2-Bromo-6-(bromomethyl)benzonitrile

Similarity: 0.89

Nitriles

Chemical Structure| 1032822-10-8

A173733 [1032822-10-8]

2-Bromo-5-(bromomethyl)benzonitrile

Similarity: 0.97

Chemical Structure| 1086429-87-9

A315332 [1086429-87-9]

2-Bromo-3-(bromomethyl)benzonitrile

Similarity: 0.94

Chemical Structure| 89892-39-7

A754884 [89892-39-7]

3-Bromo-4-(bromomethyl)benzonitrile

Similarity: 0.94

Chemical Structure| 190197-86-5

A509956 [190197-86-5]

4-Bromo-3-(bromomethyl)benzonitrile

Similarity: 0.91

Chemical Structure| 1243536-87-9

A541753 [1243536-87-9]

2-Bromo-6-(bromomethyl)benzonitrile

Similarity: 0.89