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Chemical Structure| 863393-98-0 Chemical Structure| 863393-98-0

Structure of 863393-98-0

Chemical Structure| 863393-98-0

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Product Details of [ 863393-98-0 ]

CAS No. :863393-98-0
Formula : C10H16N2O3
M.W : 212.25
SMILES Code : O=CC1=NC=CN1CC(OCC)OCC

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Application In Synthesis of [ 863393-98-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 863393-98-0 ]

[ 863393-98-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 863393-98-0 ]
  • [ 18653-98-0 ]
  • N,N'-{N-ethyl-2-diethoxy}-2-methyl-imidazole-N,N'-bis(2-hydroxybenzyl)-ethylenediamine [ No CAS ]
YieldReaction ConditionsOperation in experiment
20.1% With sodium tris(acetoxy)borohydride; In 1,1-dichloroethane; at 20℃; for 18h; Placed N, N'-Bis (2-hydroxybenzyl) ethylenediamine (0.1 g,0..367 mmol) in a 100 ml round-bottom flask equipped with a stirrer under nitrogen. The solid was dissolved in 8 ml of dichloroethane, followed by addition of [N-{ethyl-2-diethoxy}-2- imidazolecarboxaldehyde] (0.165 g, 0.775 mmol) and sodium triacetoxyborohydride (0.178 g, 0.845 mmol). The solution was stirred at room temperature for 18 hours. The solution was then vacuumed down to residue. The residue was passed through a silca gel column using 0-20% methanol/methylene chloride as the solvents, yielding 0.049 g, 20. 1 % yield.lHNMR ((CDC13), 300 MHz): 1.10 (t, 12H), 2.10 (s, 8H), 2.77 (s, 2H), 3.34 (m, 4H), 3.58 (m, 4H), 3.77 (s, 2H), 3.84 (d, 2H), 4.45 (t, 2H), 6.72 (t, 2H), 6.85 (m, 8H), 6.96 (s, 2H), 7.13 (t, 2H). ES/MS = 666-668: expected 668.
 

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