Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 86398-94-9 Chemical Structure| 86398-94-9

Structure of 86398-94-9

Chemical Structure| 86398-94-9

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 86398-94-9 ]

CAS No. :86398-94-9
Formula : C7H5Cl2F3N2
M.W : 245.03
SMILES Code : NNC1=C(Cl)C=C(C=C1Cl)C(F)(F)F
MDL No. :MFCD00085001
InChI Key :FYOWOHMZNWQLFG-UHFFFAOYSA-N
Pubchem ID :688223

Safety of [ 86398-94-9 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302+H312+H332-H315-H319-H335-H350
Precautionary Statements:P201-P202-P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312-P304+P340+P312-P305+P351+P338-P308+P313-P332+P313-P337+P313-P403+P233-P405-P501
Class:6.1
UN#:2811
Packing Group:

Application In Synthesis of [ 86398-94-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 86398-94-9 ]

[ 86398-94-9 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 55589-47-4 ]
  • [ 86398-94-9 ]
  • <i>N</i>-(2,6-dichloro-4-trifluoromethyl-phenyl)-<i>N</i>'-(3-methyl-pyridin-2-ylmethylene)-hydrazine [ No CAS ]
  • 2
  • [ 5780-66-5 ]
  • [ 86398-94-9 ]
  • <i>N</i>-(2,6-dichloro-4-trifluoromethyl-phenyl)-<i>N</i>'-pyrazin-2-ylmethylene-hydrazine [ No CAS ]
  • 3
  • [ 50594-82-6 ]
  • [ 86398-94-9 ]
YieldReaction ConditionsOperation in experiment
<= 3.7% With hydrazine; In tetrahydrofuran; at 50℃; for 24h;Product distribution / selectivity; Comparative Example 1 : Preparation of 2,6-dichloro-4-(trifluoromethyl) phenylhydrazine of the formula 1-1 from 3,4,5-trichloro- benzotrifluoride in tetrahydrofurane; 10 g (40 mmole) of <strong>[50594-82-6]3,4,5-trichlorobenzotrifluoride</strong> (99.7% purity) were dissolved in 30 g (417 mmole) of tetrahydrofurane. To this solution were added 8 g (160 mmole) of <n="10"/>hydrazine hydrate (100%). The resulting mixture was stirred at 500C for 24 hours. Thereafter, an organic phase of 40.7 g was separated. The solution obtained by this separation contained the product 2,6-dichloro-4-(trifluoromethyl)phenylhydrazine in an amount of 0.9 wt-% and the starting material <strong>[50594-82-6]3,4,5-trichlorobenzotrifluoride</strong> in an amount of 27.1 wt-%, meaning that a product yield not higher than 3.7 % was obtained.
<= 3.6% With hydrazine; In toluene; at 110℃; for 24h;Product distribution / selectivity; Comparative Example 3: Preparation of 2,6-dichloro-4-(trifluoromethyl)phenyl- hydrazine of the formula 1-1 from 3,4,5-trichloro- benzotrifluoride in toluene; 10 g (40 mmole) of <strong>[50594-82-6]3,4,5-trichlorobenzotrifluoride</strong> (99.7% purity) were dissolved in 30 g (326 mmole) of toluene. To this solution were added 8 g (160 mmole) of hydrazine hydrate (100%). The resulting mixture was stirred at reflux (approx. 1100C) for 24 hours. Thereafter, an organic phase of 39.4 g was separated. The solution obtained by this separation contained the product 2,6-dichloro-4-(trifluoromethyl)phenylhydrazine in an amount of 0.9 wt-% and the starting material <strong>[50594-82-6]3,4,5-trichlorobenzotrifluoride</strong> in an amount of 26.3 wt-%, meaning that a product yield not higher than 3.6 % was obtained.
<= 2.5% With hydrazine; In pyridine; at 25℃; for 24h;Product distribution / selectivity; Comparative Example 2: Preparation of 2,6-dichloro-4-(trifluoromethyl)phenyl- hydrazine of the formula 1-1 from 3,4,5-trichloro- benzotrifluoride in pyridine (amount of hydrazine hydrate: 4 equivalents, reaction time: 24 hours, reaction temperature: 25C); 10 g (40 mmole) of <strong>[50594-82-6]3,4,5-trichlorobenzotrifluoride</strong> (99.7% purity) were dissolved in 30 g (380 mmole) of pyridine. To this solution were added 8 g (160 mmole) of hydrazine hydrate (100%). The resulting mixture was stirred at 25C for 24 hours. Thereafter, an organic phase of 41.6 g was separated (lower phase). The solution obtained by this separation contained the product 2,6-dichloro-4-(trifluoromethyl) phenylhydrazine in an amount of 0.5 wt-% and the starting material <strong>[50594-82-6]3,4,5-trichlorobenzotrifluoride</strong> in an amount of 26.4 wt-%, meaning that a product yield not higher than 2.5 % was obtained.
With hydrazine hydrate; In pyridine; water; 6.2 g (0.025 mol) of 3,4,5-trichloro-trifluoromethylbenzene and 6.25 g (0.125 mol) of hydrazine hydrate are heated under reflux for 48 hours at 115-120 C. in 12 ml of pyridine. For working up, the solvent is distilled off, and the residue is taken up in water and extracted three times with about 30 ml of dichloromethane each time. The combined organic phases are dried over magnesium sulphate and evaporated in vacuo, and the residue is then distilled. 5.1 g (83% of theory) of 2,6-dichloro-4-trifluoromethylphenylhydrazine of melting point 56 to 57 C. are obtained. STR954
With hydrazine hydrate; In pyridine; dichloromethane; water; 6.2 g (0.025 mole) of 3,4,5-trichloro-trifluoromethylbenzene and 6.25 g (0.125 mole) of hydrazine hydrate are heated under reflux in 12 ml of pyridine at 115-120 C. for 48 hours. For working up, the solvent is distilled off, the residue is taken up in water and the mixture is extracted three times with in each case about 30 ml of methylene chloride. The combined organic phases are dried over magnesium sulphate, concentrated in vacuo and then distilled. 5.1 g (83% of theory) of 2,6-dichloro-4-trifluoromethylphenylhydrazine of melting point 56 to 57 C. are obtained. The following 1-aryl-5-hydrazino-pyrazoles of the formula (I) are obtained in a corresponding manner and in accordance with the general statements on the preparation: STR59
With hydrazine hydrate; In pyridine; water; 6.2 g (0.025 mol) of 3,4,5-trichloro-trifluoromethylbenzene and 6.25 g (0.125 mol) of hydrazine hydrate are refluxed at 115-120 C. for 48 hours in 12 ml of pyridine. For work-up, the solvent is removed by distillation, and the residue is taken up in water and extracted three times with about 30 ml of dichloromethane in each case. The combined organic phases are dried over magnesium sulphate, concentrated in vacuo and subsequently distilled. 5.1 g (83% of theory) of 2,6-dichloro-4-trifluoromethylphenylhydrazine of melting point 56 to 57 C. are obtained.

 

Historical Records

Technical Information

Categories