[ CAS No. 88353-04-2 ] 12-(Benzyloxy)-12-oxododecanoic acid

Cat. No.: A408850

2D 3D

Structure of 88353-04-2 * Storage: Sealed in dry,Room Temperature

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* Storage: Sealed in dry,Room Temperature

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Quality Control of [ 88353-04-2 ]

COA NMR CNMR HPLC LC-MS

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Specification

Alternatived Products of [ 88353-04-2 ]

Product Details of [ 88353-04-2 ]

CAS No. :	88353-04-2	MDL No. :	MFCD29090558
Formula :	C₁₉H₂₈O₄	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	ZDTVBXVYNIHVNR-UHFFFAOYSA-N
M.W :	320.42	Pubchem ID :	14250267
Synonyms :

Safety of [ 88353-04-2 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 88353-04-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 88353-04-2 ]

[ 88353-04-2 ] Synthesis Path-Downstream 1~2

1
[ 623-57-4 ]
[ 88353-04-2 ]
1,12-dodecanedioic acid benzyl ester 2-(11-benzyloxycarbonylundecanoyloxy)-3-dimethylaminopropyl ester [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
50%	With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 20℃; for 48h;	Dodecanedioic acid benzyl ester 2-(11-benzyloxycarbonyl-undecanoyloxy)-3-dimethylamino-propyl ester (29a) To an ice-cold solution of 24a (1.78 g, 5.5 mmol), 3-dimethylamino-propane-1,2-diol (0.3 mL, 2.5 mmol) and DMAP (catalytic amount) in DCM (15 mL) was slowly added a solution of DCC (1.1 g, 5.5 mmol) in DCM (5 mL). After the addition, the solution was warmed to room temperature and stirred for 2 days. The reaction mixture was then filtered to remove the insoluble DCU. Concentration of the filtrate followed by chromatography (50percent EtOAc/DCM to 100percent EtOAC) afforded 0.9 g (50percent yield) product as colorless oil. The characterization data were consistent with the proposed structure.

Reference： [1]Journal of the American Chemical Society,2004,vol. 126,p. 12196 - 12197
[2]Patent: US2006/241071,2006,A1 .Location in patent: Page/Page column 58-59
[3]Bioconjugate Chemistry,2011,vol. 22,p. 690 - 699

2
[ 623-57-4 ]
[ 88353-04-2 ]
[2,3-bis-(11-benzyloxycarbonylundecanoyloxy)propyl]trimethylammonium iodide [ No CAS ]

Reference： [1]Bioconjugate Chemistry,2011,vol. 22,p. 690 - 699

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Isomers

Technical Information

• Acyl Group Substitution • Arndt-Eistert Homologation • Bouveault-Blanc Reduction • Catalytic Hydrogenation • Complex Metal Hydride Reductions • Ester Cleavage • Hunsdiecker-Borodin Reaction • Passerini Reaction • Preparation of Amines • Preparation of Carboxylic Acids • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Reactions of Carboxylic Acids • Reactions with Organometallic Reagents • Schmidt Reaction • Specialized Acylation Reagents-Carbodiimides and Related Reagents • Specialized Acylation Reagents-Ketenes • Ugi Reaction

Historical Records

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[ 88353-04-2 ]

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[ CAS No. 88353-04-2 ] 12-(Benzyloxy)-12-oxododecanoic acid

Quality Control of [ 88353-04-2 ]

Related Doc. of [ 88353-04-2 ]

Product Details of [ 88353-04-2 ]

Safety of [ 88353-04-2 ]

Application In Synthesis of [ 88353-04-2 ]

[ 88353-04-2 ] Synthesis Path-Downstream 1~2

Technical Information

Related Functional Groups of [ 88353-04-2 ]

Aryls

Esters

Carboxylic Acids

Precautionary Statements-General

Prevention

Response

Storage

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Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 88353-04-2 ]