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Chemical Structure| 7703-74-4 Chemical Structure| 7703-74-4

Structure of 2,6-Bis(bromomethyl)pyridine
CAS No.: 7703-74-4

Chemical Structure| 7703-74-4

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Product Details of [ 7703-74-4 ]

CAS No. :7703-74-4
Formula : C7H7Br2N
M.W : 264.95
SMILES Code : BrCC1=CC=CC(CBr)=N1
MDL No. :MFCD00191795
InChI Key :QUTSYCOAZVHGGT-UHFFFAOYSA-N
Pubchem ID :603610

Safety of [ 7703-74-4 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302-H315-H318-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P310-P321-P330-P332+P313-P362-P403+P233-P405-P501
Class:8
UN#:1759
Packing Group:

Application In Synthesis of [ 7703-74-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 7703-74-4 ]

[ 7703-74-4 ] Synthesis Path-Downstream   1~11

  • 1
  • [ 7703-74-4 ]
  • [ 3386-18-3 ]
  • [ 95216-13-0 ]
  • 2
  • [ 7703-74-4 ]
  • [ 35344-95-7 ]
  • 2,6-bis(4-formylpyrazolylmethyl)pyridine [ No CAS ]
  • 4
  • [ 6086-21-1 ]
  • [ 7703-74-4 ]
  • 2,6-bis(N1-methyl-N4-methylenetriazolium)pyridine dibromide [ No CAS ]
  • 5
  • [ 7703-74-4 ]
  • [ 69506-85-0 ]
  • C16H19N5(2+)*2Br(1-) [ No CAS ]
  • 6
  • [ 7703-74-4 ]
  • [ 39987-25-2 ]
  • dimethyl 2,2'-((6-(bromomethyl)pyridin-2-yl)methylazanediyl)diacetate [ No CAS ]
  • 7
  • [ 7703-74-4 ]
  • [ 939-69-5 ]
  • 6-((6-(bromomethyl)pyridin-2-yl)methoxy)benzo[d]thiazole-2-carbonitrile [ No CAS ]
YieldReaction ConditionsOperation in experiment
69% With caesium carbonate; In tetrahydrofuran; at 50℃; for 16h; To a solution of 2,6-bis(bromomethyl)pyridine (460 mg, 1.74 mmol) and <strong>[939-69-5]2-cyano-6-hydroxybenzothiazole</strong> (200 mg, 1.14 mmol)in THF (50 mL) was added Cs2CO3 (450 mg, 1.38 mmol). The reaction was heated at 50 C for 16 hthen cooled to rt and filtered. The filtrate was concentrated and purified by flash chromatography(hexanes/EtOAc, 6:4) to afford 5 as a white solid (284 mg, 69%). 1H NMR (400 MHz, CDCl3): d 8.10 (d,1H, J = 9.2 Hz), 7.76 (t, 1H, J = 7.6 Hz), 7.40-7.47. (m, 3H), 7.34 (dd, 1H, J = 2.4, 9.2 Hz), 5.30 (s, 2H), 4.58(s, 2H). ESI-MS: m/z 360.0 [M + H]+.
  • 8
  • [ 17084-13-8 ]
  • [ 7703-74-4 ]
  • [ 584-08-7 ]
  • [ 58966-93-1 ]
  • C33H45N9*F6P(1-)*K(1+) [ No CAS ]
  • 9
  • [ 7703-74-4 ]
  • [ 497-19-8 ]
  • [ 58966-93-1 ]
  • C33H46N9(1+)*Na(1+)*2Cl(1-) [ No CAS ]
  • 10
  • [ 7703-74-4 ]
  • [ 497-19-8 ]
  • [ 58966-93-1 ]
  • C33H45N9*Na(1+)*Cl(1-) [ No CAS ]
  • 11
  • [ 7703-74-4 ]
  • [ 554-13-2 ]
  • [ 58966-93-1 ]
  • C33H45N9*Li(1+)*F6P(1-) [ No CAS ]
 

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