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[ CAS No. 84689-37-2 ] {[proInfo.proName]}

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3d Animation Molecule Structure of 84689-37-2
Chemical Structure| 84689-37-2
Chemical Structure| 84689-37-2
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Product Details of [ 84689-37-2 ]

CAS No. :84689-37-2 MDL No. :MFCD19690055
Formula : C11H11NO Boiling Point : -
Linear Structure Formula :- InChI Key :AEMWYMNWYXZDHH-UHFFFAOYSA-N
M.W : 173.21 Pubchem ID :12820990
Synonyms :

Safety of [ 84689-37-2 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501 UN#:
Hazard Statements:H302-H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 84689-37-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 84689-37-2 ]

[ 84689-37-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 108-05-4 ]
  • [ 1257846-26-6 ]
  • [ 76143-84-5 ]
  • [ 84689-37-2 ]
YieldReaction ConditionsOperation in experiment
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; cesium acetate In methanol at 60℃; for 48h; Inert atmosphere; Sealed tube; Overall yield = 58 %; Overall yield = 100 mg; General procedure for the synthesis of isoquinolines General procedure: Vinyl acetate (922μL, 10.0mmol) was added to a solution of the acetylated oxime (1mmol) in MeOH (0.5mL, 2M) with CsOAc (58mg, 0.3mmol) and [Cp*RhCl2]2 (6mg, 0.01mmol) in a septum-topped vial under nitrogen. The reaction vials were sealed and heated to 60°C for 48h. The crude reaction mixture was loaded on to a 5g SCX column that was subsequently washed with MeOH (2×25mL). The product eluted with the secondary wash using 0.7M NH3 in MeOH (2×25mL) to give the clean product (>90% purity). Products containing impurities were purified using flash silica chromatography.
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